Synthesis of an Arylbromosilylene–Platinum Complex by Using a 1,2-Dibromodisilene As a Silylene Source
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† Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan
‡ Kyoto University Pioneering Research Unit for Next Generation, Gokasho, Uji, Kyoto 611-0011, Japan
*E-mail: [email protected]; [email protected]
Abstract
Kinetically stabilized 1,2-dibromodisilene, Bbt(Br)Si═Si(Br)Bbt (Bbt = 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl) (2), was treated with [Pt(PCy3)2] to afford the corresponding arylbromosilylene–Pt complex, Bbt(Br)Si═Pt(PCy3)2 (1), as stable orange crystals. The molecular structure of 1 was elucidated by spectroscopic and X-ray crystallographic analyses. The nature of the Si–Pt bond in 1 was investigated with the aid of DFT calcualtions.
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- Joyce Y. Corey . Reactions of Hydrosilanes with Transition Metal Complexes. Chemical Reviews 2016, 116 (19) , 11291-11435. https://doi.org/10.1021/acs.chemrev.5b00559
- Thibault Troadec, Amparo Prades, Ricardo Rodriguez, Raphael Mirgalet, Antoine Baceiredo, Nathalie Saffon-Merceron, Vicenç Branchadell, and Tsuyoshi Kato . Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst. Inorganic Chemistry 2016, 55 (16) , 8234-8240. https://doi.org/10.1021/acs.inorgchem.6b01505
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- Nora C. Breit, Tibor Szilvási, Tsuyoshi Suzuki, Daniel Gallego, and Shigeyoshi Inoue . From a Zwitterionic Phosphasilene to Base Stabilized Silyliumylidene-Phosphide and Bis(silylene) Complexes. Journal of the American Chemical Society 2013, 135 (47) , 17958-17968. https://doi.org/10.1021/ja409720c
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- Takeaki Iwamoto, Shintaro Ishida. Stable Silylenes and Their Transition Metal Complexes. 2017,,, 361-532. https://doi.org/10.1016/B978-0-12-801981-8.00008-3
- . Organosilicon Compounds. 2017,,https://doi.org/
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- . Organosilicon Compounds. 2017,,https://doi.org/
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- . Organosilicon Compounds. 2017,,https://doi.org/
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- Roland C. Fischer, Jan J. Weigand. Anorganische Chemie 2012. Nachrichten aus der Chemie 2013, 61 (3) , 219-234. https://doi.org/10.1002/nadc.201390083