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Isolation and Structural Characterization of a Lewis Base-Free Monolithioferrocene

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Institute for Chemical Research, Kyoto University, Gokasho Uji, Kyoto 611-0011, Japan
Cite this: Organometallics 2014, 33, 22, 6696–6699
Publication Date (Web):October 27, 2014
https://doi.org/10.1021/om500898v
Copyright © 2014 American Chemical Society
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Abstract

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A sterically hindered ferrocenyl lithium derivative was successfully isolated as a stable, crystalline compound without any stabilization by Lewis bases. On the grounds of X-ray crystallography and multinuclear NMR spectroscopy, a dimeric structure was assigned to this monolithioferrocene in the crystalline state and in solution.

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Experimental and computational details as well as and X-ray crystallographic data for 2 and 3. This material is available free of charge via the Internet at http://pubs.acs.org.

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Cited By


This article is cited by 10 publications.

  1. Afrooz Zirakzadeh, Alexander Herlein, Manuela A. Groß, Kurt Mereiter, Yaping Wang, and Walter Weissensteiner . Halide-Mediated Ortho-Deprotonation Reactions Applied to the Synthesis of 1,2- and 1,3-Disubstituted Ferrocene Derivatives. Organometallics 2015, 34 (15) , 3820-3832. https://doi.org/10.1021/acs.organomet.5b00464
  2. Yang Pan, Shogo Morisako, Shinobu Aoyagi, Takahiro Sasamori. Generation of Bis(ferrocenyl)silylenes from Siliranes. Molecules 2020, 25 (24) , 5917. https://doi.org/10.3390/molecules25245917
  3. Takahiro Sasamori. Ferrocenyl-substituted low-coordinated heavier group 14 elements. Dalton Transactions 2020, 49 (24) , 8029-8035. https://doi.org/10.1039/D0DT01426E
  4. Chip Nataro. Ferrocene: To Infinity and Back Again. 2019,,https://doi.org/10.1016/B978-0-12-409547-2.14671-2
  5. . Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. 2019,,https://doi.org/
  6. Takahiro Sasamori, Yuko Suzuki, Koh Sugamata, Tomohiro Sugahara, Norihiro Tokitoh. Synthesis of Ferrocenyl-Substituted Organochalcogenyldichlorogermanes. Inorganics 2018, 6 (3) , 68. https://doi.org/10.3390/inorganics6030068
  7. John E. Ellis, Mikhail E. Minyaev, Ilya E. Nifant'ev, Andrei V. Churakov. Scandium complexes with the tetraphenylethylene and anthracene dianions. Acta Crystallographica Section C Structural Chemistry 2018, 74 (6) , 769-781. https://doi.org/10.1107/S2053229618007295
  8. Yuko Suzuki, Takahiro Sasamori, Jing-Dong Guo, Norihiro Tokitoh. A Redox-Active Bis(ferrocenyl)germylene and Its Reactivity. Chemistry - A European Journal 2018, 24 (2) , 364-368. https://doi.org/10.1002/chem.201705598
  9. Jason Y. C. Lim, Paul D. Beer. A Halogen Bonding 1,3-Disubstituted Ferrocene Receptor for Recognition and Redox Sensing of Azide. European Journal of Inorganic Chemistry 2017, 2017 (2) , 220-224. https://doi.org/10.1002/ejic.201600805
  10. Yuko Suzuki, Takahiro Sasamori, Jing-Dong Guo, Shigeru Nagase, Norihiro Tokitoh. Isolation and Ambident Reactivity of a Chlorogermylenoid. Chemistry - A European Journal 2016, 22 (39) , 13784-13788. https://doi.org/10.1002/chem.201602601

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