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Highly Luminescent and Optically Switchable Hybrid Material by One-Pot Encapsulation of Dyes into MgAPO-11 Unidirectional Nanopores

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    Highly Luminescent and Optically Switchable Hybrid Material by One-Pot Encapsulation of Dyes into MgAPO-11 Unidirectional Nanopores
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    † Departamento de Química Física, Universidad del País Vasco, UPV/EHU, Apartado 644, 48080 Bilbao, Spain
    ‡ Instituto de Catálisis y Petroleoquímica-CSIC, C/Marie Curie 2, 28049, Cantoblanco, Madrid, Spain
    *E-mail: [email protected]
    *E-mail: (R. García) [email protected]
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    ACS Photonics

    Cite this: ACS Photonics 2014, 1, 3, 205–211
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    https://doi.org/10.1021/ph4000604
    Published February 6, 2014
    Copyright © 2014 American Chemical Society
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    Abstract

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    In this work a highly fluorescent hybrid material with strong anisotropic response is obtained by “one-pot” synthesis. The system is based on the “in situ” encapsulation of two chromophores, acridine (AC) and pyronine Y (PY), with similar molecular structure but perpendicular dipole moment vectors, into the 1D-nanochannels of MgAPO-11 aluminophosphate crystals (AEL structure). This non-diffusional-limited synthetic approach allows the filling of very long channels, reducing considerably the time of sample preparation (>10 μm rectangular-like AEL particles), as well as a perfect fit between the molecular and channel dimensions, avoiding the leakage of the guest dyes and any Davidov coupling. As a consequence, both dyes are embedded only in momomeric units and preferentially aligned with their long molecular axes along the channels. Interestingly, the less bulky nature of AC without pendant groups leads to a much stronger incorporation with respect to PY (48:1), enabling an efficient FRET process between them. The final solid hybrid material shows fluorescent quantum yields higher than the respective dyes in diluted solution together with blue (AC)/green (PY) fluorescence color switching depending on the direction of the polarizers upon UV light excitation.

    Copyright © 2014 American Chemical Society

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    Supporting Information

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    AC and PY molecular structures, AEL framework structure, quantum mechanics calculations on AC (Gaussian 09), photophysical parameters of AC (at different pHs) and PY dye in aqueous solution and their respective absorption and fluorescence spectra, FLIM and polarized intensity fluorescence images of AC/MgAPO-11 single crystal, calculation of the probability of finding an AC molecule around a given PY molecule at a given (R) distance. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cited By

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    This article is cited by 21 publications.

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    ACS Photonics

    Cite this: ACS Photonics 2014, 1, 3, 205–211
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ph4000604
    Published February 6, 2014
    Copyright © 2014 American Chemical Society
    Request reuse permissions

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