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Responsive Multidomain Free-Standing Films of Gold Nanoparticles Assembled by DNA-Directed Layer-by-Layer Approach

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Nano Lett. 2013, 13, 9, 4449-4455
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    Responsive Multidomain Free-Standing Films of Gold Nanoparticles Assembled by DNA-Directed Layer-by-Layer Approach
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    ‡ †Department of Chemical and Biomolecular Engineering and ‡Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States
    § Department of Chemistry and Nano Science, Global Top 5 Program, Ewha Womans University, Seoul, 120-750, Korea
    *E-mail: [email protected] (S.-J.P); [email protected] (J.C.C.).
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    Nano Letters

    Cite this: Nano Lett. 2013, 13, 9, 4449–4455
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    https://doi.org/10.1021/nl4023308
    Published August 9, 2013
    Copyright © 2013 American Chemical Society
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    Abstract

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    Responsive free-standing films of gold nanoparticles are fabricated by a new approach combining the programmable DNA-directed self-assembly and the layer-by-layer (LbL) thin film fabrication technique. This approach allows for the assembly of multidomain nanoparticle films with each domain possessing distinct properties in response to external stimuli, which is essential for the formation of dynamic nanostructures. Large area free-standing films of DNA-modified gold particles are fabricated by the selective melting of a sacrificial nanoparticle domain, taking advantage of the unique sharp melting transition of DNA-modified gold nanoparticles. Furthermore, we show that released multidomain films can be designed to further split into multiple intact daughter films in a precisely controlled manner, demonstrating that this new approach provides a powerful means to fabricate free-standing nanoparticle films that are capable of programmable transformation.

    Copyright © 2013 American Chemical Society

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    Supporting Information

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    Detailed experimental methods, free energy calculations, linker exchange experiments, kinetic experiments, and additional extinction spectra, melting profiles, and SEM images of LbL films. This material is available free of charge via the Internet at http://pubs.acs.org.

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    This article is cited by 49 publications.

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    Nano Letters

    Cite this: Nano Lett. 2013, 13, 9, 4449–4455
    Click to copy citationCitation copied!
    https://doi.org/10.1021/nl4023308
    Published August 9, 2013
    Copyright © 2013 American Chemical Society
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