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Boron Nitride Nanosheet Coatings with Controllable Water Repellency

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Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1, Tsukuba, Ibaraki 305-0005, Japan,
International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan
Address correspondence to [email protected], [email protected], [email protected]
Cite this: ACS Nano 2011, 5, 8, 6507–6515
Publication Date (Web):July 18, 2011
https://doi.org/10.1021/nn201838w
Copyright © 2011 American Chemical Society
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The growth, structure, and properties of two-dimensional boron nitride (BN) nanostructures synthesized by a thermal chemical vapor deposition method have been systematically investigated. Most of the BN nanosheets (BNNSs) were less than 5 nm in thickness, and their purity was confirmed by X-ray energy dispersive spectroscopy, X-ray photoelectron spectroscopy, electron energy loss spectroscopy, and Raman spectroscopy. The effects of the process variables on the morphology and roughness of the coatings were studied using atomic force microscopy and scanning electron microscopy. A smooth BN coating was obtained at 900 °C, while compact BNNS coatings composed of partially vertically aligned nanosheets could be achieved at 1000 °C and higher temperatures. These nanosheets were mostly separated and exhibited high surface area especially at higher synthesis temperatures. The nonwetting properties of the BNNS coatings were independent of the water pH and were examined by contact angle goniometry. The present results enable a convenient growth of pure BNNS coatings with controllable levels of water repellency, ranging from partial hydrophilicity to superhydrophobicity with contact angles exceeding 150°.

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Chemical composition analysis by EDS and XPS, TEM images and EEL spectrum of the BNNS coatings prepared at 1000 °C, more discussion on Raman spectroscopy results, typical AFM images of the BNNS coatings prepared at 1000 and 1200 °C and their height profile analysis, morphology-related CA test results, self-cleaning efficiency test results, and detailed definitions of surface roughness parameters mentioned in Table 1 of the main text. This material is available free of charge via the Internet at http://pubs.acs.org.

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