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High Electrochemical Selectivity of Edge versus Terrace Sites in Two-Dimensional Layered MoS2 Materials

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† Department of Applied Physics, Stanford University, Stanford, California 94305, United States
‡ School of Materials Science and Engineering, Beihang University, Beijing 100191, People’s Republic of China
§ §Department of Materials Science and Engineering and ∥Department of Chemical Engineering, Stanford University, Stanford, California 94305, United States
⊥ Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United States
*E-mail: [email protected] (Y.C.).
*E-mail: [email protected] (Q.Z.).
Cite this: Nano Lett. 2014, 14, 12, 7138–7144
Publication Date (Web):November 5, 2014
https://doi.org/10.1021/nl503730c
Copyright © 2014 American Chemical Society
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    Abstract

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    Exploring the chemical reactivity of different atomic sites on crystal surface and controlling their exposures are important for catalysis and renewable energy storage. Here, we use two-dimensional layered molybdenum disulfide (MoS2) to demonstrate the electrochemical selectivity of edge versus terrace sites for Li–S batteries and hydrogen evolution reaction (HER). Lithium sulfide (Li2S) nanoparticles decorates along the edges of the MoS2 nanosheet versus terrace, confirming the strong binding energies between Li2S and the edge sites and guiding the improved electrode design for Li–S batteries. We also provided clear comparison of HER activity between edge and terrace sites of MoS2 beyond the previous theoretical prediction and experimental proof.

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