Synthesis of a Rhodium Carbonyl Phosphaalkenyl–Phosphido Complex: A Phosphorus Congener of Schiff Base Type N,N′-Chelating Monoanionic Ligands
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Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611-0011, Japan
*E-mail for T.S.: [email protected]
Abstract
A monoanionic, bidentate phosphaalkenyl–phosphido ligand was designed, synthesized, and used for the complexation of a rhodium carbonyl fragment. The characterization of the latter revealed delocalized π electrons on the phosphaalkenyl–phosphide moiety. The catalytic activity of this rhodium carbonyl complex has been demonstrated in a hydrosilylation reaction.
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This article is cited by 4 publications.
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