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Synthesis and Reactivity of Cationic Palladium Phosphine Carboxylate Complexes

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    Synthesis and Reactivity of Cationic Palladium Phosphine Carboxylate Complexes
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    Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106, and Promerus LLC, Brecksville, Ohio 44141
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    Organometallics

    Cite this: Organometallics 2005, 24, 17, 4099–4102
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    https://doi.org/10.1021/om050356p
    Published July 12, 2005
    Copyright © 2005 American Chemical Society
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    Abstract

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    Simple routes to two new types of mononuclear cationic palladium phosphine acetate complexes featuring κ1- or κ2-carboxylates have been developed, and the resulting materials have been characterized by single-crystal X-ray diffraction. In acetonitrile the complex [(iPr3P)2Pd(κ2O,O‘-OAc)]+ leads not to the independently prepared trans-[(iPr3P)2Pd(MeCN)(OAc)]+ but to reversible cyclometalation to form [(iPr3P)(MeCN)Pd(κ2C,P-C(Me)2PiPr2)]+.

    Copyright © 2005 American Chemical Society

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    †

     Case Western Reserve University.

    ‡

     Current address:  Department of Chemistry, University of Delhi, Delhi 110 007, India.

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     Promerus LLC.

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    In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

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    Text giving full experimental details for all compounds and X-ray crystallographic files in CIF format for 1a, 2a, and 3b. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cited By

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    This article is cited by 22 publications.

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    Organometallics

    Cite this: Organometallics 2005, 24, 17, 4099–4102
    Click to copy citationCitation copied!
    https://doi.org/10.1021/om050356p
    Published July 12, 2005
    Copyright © 2005 American Chemical Society
    Request reuse permissions

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