ACS Publications. Most Trusted. Most Cited. Most Read

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Nano Lett. 2015, 15, 5, 2910-2916
RETURN TO ISSUEPREVLetterNEXT

Polymer Nanofiber-Guided Uniform Lithium Deposition for Battery Electrodes

View Author Information
† †Department of Materials Science and Engineering, ‡Department of Chemical Engineering, and §Department of Physics, Stanford University, Stanford, California 94305, United States
∥ Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, United States
*E-mail: [email protected]
Cite this: Nano Lett. 2015, 15, 5, 2910–2916
Publication Date (Web):March 30, 2015
https://doi.org/10.1021/nl5046318
Copyright © 2015 American Chemical Society
Request reuse permissions

    Article Views

    9737

    Altmetric

    -

    Citations

    474
    LEARN ABOUT THESE METRICS
    Read OnlinePDF (6 MB)
    Get e-Alerts
    Supporting Info (1)»
    SUBJECTS:

    Abstract

    Abstract Image

    Lithium metal is one of the most promising candidates as an anode material for next-generation energy storage systems due to its highest specific capacity (3860 mAh/g) and lowest redox potential of all. The uncontrolled lithium dendrite growth that causes a poor cycling performance and serious safety hazards, however, presents a significant challenge for the realization of lithium metal-based batteries. Here, we demonstrate a novel electrode design by placing a three-dimensional (3D) oxidized polyacrylonitrile nanofiber network on top of the current collector. The polymer fiber with polar surface functional groups could guide the lithium ions to form uniform lithium metal deposits confined on the polymer fiber surface and in the 3D polymer layer. We showed stable cycling of lithium metal anode with an average Coulombic efficiency of 97.4% over 120 cycles in ether-based electrolyte at a current density of 3 mA/cm2 for a total of 1 mAh/cm2 of lithium.

    KEYWORDS:

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    Schematics of the fabrication processes of the polymer nanofiber, SEM characterization and cycling performance of Li deposition on Cu-OxPAN* electrode, statistics of the polymer fiber diameter distribution, SEM characterization and cycling performance of Li deposition on Cu-OxPAN electrode and Cu-PP electrode, high areal capacity electrochemical cycling, statistics of the oxidized PAN fiber porosity distribution, electrochemical testing in electrolyte without LiNO3, XPS study of oxidized PAN fiber before and after cycling, experimental details of polymer fiber fabrication, characterizations, electrochemical testing, and volumetric specific capacity calculation. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 474 publications.

    1. Nai-Lu Shen, He Liu, Wen-Bo Tang, Zaichun Liu, Tao Wang, Yuan Ma, Yiren Zhong, Jiarui He, Zhi Zhu, Yuping Wu, Xin-Bing Cheng. Gradient Host for Bottom-Up Deposition of Lithium Metal Anode. Industrial & Engineering Chemistry Research 2023, 62 (38) , 15360-15377. https://doi.org/10.1021/acs.iecr.3c02202
    2. Chao Li, Zhenye Liang, Zizhao Li, Daofan Cao, Daxian Zuo, Jian Chang, Jun Wang, Yonghong Deng, Ke Liu, Xian Kong, Jiayu Wan. Self-Assembly Monolayer Inspired Stable Artificial Solid Electrolyte Interphase Design for Next-Generation Lithium Metal Batteries. Nano Letters 2023, 23 (9) , 4014-4022. https://doi.org/10.1021/acs.nanolett.3c00783
    3. Naijie Wang, Di Qin, Qiu Sun, Xiangqun Chen, Ying Song, Tiezhu Xin. Single-Ion Conducting Polyurethane-Ester Solid Polymer Electrolyte Membrane toward Lithium Metal Batteries. ACS Applied Polymer Materials 2023, 5 (4) , 2607-2616. https://doi.org/10.1021/acsapm.2c02197
    4. Di Yang, Xiaoyu Wu, Li He, Zhihui Sun, Hainan Zhao, Meiling Wang, Yizhan Wang, Yingjin Wei. Physicochemical Synergistic Separator Coating Induces Uniform and Rapid Deposition of Li and Zn Ions. Nano Letters 2023, 23 (1) , 336-343. https://doi.org/10.1021/acs.nanolett.2c04613
    5. Xue Liu, Jian Liu, Guo-Ran Li, Sheng Liu, Xue-Ping Gao. Dimensionally Stable Composite Li Electrode with Cu Skeleton and Lithophilic Li–Mg Alloy Microstructure. ACS Applied Materials & Interfaces 2022, 14 (51) , 56801-56807. https://doi.org/10.1021/acsami.2c17084
    6. Yun Zhao, Jianhua Yan, Jianyong Yu, Bin Ding. Advances in Nanofibrous Materials for Stable Lithium-Metal Anodes. ACS Nano 2022, 16 (11) , 17891-17910. https://doi.org/10.1021/acsnano.2c09037
    7. Hao Peng, Hui Sun. Electrochemical Modified Solid Electrolyte with a Li–Al–O Interface Layer for Improved Room-Temperature Rate Performance of Solid-State Lithium Batteries. ACS Applied Energy Materials 2022, 5 (6) , 7115-7123. https://doi.org/10.1021/acsaem.2c00705
    8. Junbeom Cho, Oh B. Chae, Yu Jin Hong, San Moon, Do Youb Kim, Sungho Choi, Jungdon Suk, Issam Gereige, Mihye Wu, Hee-Tae Jung. Sea-Urchin-like Hierarchical Carbon Spheres with Conical Pores as a Three-Dimensional Lithium Host for Dendrite Suppression. ACS Applied Energy Materials 2022, 5 (5) , 5919-5927. https://doi.org/10.1021/acsaem.2c00277
    9. Trina Dhara, Udita Uday Ghosh, Asmita Ghosh, Bairav Sabarish Vishnugopi, Partha P. Mukherjee, Sunando DasGupta. Mechanistic Underpinnings of Morphology Transition in Electrodeposition under the Application of Pulsatile Potential. Langmuir 2022, 38 (16) , 4879-4886. https://doi.org/10.1021/acs.langmuir.2c00066
    10. Woo-Bin Jung, Oh B. Chae, Minki Kim, Yesol Kim, Yu Jin Hong, Ju Ye Kim, Sungho Choi, Do Youb Kim, San Moon, Jungdon Suk, Yongku Kang, Mihye Wu, Hee-Tae Jung. Effect of Highly Periodic Au Nanopatterns on Dendrite Suppression in Lithium Metal Batteries. ACS Applied Materials & Interfaces 2021, 13 (51) , 60978-60986. https://doi.org/10.1021/acsami.1c15196
    11. Riyul Kim, Jinkwan Jung, Ju-Hyuk Lee, Soohyun Kim, Jiyun Heo, Kyungjae Shin, Junhyuk Kim, Hee-Tak Kim. Modulated Zn Deposition by Glass Fiber Interlayers for Enhanced Cycling Stability of Zn–Br Redox Flow Batteries. ACS Sustainable Chemistry & Engineering 2021, 9 (36) , 12242-12251. https://doi.org/10.1021/acssuschemeng.1c03796
    12. Lina Wang, Guangfu Luo. Atomistic Mechanism and Long-Term Stability of Using Chlorinated Graphdiyne Film to Reduce Lithium Dendrites in Rechargeable Lithium Metal Batteries. Nano Letters 2021, 21 (17) , 7284-7290. https://doi.org/10.1021/acs.nanolett.1c02429
    13. Yongchao Liu, Dian Gao, Hongfa Xiang, Xuyong Feng, Yan Yu. Research Progress on Copper-Based Current Collector for Lithium Metal Batteries. Energy & Fuels 2021, 35 (16) , 12921-12937. https://doi.org/10.1021/acs.energyfuels.1c02008
    14. Yun Lu, Yutong Lu, Chengbin Jin, Runan Gao, Bo Liu, Yuxiang Huang, Yanglun Yu, Jun Ren, Yulin Deng, Xinyong Tao, Jianxiong Lyu. Natural Wood Structure Inspires Practical Lithium–Metal Batteries. ACS Energy Letters 2021, 6 (6) , 2103-2110. https://doi.org/10.1021/acsenergylett.1c00629
    15. Peichao Zou, Yiming Sui, Houchao Zhan, Chunyang Wang, Huolin L. Xin, Hui-Ming Cheng, Feiyu Kang, Cheng Yang. Polymorph Evolution Mechanisms and Regulation Strategies of Lithium Metal Anode under Multiphysical Fields. Chemical Reviews 2021, 121 (10) , 5986-6056. https://doi.org/10.1021/acs.chemrev.0c01100
    16. Saebom Ryu, Toshinori Sugimoto, Jaemin Kim, Kiho Park, Dongmin Im, Yong-Gun Lee, Jang Wook Choi. Synergistic Composite Coating for Separators in Lithium Metal Batteries. ACS Applied Energy Materials 2021, 4 (5) , 5237-5245. https://doi.org/10.1021/acsaem.1c00758
    17. Ji-Yong Eom, Seung Hyun Choi, Ji-Hoon Kang, Gwang Hyeon Eom, Janghyuk Moon, Min-Sik Park. Rational Design of a 3D Li-Metal Electrode for High-Energy Lithium Batteries. ACS Applied Energy Materials 2021, 4 (2) , 1936-1941. https://doi.org/10.1021/acsaem.0c03042
    18. Baozhi Yu, Ye Fan, Srikanth Mateti, Donggun Kim, Chen Zhao, Shengguo Lu, Xin Liu, Qiangzhou Rong, Tao Tao, Khagesh Kumar Tanwar, Xin Tan, Sean C. Smith, Ying Ian Chen. An Ultra-Long-Life Flexible Lithium–Sulfur Battery with Lithium Cloth Anode and Polysulfone-Functionalized Separator. ACS Nano 2021, 15 (1) , 1358-1369. https://doi.org/10.1021/acsnano.0c08627
    19. Dazhe Li, Hui Wang, Longbo Luo, Jiadeng Zhu, Junfeng Li, Pengqing Liu, Yuanyuan Yu, Mengjin Jiang. Electrospun Separator Based on Sulfonated Polyoxadiazole with Outstanding Thermal Stability and Electrochemical Properties for Lithium-Ion Batteries. ACS Applied Energy Materials 2021, 4 (1) , 879-887. https://doi.org/10.1021/acsaem.0c02767
    20. Tao Ma, Rui Wang, Song Jin, Shibing Zheng, Lin Li, Jinqiang Shi, Yichao Cai, Jing Liang, Zhanliang Tao. Functionalized Boron Nitride-Based Modification Layer as Ion Regulator Toward Stable Lithium Anode at High Current Densities. ACS Applied Materials & Interfaces 2021, 13 (1) , 391-399. https://doi.org/10.1021/acsami.0c16354
    21. Ji-Guang Zhang, Wu Xu, Jie Xiao, Xia Cao, Jun Liu. Lithium Metal Anodes with Nonaqueous Electrolytes. Chemical Reviews 2020, 120 (24) , 13312-13348. https://doi.org/10.1021/acs.chemrev.0c00275
    22. Gang Huang, Jin Wang, Xinbo Zhang. Electrode Protection in High-Efficiency Li–O2 Batteries. ACS Central Science 2020, 6 (12) , 2136-2148. https://doi.org/10.1021/acscentsci.0c01069
    23. Jinqiang Shi, Mingyue Ma, Rui Wang, Junquan Bao, Zhanliang Tao. Ion Redistribution and Rapid-Transfer Composite Protective Layer for Stable Lithium Metal Anodes. ACS Applied Energy Materials 2020, 3 (8) , 7257-7264. https://doi.org/10.1021/acsaem.0c00020
    24. Chihyun Hwang, Woo-Jin Song, Gyujin Song, Yutong Wu, Sangyeop Lee, Hye Bin Son, Jonghak Kim, Nian Liu, Soojin Park, Hyun-Kon Song. A Three-Dimensional Nano-web Scaffold of Ferroelectric Beta-PVDF Fibers for Lithium Metal Plating and Stripping. ACS Applied Materials & Interfaces 2020, 12 (26) , 29235-29241. https://doi.org/10.1021/acsami.0c05065
    25. Xiaofeng Song, Yanan Zhang, Youwen Ye, Zefei Liu, Fei Cheng, Huanrong Li. A Durable Gel Polymer Electrolyte with Excellent Cycling and Rate Performance for Enhanced Lithium Storage. ACS Applied Energy Materials 2020, 3 (5) , 4906-4913. https://doi.org/10.1021/acsaem.0c00485
    26. Juran Noh, Jian Tan, Digvijay Rajendra Yadav, Peng Wu, Kelvin Y. Xie, Choongho Yu. Understanding of Lithium Insertion into 3D Porous Carbon Scaffolds with Hybridized Lithiophobic and Lithiophilic Surfaces by In-Operando Study. Nano Letters 2020, 20 (5) , 3681-3687. https://doi.org/10.1021/acs.nanolett.0c00618
    27. Xi Chen, Mingwei Shang, Junjie Niu. Inter-layer-calated Thin Li Metal Electrode with Improved Battery Capacity Retention and Dendrite Suppression. Nano Letters 2020, 20 (4) , 2639-2646. https://doi.org/10.1021/acs.nanolett.0c00201
    28. Xiaoyu Luan, Chenggang Wang, Chunsheng Wang, Xin Gu, Jian Yang, Yitai Qian. Stable Lithium Deposition Enabled by an Acid-Treated g-C3N4 Interface Layer for a Lithium Metal Anode. ACS Applied Materials & Interfaces 2020, 12 (9) , 11265-11272. https://doi.org/10.1021/acsami.9b23520
    29. Joshua P. Pender, Gaurav Jha, Duck Hyun Youn, Joshua M. Ziegler, Ilektra Andoni, Eric J. Choi, Adam Heller, Bruce S. Dunn, Paul S. Weiss, Reginald M. Penner, C. Buddie Mullins. Electrode Degradation in Lithium-Ion Batteries. ACS Nano 2020, 14 (2) , 1243-1295. https://doi.org/10.1021/acsnano.9b04365
    30. Mengxue Chen, Liwei Cheng, Jiangchun Chen, Yan Zhou, Jiandong Liang, Shuai Dong, Mo Chen, Xiaotian Wang, Hua Wang. Facile and Scalable Modification of a Cu Current Collector toward Uniform Li Deposition of the Li Metal Anode. ACS Applied Materials & Interfaces 2020, 12 (3) , 3681-3687. https://doi.org/10.1021/acsami.9b20777
    31. Lijuan Chen, Aijing Lv, Feng Guo, Mingyong Wang, Shuqiang Jiao. Solid–Liquid Coexisting LiNO3 Electrolyte for Extremely Stable Lithium Metal Anodes on a Bare Cu Foil. ACS Sustainable Chemistry & Engineering 2020, 8 (1) , 706-713. https://doi.org/10.1021/acssuschemeng.9b06624
    32. Xing Gao, Ying Du, Siwu Li, Junwen Zhou, Xiao Feng, Xu Jin, Bo Wang. Synergistic Effects of Inorganic–Organic Protective Layer for Robust Cycling Dendrite-Free Lithium Metal Batteries. ACS Applied Materials & Interfaces 2020, 12 (1) , 844-850. https://doi.org/10.1021/acsami.9b18703
    33. Guangmin Zhou, Lin Xu, Guangwu Hu, Liqiang Mai, Yi Cui. Nanowires for Electrochemical Energy Storage. Chemical Reviews 2019, 119 (20) , 11042-11109. https://doi.org/10.1021/acs.chemrev.9b00326
    34. Xian Huang, Xiaoyu Feng, Ben Zhang, Liao Zhang, Shichang Zhang, Biao Gao, Paul K. Chu, Kaifu Huo. Lithiated NiCo2O4 Nanorods Anchored on 3D Nickel Foam Enable Homogeneous Li Plating/Stripping for High-Power Dendrite-Free Lithium Metal Anode. ACS Applied Materials & Interfaces 2019, 11 (35) , 31824-31831. https://doi.org/10.1021/acsami.9b08438
    35. Woo Jin Hyun, Ana C. M. de Moraes, Jin-Myoung Lim, Julia R. Downing, Kyu-Young Park, Mark Tian Zhi Tan, Mark C. Hersam. High-Modulus Hexagonal Boron Nitride Nanoplatelet Gel Electrolytes for Solid-State Rechargeable Lithium-Ion Batteries. ACS Nano 2019, 13 (8) , 9664-9672. https://doi.org/10.1021/acsnano.9b04989
    36. Yuanming Liu, Shaoqiong Zhang, Xianying Qin, Feiyu Kang, Guohua Chen, Baohua Li. In-Plane Highly Dispersed Cu2O Nanoparticles for Seeded Lithium Deposition. Nano Letters 2019, 19 (7) , 4601-4607. https://doi.org/10.1021/acs.nanolett.9b01567
    37. Ming Liu, Zhu Cheng, Kun Qian, Tomas Verhallen, Chao Wang, Marnix Wagemaker. Efficient Li-Metal Plating/Stripping in Carbonate Electrolytes Using a LiNO3-Gel Polymer Electrolyte, Monitored by Operando Neutron Depth Profiling. Chemistry of Materials 2019, 31 (12) , 4564-4574. https://doi.org/10.1021/acs.chemmater.9b01325
    38. Tiancun Liu, Jiulin Hu, Chilin Li, Yong Wang. Unusual Conformal Li Plating on Alloyable Nanofiber Frameworks to Enable Dendrite Suppression of Li Metal Anode. ACS Applied Energy Materials 2019, 2 (6) , 4379-4388. https://doi.org/10.1021/acsaem.9b00573
    39. Jiajia Xue, Tong Wu, Yunqian Dai, Younan Xia. Electrospinning and Electrospun Nanofibers: Methods, Materials, and Applications. Chemical Reviews 2019, 119 (8) , 5298-5415. https://doi.org/10.1021/acs.chemrev.8b00593
    40. Tuo Kang, Yalong Wang, Feng Guo, Chenghao Liu, Jianghui Zhao, Jin Yang, Hongzhen Lin, Yejun Qiu, Yanbin Shen, Wei Lu, Liwei Chen. Self-Assembled Monolayer Enables Slurry-Coating of Li Anode. ACS Central Science 2019, 5 (3) , 468-476. https://doi.org/10.1021/acscentsci.8b00845
    41. Wooseok Go, Min-Ho Kim, Jehee Park, Chek Hai Lim, Sang Hoon Joo, Youngsik Kim, Hyun-Wook Lee. Nanocrevasse-Rich Carbon Fibers for Stable Lithium and Sodium Metal Anodes. Nano Letters 2019, 19 (3) , 1504-1511. https://doi.org/10.1021/acs.nanolett.8b04106
    42. Hansen Wang, Yuzhang Li, Yanbin Li, Yayuan Liu, Dingchang Lin, Cheng Zhu, Guangxu Chen, Ankun Yang, Kai Yan, Hao Chen, Yangying Zhu, Jun Li, Jin Xie, Jinwei Xu, Zewen Zhang, Rafael Vilá, Allen Pei, Kecheng Wang, Yi Cui. Wrinkled Graphene Cages as Hosts for High-Capacity Li Metal Anodes Shown by Cryogenic Electron Microscopy. Nano Letters 2019, 19 (2) , 1326-1335. https://doi.org/10.1021/acs.nanolett.8b04906
    43. Yifang Zhang, Yiren Zhong, Qiuwei Shi, Shuquan Liang, Hailiang Wang. Cycling and Failing of Lithium Metal Anodes in Carbonate Electrolyte. The Journal of Physical Chemistry C 2018, 122 (37) , 21462-21467. https://doi.org/10.1021/acs.jpcc.8b06650
    44. Quan Li, Hongyi Pan, Wenjun Li, Yi Wang, Junyang Wang, Jieyun Zheng, Xiqian Yu, Hong Li, Liquan Chen. Homogeneous Interface Conductivity for Lithium Dendrite-Free Anode. ACS Energy Letters 2018, 3 (9) , 2259-2266. https://doi.org/10.1021/acsenergylett.8b01244
    45. Zhaohui Wang, Ruijun Pan, Rui Sun, Kristina Edström, Maria Strømme, Leif Nyholm. Nanocellulose Structured Paper-Based Lithium Metal Batteries. ACS Applied Energy Materials 2018, 1 (8) , 4341-4350. https://doi.org/10.1021/acsaem.8b00961
    46. Yang Wang, Chuan-Fu Lin, Jiancun Rao, Karen Gaskell, Gary Rubloff, Sang Bok Lee. Electrochemically Controlled Solid Electrolyte Interphase Layers Enable Superior Li–S Batteries. ACS Applied Materials & Interfaces 2018, 10 (29) , 24554-24563. https://doi.org/10.1021/acsami.8b07248
    47. John Joseph, Aarya G. Krishnan, Aleena M. Cherian, Balasubramoniam Rajagopalan, Rajesh Jose, Praveen Varma, Vijayakumar Maniyal, Sivanarayanan Balakrishnan, Shantikumar V. Nair, Deepthy Menon. Transforming Nanofibers into Woven Nanotextiles for Vascular Application. ACS Applied Materials & Interfaces 2018, 10 (23) , 19449-19458. https://doi.org/10.1021/acsami.8b05096
    48. Huibo Yan, Chao Shen, Kai Yuan, Kun Zhang, Xingrui Liu, Jian-Gan Wang, Keyu Xie. Hosting Ultrahigh Areal Capacity and Dendrite-free Lithium via Porous Scaffold. ACS Sustainable Chemistry & Engineering 2018, 6 (4) , 4776-4783. https://doi.org/10.1021/acssuschemeng.7b03910
    49. Sheng S. Zhang. Problem, Status, and Possible Solutions for Lithium Metal Anode of Rechargeable Batteries. ACS Applied Energy Materials 2018, 1 (3) , 910-920. https://doi.org/10.1021/acsaem.8b00055
    50. Nan Li, Wenfei Wei, Keyu Xie, Jinwang Tan, Lin Zhang, Xiaodong Luo, Kai Yuan, Qiang Song, Hejun Li, Chao Shen, Emily M. Ryan, Ling Liu, Bingqing Wei. Suppressing Dendritic Lithium Formation Using Porous Media in Lithium Metal-Based Batteries. Nano Letters 2018, 18 (3) , 2067-2073. https://doi.org/10.1021/acs.nanolett.8b00183
    51. Olha Mashtalir, Minh Nguyen, Emilie Bodoin, Larry Swonger, and Stephen P. O’Brien . High-Purity Lithium Metal Films from Aqueous Mineral Solutions. ACS Omega 2018, 3 (1) , 181-187. https://doi.org/10.1021/acsomega.7b01501
    52. Tong-Tong Zuo, Ya-Xia Yin, Shu-Hua Wang, Peng-Fei Wang, Xinan Yang, Jian Liu, Chun-Peng Yang, and Yu-Guo Guo . Trapping Lithium into Hollow Silica Microspheres with a Carbon Nanotube Core for Dendrite-Free Lithium Metal Anodes. Nano Letters 2018, 18 (1) , 297-301. https://doi.org/10.1021/acs.nanolett.7b04136
    53. Di Zhang, Bin Li, Shuai Wang, and Shubin Yang . Simultaneous Formation of Artificial SEI Film and 3D Host for Stable Metallic Sodium Anodes. ACS Applied Materials & Interfaces 2017, 9 (46) , 40265-40272. https://doi.org/10.1021/acsami.7b12568
    54. Xin-Bing Cheng, Rui Zhang, Chen-Zi Zhao, and Qiang Zhang . Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review. Chemical Reviews 2017, 117 (15) , 10403-10473. https://doi.org/10.1021/acs.chemrev.7b00115
    55. Yong-Gun Lee, Saebom Ryu, Toshinori Sugimoto, Taehwan Yu, Won-seok Chang, Yooseong Yang, Changhoon Jung, Jaesung Woo, Sung Gyu Kang, Heung Nam Han, Seok-Gwang Doo, Yunil Hwang, Hyuk Chang, Jae-Myung Lee, and Jeong-Yun Sun . Dendrite-Free Lithium Deposition for Lithium Metal Anodes with Interconnected Microsphere Protection. Chemistry of Materials 2017, 29 (14) , 5906-5914. https://doi.org/10.1021/acs.chemmater.7b01304
    56. Dingchang Lin, Yayuan Liu, Wei Chen, Guangmin Zhou, Kai Liu, Bruce Dunn, and Yi Cui . Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon. Nano Letters 2017, 17 (6) , 3731-3737. https://doi.org/10.1021/acs.nanolett.7b01020
    57. Zhenglin Hu, Shu Zhang, Shanmu Dong, Wenjun Li, Hong Li, Guanglei Cui, and Liquan Chen . Poly(ethyl α-cyanoacrylate)-Based Artificial Solid Electrolyte Interphase Layer for Enhanced Interface Stability of Li Metal Anodes. Chemistry of Materials 2017, 29 (11) , 4682-4689. https://doi.org/10.1021/acs.chemmater.7b00091
    58. Boyang Liu, Yunhui Gong, Kun Fu, Xiaogang Han, Yonggang Yao, Glenn Pastel, Chunpeng Yang, Hua Xie, Eric D. Wachsman, and Liangbing Hu . Garnet Solid Electrolyte Protected Li-Metal Batteries. ACS Applied Materials & Interfaces 2017, 9 (22) , 18809-18815. https://doi.org/10.1021/acsami.7b03887
    59. Huan Ye, Sen Xin, Ya-Xia Yin, Jin-Yi Li, Yu-Guo Guo, and Li-Jun Wan . Stable Li Plating/Stripping Electrochemistry Realized by a Hybrid Li Reservoir in Spherical Carbon Granules with 3D Conducting Skeletons. Journal of the American Chemical Society 2017, 139 (16) , 5916-5922. https://doi.org/10.1021/jacs.7b01763
    60. Shoichi Matsuda, Yoshimi Kubo, Kohei Uosaki, and Shuji Nakanishi . Insulative Microfiber 3D Matrix as a Host Material Minimizing Volume Change of the Anode of Li Metal Batteries. ACS Energy Letters 2017, 2 (4) , 924-929. https://doi.org/10.1021/acsenergylett.7b00149
    61. Jialiang Lang, Jianan Song, Longhao Qi, Yuzi Luo, Xinyi Luo, and Hui Wu . Uniform Lithium Deposition Induced by Polyacrylonitrile Submicron Fiber Array for Stable Lithium Metal Anode. ACS Applied Materials & Interfaces 2017, 9 (12) , 10360-10365. https://doi.org/10.1021/acsami.7b00181
    62. Lei Fan, Weidong Zhang, Shoupu Zhu, and Yingying Lu . Enhanced Lithium Storage Capability in Li-Ion Batteries Using Porous 3D Co3O4 Nanofiber Anodes. Industrial & Engineering Chemistry Research 2017, 56 (8) , 2046-2053. https://doi.org/10.1021/acs.iecr.7b00222
    63. Allen Pei, Guangyuan Zheng, Feifei Shi, Yuzhang Li, and Yi Cui . Nanoscale Nucleation and Growth of Electrodeposited Lithium Metal. Nano Letters 2017, 17 (2) , 1132-1139. https://doi.org/10.1021/acs.nanolett.6b04755
    64. Adam P. Cohn, Nitin Muralidharan, Rachel Carter, Keith Share, and Cary L. Pint . Anode-Free Sodium Battery through in Situ Plating of Sodium Metal. Nano Letters 2017, 17 (2) , 1296-1301. https://doi.org/10.1021/acs.nanolett.6b05174
    65. Keyu Xie, Kai Yuan, Kun Zhang, Chao Shen, Weibang Lv, Xingrui Liu, Jian-Gan Wang, and Bingqing Wei . Dual Functionalities of Carbon Nanotube Films for Dendrite-Free and High Energy–High Power Lithium–Sulfur Batteries. ACS Applied Materials & Interfaces 2017, 9 (5) , 4605-4613. https://doi.org/10.1021/acsami.6b14039
    66. Le Shi, Ao Xu, and Tianshou Zhao . First-Principles Investigations of the Working Mechanism of 2D h-BN as an Interfacial Layer for the Anode of Lithium Metal Batteries. ACS Applied Materials & Interfaces 2017, 9 (2) , 1987-1994. https://doi.org/10.1021/acsami.6b14560
    67. Fu Sun, Riko Moroni, Kang Dong, Henning Markötter, Dong Zhou, André Hilger, Lukas Zielke, Roland Zengerle, Simon Thiele, John Banhart, and Ingo Manke . Study of the Mechanisms of Internal Short Circuit in a Li/Li Cell by Synchrotron X-ray Phase Contrast Tomography. ACS Energy Letters 2017, 2 (1) , 94-104. https://doi.org/10.1021/acsenergylett.6b00589
    68. Zhenggang Zhang, Xiaoyue Xu, Shuwei Wang, Zhe Peng, Meng Liu, Jingjing Zhou, Cai Shen, and Deyu Wang . Li2O-Reinforced Cu Nanoclusters as Porous Structure for Dendrite-Free and Long-Lifespan Lithium Metal Anode. ACS Applied Materials & Interfaces 2016, 8 (40) , 26801-26808. https://doi.org/10.1021/acsami.6b08775
    69. Hee-Kook Kang, Sang-Gil Woo, Jae-Hun Kim, Ji-Sang Yu, Seong-Rae Lee, and Young-Jun Kim . Few-Layer Graphene Island Seeding for Dendrite-Free Li Metal Electrodes. ACS Applied Materials & Interfaces 2016, 8 (40) , 26895-26901. https://doi.org/10.1021/acsami.6b09757
    70. Keyu Xie, Wenfei Wei, Kai Yuan, Wei Lu, Min Guo, Zhihua Li, Qiang Song, Xingrui Liu, Jian-Gan Wang, and Chao Shen . Toward Dendrite-Free Lithium Deposition via Structural and Interfacial Synergistic Effects of 3D Graphene@Ni Scaffold. ACS Applied Materials & Interfaces 2016, 8 (39) , 26091-26097. https://doi.org/10.1021/acsami.6b09031
    71. Byeong-Chul Yu, Kyusung Park, Ji-Hoon Jang, and John B. Goodenough . Cellulose-Based Porous Membrane for Suppressing Li Dendrite Formation in Lithium–Sulfur Battery. ACS Energy Letters 2016, 1 (3) , 633-637. https://doi.org/10.1021/acsenergylett.6b00209
    72. Fu Sun, Lukas Zielke, Henning Markötter, André Hilger, Dong Zhou, Riko Moroni, Roland Zengerle, Simon Thiele, John Banhart, and Ingo Manke . Morphological Evolution of Electrochemically Plated/Stripped Lithium Microstructures Investigated by Synchrotron X-ray Phase Contrast Tomography. ACS Nano 2016, 10 (8) , 7990-7997. https://doi.org/10.1021/acsnano.6b03939
    73. Lei-Lei Lu, Jin Ge, Jun-Nan Yang, Si-Ming Chen, Hong-Bin Yao, Fei Zhou, and Shu-Hong Yu . Free-Standing Copper Nanowire Network Current Collector for Improving Lithium Anode Performance. Nano Letters 2016, 16 (7) , 4431-4437. https://doi.org/10.1021/acs.nanolett.6b01581
    74. Snehashis Choudhury, Akanksha Agrawal, Shuya Wei, Emily Jeng, and Lynden A. Archer . Hybrid Hairy Nanoparticle Electrolytes Stabilizing Lithium Metal Batteries. Chemistry of Materials 2016, 28 (7) , 2147-2157. https://doi.org/10.1021/acs.chemmater.6b00029
    75. Fan Xia, Sunsang Kwon, Won Woo Lee, Zhiming Liu, Suhan Kim, Taeseup Song, Kyoung Jin Choi, Ungyu Paik, and Won Il Park . Graphene as an Interfacial Layer for Improving Cycling Performance of Si Nanowires in Lithium-Ion Batteries. Nano Letters 2015, 15 (10) , 6658-6664. https://doi.org/10.1021/acs.nanolett.5b02482
    76. Xin-Bing Cheng, Hong-Jie Peng, Jia-Qi Huang, Rui Zhang, Chen-Zi Zhao, and Qiang Zhang . Dual-Phase Lithium Metal Anode Containing a Polysulfide-Induced Solid Electrolyte Interphase and Nanostructured Graphene Framework for Lithium–Sulfur Batteries. ACS Nano 2015, 9 (6) , 6373-6382. https://doi.org/10.1021/acsnano.5b01990
    77. Fangfang Shang, Zhuo Li, Hendao Quan, Xiaoxun Ma. The multifunctional 2-Trifluoroacetyl furan electrolyte additive for suppressing lithium dendrite growth. Fuel 2024, 357 , 129931. https://doi.org/10.1016/j.fuel.2023.129931
    78. Qian Wang, Tiantian Lu, Yuanbin Xiao, Jianyang Wu, Lixiang Guan, Lifeng Hou, Huayun Du, Huan Wei, Xiaoda Liu, Chengkai Yang, Yinghui Wei, Henghui Zhou, Yan Yu. Leap of Li Metal Anodes from Coin Cells to Pouch Cells: Challenges and Progress. Electrochemical Energy Reviews 2023, 6 (1) https://doi.org/10.1007/s41918-023-00185-7
    79. Hassan Raza, Songyan Bai, Junye Cheng, Soumyadip Majumder, He Zhu, Qi Liu, Guangping Zheng, Xifei Li, Guohua Chen. Li-S Batteries: Challenges, Achievements and Opportunities. Electrochemical Energy Reviews 2023, 6 (1) https://doi.org/10.1007/s41918-023-00188-4
    80. Jun-Fan Ding, Yu-Tong Zhang, Rui Xu, Rui Zhang, Ye Xiao, Shuo Zhang, Chen-Xi Bi, Cheng Tang, Rong Xiang, Ho Seok Park, Qiang Zhang, Jia-Qi Huang. Review on lithium metal anodes towards high energy density batteries. Green Energy & Environment 2023, 8 (6) , 1509-1530. https://doi.org/10.1016/j.gee.2022.08.002
    81. Ziqin Liu, Xiaowei Wu, Pu Hu, Chaoqun Shang. The shield-like nano-sized Si3N4 derivatives to defend against the attack of lithium dendrites. Journal of Colloid and Interface Science 2023, 652 , 50-56. https://doi.org/10.1016/j.jcis.2023.08.080
    82. Yuanyue He, Libo Song, Zhendong Li, Xiayin Yao, Zhe Peng. Hosting Li0 in an activated lithiophilic polymer matrix with electrodeposition regulating spaces for stable lithium metal anodes. Nano Energy 2023, 118 , 109027. https://doi.org/10.1016/j.nanoen.2023.109027
    83. Xiaoyi Hu, Kangli Liu, Shijie Zhang, Guosheng Shao, S. Ravi P. Silva, Peng Zhang. A functional gel polymer electrolyte based on PVDF-HFP/gelatin toward dendrite-free lithium metal batteries. Nano Research 2023, 5 https://doi.org/10.1007/s12274-023-6230-0
    84. Gang Su, Xin Zhang, Min Xiao, Shuanjin Wang, Sheng Huang, Dongmei Han, Yuezhong Meng. Polymeric Electrolytes for Solid‐state Lithium Ion Batteries: Structure Design, Electrochemical Properties and Cell Performances. ChemSusChem 2023, 414 https://doi.org/10.1002/cssc.202300293
    85. Xiaoyu Feng, Xian Huang, Biao Gao. A Three‐Dimensional (3D) Framework of Freestanding Vanadium Nitride Nanowires for Dendrite‐Free and Long Life‐Span Lithium Metal Anodes. Chemistry – A European Journal 2023, 451 https://doi.org/10.1002/chem.202302773
    86. Zicheng Wang, Jianguo Song, Yuan Tian, Cheng Wang. A multifunctional interlayer activated by lithiophilic electrospun Ag nanowires/polyvinylpyrrolidone nanofibers for efficient lithium storage. Chemical Communications 2023, 59 (86) , 12879-12882. https://doi.org/10.1039/D3CC04330D
    87. Jae Hun Choi, Jae Wook Kang, Hye Young Koo, Yun Chan Kang, . Lithiophilic and Conductive CuO-Cu2O-Cu Microspheres with Controlled Void Structure via Spray Pyrolysis for Improved Lithium Metal Anode Performance. International Journal of Energy Research 2023, 2023 , 1-15. https://doi.org/10.1155/2023/2200257
    88. Paul Choi, Bharathy Parimalam, Yubai Li, Shawn Litster. Operando ultra-high-resolution X-ray microscopy of lithium anodes with separator interactions. Journal of Power Sources 2023, 581 , 233468. https://doi.org/10.1016/j.jpowsour.2023.233468
    89. Jian Song, Yuanyuan Jiang, Yizhong Lu, Yundong Cao, Yuxi Zhang, Linlin Fan, Hong Liu, Guanggang Gao. A Forceful “Dendrite‐Killer” of Polyoxomolybdate with Reusability Effectively Dominating Dendrite‑Free Lithium Metal Anode. Small 2023, 19 (40) https://doi.org/10.1002/smll.202301740
    90. Xin Wang, Hui Liu, Kai Pan, Rui Huang, Xiaoqing Gou, Yujie Qiang. Exploring thermal hazard of lithium-ion batteries by bibliometric analysis. Journal of Energy Storage 2023, 67 , 107578. https://doi.org/10.1016/j.est.2023.107578
    91. Ziping Wang, Mingyang Xin, Shuyuan Xie, Hao Sun, Shuang Yu, Yiqi Gong, Haiming Xie, Yulong Liu. Design of symbiosis 3D framework interface for long-life lithium metal batteries. Journal of Energy Storage 2023, 68 , 107823. https://doi.org/10.1016/j.est.2023.107823
    92. Ju Ye Kim, Oh B. Chae, Gukbo Kim, Woo‐Bin Jung, Sungho Choi, Do Youb Kim, San Moon, Jungdon Suk, Yongku Kang, Mihye Wu, Hee‐Tae Jung. Spatial Control of Lithium Deposition by Controlling the Lithiophilicity with Copper(I) Oxide Boundaries. ENERGY & ENVIRONMENTAL MATERIALS 2023, 6 (5) https://doi.org/10.1002/eem2.12392
    93. Fan Wu, Zhichao He, Li Liu, Shengjie Guan, Fei Wang, Yudong Huang. Hierarchical-structure and high-modulus aramid nanofiber membrane protective layer achieving high-performance lithium metal anode. Chemical Engineering Journal 2023, 471 , 144477. https://doi.org/10.1016/j.cej.2023.144477
    94. Ce Wang, Jiahao Zhu, Yuhong Jin, Jingbing Liu, Hao Wang, Qianqian Zhang. Ion modulation engineering toward stable lithium metal anodes. Materials Horizons 2023, 10 (9) , 3218-3236. https://doi.org/10.1039/D3MH00403A
    95. Shiman He, Jie Wang, Xu Zhang, Weiqin Chu, Shu Zhao, Daping He, Min Zhu, Haijun Yu. Aluminum dendrite suppression by graphite coated anodes of Al-metal batteries. Journal of Materials Chemistry A 2023, 11 (32) , 17020-17026. https://doi.org/10.1039/D3TA02404K
    96. Yanqi Feng, Hui Liu, Qiongqiong Lu. From non-carbon host toward carbon-free lithium-sulfur batteries. Nano Research 2023, 11 https://doi.org/10.1007/s12274-023-5945-y
    97. Yuhang Liu, Yifan Li, Zhuzhu Du, Chen He, Jingxuan Bi, Siyu Li, Wanqing Guan, Hongfang Du, Wei Ai. Integrated Gradient Cu Current Collector Enables Bottom‐Up Li Growth for Li Metal Anodes: Role of Interfacial Structure. Advanced Science 2023, 10 (23) https://doi.org/10.1002/advs.202301288
    98. Zhongzhe Li, Yufang Chen, Xiaoru Yun, Peng Gao, Chunman Zheng, Peitao Xiao. Critical Review of Fluorinated Electrolytes for High‐Performance Lithium Metal Batteries. Advanced Functional Materials 2023, 33 (32) https://doi.org/10.1002/adfm.202300502
    99. Yifan Xu, Ruo Zhao, Lei Gao, Tingsong Gao, Wenjuan Wang, Juncao Bian, Songbai Han, Jinlong Zhu, Qiang Xu, Yusheng Zhao. A fiber-reinforced solid polymer electrolyte by in situ polymerization for stable lithium metal batteries. Nano Research 2023, 16 (7) , 9259-9266. https://doi.org/10.1007/s12274-023-5480-x
    100. Lei Zhao, Fen Ran. Electrolyte-philicity of electrode materials. Chemical Communications 2023, 59 (46) , 6969-6986. https://doi.org/10.1039/D3CC00412K
    Load more citations
    Download PDF

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect