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Neighboring Metal-Induced Oxidative Addition in Conjunction with a Hydride Trap:  Formation of [(η5-MeC5H4)Fe(CO)(μ-η11-PPh2CH2PPh2)(μ-H)M(CO)4] (M = W, Mo)

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Institute of Chemistry, Academia Sinica, Taipei, Taiwan 11529, Republic of China
Cite this: Organometallics 1997, 16, 2, 155–157
Publication Date (Web):January 21, 1997
https://doi.org/10.1021/om9608061
Copyright © 1997 American Chemical Society

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    Abstract

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    The reaction of (η4-MeC5H5)Fe(CO)21-dppm), 1, with M(CO)3L3 produced (η5-MeC5H4)Fe(CO)(μ-η11-dppm)(μ-H)M(CO)4, 3 (L3 = (C2H5CN)3, (THF)3, C7H8; M = W, Mo). The novel hydrido-bridged Fe(II)−M(0) compound was likely formed via the following steps:  coordination of the monodentate dppm to M and then CO migration from Fe to M with a sequential or concerted oxidative addition of the endo-C−H bond of the η4-MeC5H5 ligand to give the (η5-MeC5H4)FeH complex, followed by a trapping of the Fe−H bond by M, forming a six-membered heterocyclic ring in 3.

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     Abstract published in Advance ACS Abstracts, December 15, 1996.

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    For the structures of (η4-MeC5H5)Fe(CO)2(μ-η11-dppm)W(CO)5, 2a, and (η5-MeC5H4)Fe(CO)(μ-η11-dppm)(μ-H)W(CO)4, 3a, listings of crystallographic data, positional and isotropic and anisotropic thermal parameters, and bond distances and angles (13 pages). Ordering information is given on any current masthead page.

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    Cited By

    This article is cited by 10 publications.

    1. Alexandra B. Grimm, Kai Wang, Arnold L. Rheingold, Curtis E. Moore, Dénes Szieberth, László Nyulászi, John D. Protasiewicz. 2-Aryl-1,3-Benzoxaphospholes as Unwilling Participants for Catalytic Suzuki–Miyaura CC Coupling Reactions. Organometallics 2021, 40 (20) , 3436-3444. https://doi.org/10.1021/acs.organomet.1c00462
    2. Kyle D. Wells, Michael J. Ferguson, Robert McDonald and Martin Cowie. A-Frame Complexes of Dirhodium Bridged by Dicarbene and Diphosphine Ligands. Organometallics 2008, 27 (4) , 691-703. https://doi.org/10.1021/om7007937
    3. Marino Basato,, Andrea Biffis,, Gabriella Buscemi,, Elena Callegaro,, Mauro Polo,, Cristina Tubaro,, Alfonso Venzo,, Chiara Vianini,, Claudia Graiff,, Antonio Tiripicchio, and, Franco Benetollo. Reaction of Cyclopentadienyl Ruthenium Complexes with a Carborane Anion:  Effect of the Spectator Ligands on the Substitution Site. Organometallics 2007, 26 (17) , 4265-4270. https://doi.org/10.1021/om700305e
    4. Belén Alvarez, M. Angeles Alvarez, M. Esther García, Daniel García‐Vivó, Miguel A. Ruiz. C−C and C−N Couplings Following Hydride Addition on Isocyanide Cyclopolyenyl Dimolybdenum Complexes to Give Tethered Aldimine and Aminocarbene Derivatives. Chemistry – A European Journal 2017, 23 (56) , 14027-14038. https://doi.org/10.1002/chem.201702998
    5. M. Angeles Alvarez, Belén Alvarez, M. Esther García, Daniel García-Vivó, Miguel A. Ruiz. Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions. Dalton Transactions 2013, 42 (31) , 11039. https://doi.org/10.1039/c3dt51562a
    6. Olalere G. Adeyemi, Ling-Kang Liu. Neighbouring metal induced oxidative addition at the iron centre amongst the iron–arylpyridylphosphine complexes. Inorganica Chimica Acta 2009, 362 (2) , 477-482. https://doi.org/10.1016/j.ica.2008.04.040
    7. Sudhakar D. Dwivedi, Ashish K. Singh, Sanjay K. Singh, Sanjeev Sharma, Manish Chandra, Daya S. Pandey. Ruthenium Complexes Containing Pyridine‐2‐carbaldehyde Azine as a Synthon in the Synthesis of Bi‐/Trimetallic Complexes. European Journal of Inorganic Chemistry 2008, 2008 (36) , 5666-5673. https://doi.org/10.1002/ejic.200800867
    8. M. Tamm, R.J. Baker. Molybdenum Compounds with CO or Isocyanides. 2007, 391-512. https://doi.org/10.1016/B0-08-045047-4/00071-6
    9. M.V. Baker, D.H. Brown. Tungsten Compounds with CO or Isocyanides. 2007, 597-722. https://doi.org/10.1016/B0-08-045047-4/00073-X
    10. Sanjay K. Singh, Manish Chandra, D.S. Pandey, M.C. Puerta, Pedro Valerga. Helices of ruthenium complexes involving pyridyl–azine ligands: synthesis, spectral and structural aspects. Journal of Organometallic Chemistry 2004, 689 (22) , 3612-3620. https://doi.org/10.1016/j.jorganchem.2004.08.026

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