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Multilayer Silicene Nanoribbons

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† Consiglio Nazionale delle Ricerche -ISM, via Fosso del Cavaliere, 00133 Roma, Italy
‡ International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
§ Consiglio Nazionale delle Ricerche-ISAC, via Fosso del Cavaliere, 00133 Roma, Italy
∥ Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
⊥ Aix-Marseille University, CNRS-CINaM, Campus de Luminy, Case 913, 13288 Marseille Cedex 9, France
*(P.D.P.) Tel:+39-06-49934144. Fax:+39-06-49934153. E-mail: [email protected]. (G.L.L.) E-mail: [email protected]
Cite this: Nano Lett. 2012, 12, 11, 5500–5503
Publication Date (Web):October 11, 2012
https://doi.org/10.1021/nl302598x
Copyright © 2012 American Chemical Society
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Abstract

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The synthesis of silicene, graphene-like silicon, has generated very strong interest. Here, we reveal the growth of high aspect ratio, perfectly straight, and aligned silicon nanoribbons, exhibiting pyramidal cross section. They are multistacks of silicene and show in angle-resolved photoemission cone-like dispersion of their π and π* bands, at the X̅ point of their one-dimensional Brillouin zone, with Fermi velocity of ∼1.3 × 106 m sec–1, which is very promising for potential applications.

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