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Heterobimetallic Iron−Rhodium Complexes. Synthesis and Characteristics of CpFe(μ-η5:η5-as-indacenediide)RhL2 (L2 = COD, NBD, (ethylene)2)

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    Heterobimetallic Iron−Rhodium Complexes. Synthesis and Characteristics of CpFe(μ-η5:η5-as-indacenediide)RhL2 (L2 = COD, NBD, (ethylene)2)
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    Dipartimento di Chimica Fisica, Università degli Studi di Padova, via Loredan 2, 35131 Padova, Italy, and CNR, Centro di Studio sugli Stati Molecolari Radicalici ed Eccitati, via Loredan 2, 35131 Padova, Italy
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    Organometallics

    Cite this: Organometallics 2002, 21, 13, 2679–2686
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    https://doi.org/10.1021/om020047o
    Published May 22, 2002
    Copyright © 2002 American Chemical Society
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    Abstract

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    The heterobimetallic CpFe(μ-η5: η5-as-indacenediide)RhL2 complexes (L2 = COD (2), NBD (3), (ethylene)2 (4)) have been obtained from metalation of the mononuclear lithium CpFe(η5-as-indacenediide) with [Rh(μ-Cl)L2]2. Mixtures of syn and anti heterobimetallic complexes were formed and fully characterized by 2D NMR spectroscopy. The reactivity at the rhodium center is greatly influenced by the presence of the ferrocenyl moiety. The voltammetric behavior and the optical spectra are in favor of the existence of significant electronic interactions between the two metals.

    Copyright © 2002 American Chemical Society

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    *

     To whom correspondence should be addressed.

    †

     E-mail:  [email protected].

    ‡

     Università degli Studi di Padova.

    §

     Centro di Studio sugli Stati Molecolari Radicalici ed Eccitati.

    ‖

     Present address:  CNR, Istituto di Scienze e Tecnologie Molecolari, Sezione di Padova, Via Marzolo 1, 35131 Padova, Italy.

    Cited By

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    Organometallics

    Cite this: Organometallics 2002, 21, 13, 2679–2686
    Click to copy citationCitation copied!
    https://doi.org/10.1021/om020047o
    Published May 22, 2002
    Copyright © 2002 American Chemical Society
    Request reuse permissions

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