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Cellulose–Hemicellulose and Cellulose–Lignin Interactions during Fast Pyrolysis

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† Department of Chemical and Biological Engineering, Iowa State University, Ames, Iowa 50011, United States
‡ Agricultural and Biosystems Engineering, Iowa State University, Ames, Iowa 50011, United States
§ Center for Sustainable and Environmental Technologies, Iowa State University, Ames, Iowa 50011, United States
*Tel.: +1 515 294 1895. E-mail: [email protected]
Cite this: ACS Sustainable Chem. Eng. 2015, 3, 2, 293–301
Publication Date (Web):December 23, 2014
https://doi.org/10.1021/sc500664h
Copyright © 2014 American Chemical Society
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    Abstract

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    Previously, the primary product distribution resulting from fast pyrolysis of cellulose, hemicellulose, and lignin was quantified. This study extends the analysis to the examinations of interactions between cellulose–hemicellulose and cellulose–lignin, which were determined by comparing the pyrolysis products from their native mixture, physical mixture, and superposition of individual components. Negligible interactions were found for both binary physical mixtures. For the native cellulose–hemicellulose mixture, no significant interaction was identified either. In the case of the native cellulose–lignin mixture, herbaceous biomass exhibited an apparent interaction, represented by diminished yield of levoglucosan and enhanced yield of low molecular weight compounds and furans. However, such an interaction was not found for woody biomass. It is speculated that these results are due to different amounts of covalent linkages in these biomass samples. This study provides insight into the chemistry involved during the pyrolysis of multicomponent biomass, which can facilitate building a model for bio-oil composition prediction.

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    Details of the pyrolyzer-GC-MS/FID experiments and ICP-MS analysis, results for the Tukey honest significant different test, biomass component analysis of the extracted hemicellulose, mineral content for pretreated biomass samples, GC chromatographs for the native mixture and physical mixture, pyrolysis product distribution of the extracted hemicellulose, and pyrolysis product distribution of the native cellulose–lignin from switchgrass, pine, and red oak. This material is available free of charge via the Internet at http://pubs.acs.org.

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