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First Isolation and Structural Characterization of Triarylaluminum−Water and −Methanol Complexes

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    First Isolation and Structural Characterization of Triarylaluminum−Water and −Methanol Complexes
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    Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872
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    Organometallics

    Cite this: Organometallics 2003, 22, 1, 207–210
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    https://doi.org/10.1021/om020834l
    Published December 6, 2002
    Copyright © 2003 American Chemical Society
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    Abstract

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    The structurally characterized (C6F5)3Al·OH2 (1) and (C6F5)3Al·OHCH3 (2) exhibit medium-strong intermolecular and weak intramolecular O−H···FC hydrogen bonds in the solid state. Both complexes have substantial stability in toluene solutions at room temperature, while the spectroscopic data of 1 show strong activation of the weak Brønsted acid H2O by Al(C6F5)3.

    Copyright © 2003 American Chemical Society

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    Tables giving crystallographic data for 1 and 2; these data are also available as CIF files. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Organometallics

    Cite this: Organometallics 2003, 22, 1, 207–210
    Click to copy citationCitation copied!
    https://doi.org/10.1021/om020834l
    Published December 6, 2002
    Copyright © 2003 American Chemical Society
    Request reuse permissions

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