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Enhanced Electrocatalytic Activity of Pt Subnanoclusters on Graphene Nanosheet Surface

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Graduate School of Pure and Applied Science, University of Tsukuba, Tsukuba, Ibaraki 305-8573, Japan, Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology, Umezono 1-1-1, Central 2, Tsukuba, Ibaraki 305-8568, Japan, and Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology, 1-8-31 Midorigaoka, Ikeda 563-8577, Japan
* To whom correspondence should be addressed. (J.N.) Tel. and Fax: +81-29-853-5279. E-mail: [email protected]. (I.H.) Tel. and FAX: +81-29-861-5648; E-mail: [email protected]
†University of Tsukuba.
§Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology.
‡Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology.
Cite this: Nano Lett. 2009, 9, 6, 2255–2259
Publication Date (Web):April 30, 2009
https://doi.org/10.1021/nl900397t
Copyright © 2009 American Chemical Society
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Abstract

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Graphene nanosheet (GNS) gives rise to an extraordinary modification to the properties of Pt cluster electrocatalysts supported on it. The Pt/GNS electrocatalyst revealed an unusually high activity for methanol oxidation reaction compared to Pt/carbon black catalyst. The Pt/GNS electrocatalyst also revealed quite a different characteristic for CO oxidation among the measured catalyst samples. It is found that Pt particles below 0.5 nm in size are formed on GNS, which would acquire the specific electronic structures of Pt, modifying its catalytic activities.

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