Soybean Oil as a Biocompatible Multifunctional Additive for Lubricating OilClick to copy article linkArticle link copied!
Abstract

The application of greener additives based on vegetable oils in the formulation of biolubricants has attracted considerable interest due to their biocompatibility and enhanced multifunctional performances compared to conventional additives. In this investigation, homopolymers of soybean oil and copolymers with methyl acrylate, 1-decene and styrene were synthesized by a thermal method using azobisisobutyronitrile as a radical initiator. Characterization of the prepared polymers was performed by spectral (NMR, IR), viscometric analysis and gel permeation chromatography. Performance evaluations of the polymers as pour point depressant, viscosity modifier/viscosity index improver (VII) and antiwear in different base oils (mineral) were conducted by standard ASTM methods. Biodegradability of the prepared additives was tested against fungal pathogens and micro-organisms by the disc diffusion method and soil burial test method, respectively. Thermal stability of each of them was evaluated and included. The multifunctional performances were compared and reported.
Cited By
Smart citations by scite.ai include citation statements extracted from the full text of the citing article. The number of the statements may be higher than the number of citations provided by ACS Publications if one paper cites another multiple times or lower if scite has not yet processed some of the citing articles.
This article is cited by 48 publications.
- Lixia Huo, Jinshan Guo, Fahu Yang, Changou Pan, Hanjun Hu, Kaifeng Zhang, Hui Zhou, Peng Liu. Esterification of Hydrogenated Hydroxyl-Terminated Polybutadiene as a High-Performance Lubricating Oil. Industrial & Engineering Chemistry Research 2022, 61
(7)
, 2685-2692. https://doi.org/10.1021/acs.iecr.1c04314
- Xue-yi Hu, Mei-ling Sun, Yun Fang, Yin-jun Fang. Molecular Design and Structure–Property Investigation of n-Dodecylbenzyloxy Ethoxylates. Langmuir 2020, 36
(27)
, 7765-7774. https://doi.org/10.1021/acs.langmuir.0c00467
- Gobinda Karmakar Pranab Ghosh Kirtika Kohli Brajendra K. Sharma Sevim Z. Erhan . Chemicals from Vegetable Oils, Fatty Derivatives, and Plant Biomass. 2020, 1-31. https://doi.org/10.1021/bk-2020-1347.ch001
- Nicolas
A. Patience, Federico Galli, Marco G. Rigamonti, Dalma Schieppati, Daria C. Boffito. Ultrasonic Intensification To Produce Diester Biolubricants. Industrial & Engineering Chemistry Research 2019, 58
(19)
, 7957-7963. https://doi.org/10.1021/acs.iecr.9b00717
- Eun-Yeong Jeon, Joo-Hyun Seo, Woo-Ri Kang, Min-Ji Kim, Jung-Hoo Lee, Deok-Kun Oh, and Jin-Byung Park . Simultaneous Enzyme/Whole-Cell Biotransformation of Plant Oils into C9 Carboxylic Acids. ACS Catalysis 2016, 6
(11)
, 7547-7553. https://doi.org/10.1021/acscatal.6b01884
- Kalyani, Rashmi B. Rastogi, and D. Kumar . Synthesis, Characterization, and Tribological Evaluation of SDS-Stabilized Magnesium-Doped Zinc Oxide (Zn0.88Mg0.12O) Nanoparticles as Efficient Antiwear Lubricant Additives. ACS Sustainable Chemistry & Engineering 2016, 4
(6)
, 3420-3428. https://doi.org/10.1021/acssuschemeng.6b00472
- Gobinda Karmakar and Pranab Ghosh . Atom Transfer Radical Polymerization of Soybean Oil and Its Evaluation as a Biodegradable Multifunctional Additive in the Formulation of Eco-Friendly Lubricant. ACS Sustainable Chemistry & Engineering 2016, 4
(3)
, 775-781. https://doi.org/10.1021/acssuschemeng.5b00746
- R. Gallego, J. F. Arteaga, C. Valencia, M. J. Díaz, and J. M. Franco . Gel-Like Dispersions of HMDI-Cross-Linked Lignocellulosic Materials in Castor Oil: Toward Completely Renewable Lubricating Grease Formulations. ACS Sustainable Chemistry & Engineering 2015, 3
(9)
, 2130-2141. https://doi.org/10.1021/acssuschemeng.5b00389
- Wenbo Wang, Jun Qu. Current and candidate additives for environmentally acceptable lubricants—A review. Friction 2025, 13
(4)
, 9440988. https://doi.org/10.26599/FRICT.2025.9440988
- Ajay Pratap Singh Lodhi, Deepak Kumar, Sudarsan Ghosh. Performance evaluation of newly developed environmentally friendly metalworking fluids during grinding. Biomass Conversion and Biorefinery 2025, 15
(2)
, 2933-2947. https://doi.org/10.1007/s13399-023-05109-5
- Liqin Ding, Xinyi Liu, Sifan Liu, Yuntao Xi, Xiao Guo, Hanbin Zhong. Synthesis of Castor Oil-based Bifunctional Lubricant Additive. Petroleum Chemistry 2025, 65
(1)
, 103-111. https://doi.org/10.1134/S0965544123600418
- Liqin Ding, Sifan Liu, Jie Deng, Hanbin Zhong, Shengrong Liang. Controllable synthesis, characterization, and evaluation of poly (lauryl methacrylate-soybean oil) as a lubricant additive. Petroleum Science and Technology 2024, 40 , 1-16. https://doi.org/10.1080/10916466.2024.2391994
- Rosa Maria Nothnagel, Guido Boidi, Rainer Franz, Marcella Frauscher. Assessing the Potential of Bio-Based Friction Modifiers for Food-Grade Lubrication. Lubricants 2024, 12
(7)
, 247. https://doi.org/10.3390/lubricants12070247
- Paola Stradolini, Marcelo Gryczak, Cesar Liberato Petzhold. Polyols from castor oil (
Ricinus communis
) and epoxidized soybean oil (
Glycine max
) for application as a lubricant base. Journal of the American Oil Chemists' Society 2024, 101
(3)
, 321-334. https://doi.org/10.1002/aocs.12749
- Danyang Cao, Leonidas Matsakas, Jie Zhang, Lisong Dong, Yijun Shi, Jiahua Zhu, Xin Feng, Xiaohua Lu, Liwen Mu. Biolubricant. 2024, 1-56. https://doi.org/10.1002/9781119792888.ch1
- Priyanka Agarwal, Suheel K. Porwal. Non-edible/waste cooking oil–derived sustainable green multifunctional copolymeric additives for mineral base oil. Biomass Conversion and Biorefinery 2023, 13
(4)
, 3017-3027. https://doi.org/10.1007/s13399-021-01336-w
- Lixia Huo, Jinshan Guo, Fahu Yang, Changou Pan, Hanjun Hu, Kaifeng Zhang, Hui Zhou, Peng Liu. Design of linear polymer-based liquid lubricants by a strategy of complementary advantages. Polymer 2023, 265 , 125592. https://doi.org/10.1016/j.polymer.2022.125592
- Priyanka Agarwal, Sapna Chaudhary, Jyoti Porwal, Raj K. Singh, Suheel K. Porwal. Evaluation of renewable feedstock-derived copolymers of stearyl methacrylate-co-triglyceride as multifunctional green additives in lubricant. Polymer Bulletin 2022, 79
(4)
, 2133-2148. https://doi.org/10.1007/s00289-021-03611-2
- Ekta Faujdar, Raj K. Singh. Comparative study of poly(acrylate-co-maleimide) copolymers and poly(α-olefins-co-maleimide) copolymers of hindered phenolic Schiff base amine for lubricant applications. Journal of Polymer Research 2022, 29
(3)
https://doi.org/10.1007/s10965-022-02935-5
- Deep Kalita, Ihor Tarnavchyk, Dean C. Webster, Bret J. Chisholm. Synthesis and evaluation of novel plant oil-based polymers as binders for artist paints: Controllable drying behavior and low yellowness. Progress in Organic Coatings 2022, 163 , 106607. https://doi.org/10.1016/j.porgcoat.2021.106607
- Santhosh Kumar Kamarapu, M. Amarnath, B. Suresha. Experimental Investigations to Enhance the Rheological Properties of Vegetable Oils Blending with Mineral Oil. 2022, 487-492. https://doi.org/10.1007/978-981-16-7787-8_39
- Koushik Dey, Pranab Ghosh. Potential Eco‐Friendly Multifunctional Lube Oil Additives: Synthesis, Characterization and Performance Evaluation. ChemistrySelect 2021, 6
(30)
, 7604-7612. https://doi.org/10.1002/slct.202101784
- Yusif Abdullayev, Vagif Abbasov, Fuzuli Nasirov, Nigar Rzayeva, Leyla Nasibova, Jochen Autschbach. Computational mechanistic studies of the carbon–carbon double bond difunctionalization via epoxidation and subsequent aminolysis in vegetable oils. International Journal of Quantum Chemistry 2021, 121
(10)
https://doi.org/10.1002/qua.26609
- Mainul Hoque, Sujan Paul, Pranab Ghosh. Castor oil based eco-friendly lubricating oil additives. Journal of Macromolecular Science, Part A 2021, 58
(5)
, 329-335. https://doi.org/10.1080/10601325.2020.1854045
- Gobinda Karmakar, Koushik Dey, Pranab Ghosh, Brajendra K. Sharma, Sevim Z. Erhan. A Short Review on Polymeric Biomaterials as Additives for Lubricants. Polymers 2021, 13
(8)
, 1333. https://doi.org/10.3390/polym13081333
- Koushik Dey, Gobinda Karmakar, Mahua Upadhyay, Pranab Ghosh. Polyacrylate-magnetite nanocomposite as a potential multifunctional additive for lube oil. Scientific Reports 2020, 10
(1)
https://doi.org/10.1038/s41598-020-76246-4
- Fukang Deng, Tao Jiang, Kedi Yang, Fuchuan Huang. Low friction and wear self-assembly nano tribofilm of amphiphilic functionalized tea saponin in a water/oil phase. Journal of Cleaner Production 2020, 270 , 122414. https://doi.org/10.1016/j.jclepro.2020.122414
- Juliette Lomège, Claire Negrell, Jean‐Jacques Robin, Vincent Lapinte, Sylvain Caillol. Synthesis of Alkyl Sulfur‐Functionalized Oleic Acid‐Based Polymethacrylates and Their Application as Viscosity Index Improvers in a Mineral Paraffinic Lube Oil. Journal of the American Oil Chemists' Society 2020, 97
(3)
, 309-318. https://doi.org/10.1002/aocs.12316
- Shubham Pandey, Pragati R. Sharma, Vineet Kumar Soni, Ganpat Choudhary, Rakesh K. Sharma. On the study of cucurbit[6]uril and 4-
tert
-butylcalix[6]arene as multifunctional lubricant additives. New Journal of Chemistry 2020, 44
(8)
, 3425-3433. https://doi.org/10.1039/D0NJ00191K
- B. Suresha, G. Hemanth, Apurva Rakesh, K. M. Adarsh. Tribological Behaviour of Neem Oil with and without Graphene Nanoplatelets Using Four-Ball Tester. Advances in Tribology 2020, 2020 , 1-11. https://doi.org/10.1155/2020/1984931
- Min Xie, Jun Cheng, Guohu Zhao, Haixia Liu, Li Zhang, Cailing Yang. Natural wax from non-medicinal aerial part of Codonopsis pilosula as a biolubricant. Journal of Cleaner Production 2020, 242 , 118403. https://doi.org/10.1016/j.jclepro.2019.118403
- Zhuang Xu, Wenjing Lou, Gaiqing Zhao, Dongdong Zheng, Junying Hao, Xiaobo Wang. Cu nanoparticles decorated WS
2
nanosheets as a lubricant additive for enhanced tribological performance. RSC Advances 2019, 9
(14)
, 7786-7794. https://doi.org/10.1039/C9RA00337A
- Sun-Ki Kim, Yong-Cheol Park. Biosynthesis of ω-hydroxy fatty acids and related chemicals from natural fatty acids by recombinant Escherichia coli. Applied Microbiology and Biotechnology 2019, 103
(1)
, 191-199. https://doi.org/10.1007/s00253-018-9503-6
- P. V. Ivchenko, I. E. Nifant’ev. Polymer Depressor Additives: Synthesis, Microstructure, Efficiency. Polymer Science, Series A 2018, 60
(5)
, 577-593. https://doi.org/10.1134/S0965545X18050061
- Mahua Upadhyay, Gobinda Karmakar, Gurpreet Singh Kapur, Pranab Ghosh. Multifunctional greener additives for lubricating oil. Polymer Engineering & Science 2018, 58
(5)
, 810-815. https://doi.org/10.1002/pen.24635
- Debasish Kumar Saha, Pranab Ghosh. Naturally derived green bio-additives. Journal of Macromolecular Science, Part A 2018, 55
(4)
, 384-392. https://doi.org/10.1080/10601325.2018.1444419
- Xinhu Wu, Gaiqing Zhao, Xiaobo Wang, Weimin Liu, Weisheng Liu. In situ formed ionic liquids in lard oil as high‐performance lubricants for steel/steel contacts at elevated temperature. Lubrication Science 2018, 30
(2)
, 65-72. https://doi.org/10.1002/ls.1404
- Pranab Ghosh, Mainul Hoque, Gobinda Karmakar. Castor oil as potential multifunctional additive in the formulation of eco-friendly lubricant. Polymer Bulletin 2018, 75
(2)
, 501-514. https://doi.org/10.1007/s00289-017-2047-6
- Dhorali Gnanasekaran, Venkata Prasad Chavidi. Vegetable Oil as a Multifunctional and Multipurpose Green Lubricant Additive. 2018, 49-62. https://doi.org/10.1007/978-981-10-4870-8_3
- Gobinda Karmakar, Pranab Ghosh, Brajendra Sharma. Chemically Modifying Vegetable Oils to Prepare Green Lubricants. Lubricants 2017, 5
(4)
, 44. https://doi.org/10.3390/lubricants5040044
- Yurong Wang, Qiangliang Yu, Zhengfeng Ma, Guowei Huang, Meirong Cai, Feng Zhou, Weimin Liu. Significant enhancement of anti-friction capability of cationic surfactant by phosphonate functionality as additive in water. Tribology International 2017, 112 , 86-93. https://doi.org/10.1016/j.triboint.2017.03.034
- Pranab Ghosh, Mainul Hoque, Gobinda Karmakar. Terpolymers based on sunflower oil/alkyl acrylate/styrene as sustainable lubricant additive. Polymer Bulletin 2017, 74
(7)
, 2685-2700. https://doi.org/10.1007/s00289-016-1863-4
- Xinhu Wu, Gaiqing Zhao, Xiaobo Wang, Weimin Liu. Preparation of High-Temperature Lubricants by Blending Castor Oil with Lithium Bis(trifluoromethylsulfonyl)imide. Tribology Letters 2017, 65
(2)
https://doi.org/10.1007/s11249-017-0833-9
- Yurong Wang, Qiangliang Yu, Meirong Cai, Lei Shi, Feng Zhou, Weimin Liu. Ibuprofen-Based Ionic Liquids as Additives for Enhancing the Lubricity and Antiwear of Water–Ethylene Glycol Liquid. Tribology Letters 2017, 65
(2)
https://doi.org/10.1007/s11249-017-0840-x
- Mercedes González, Rocío Gallego, Miguel A. Romero, José A. González-Delgado, Jesús F. Arteaga, Concepción Valencia, José M. Franco. Impact of natural sources-derived antioxidants on the oxidative stability and rheological properties of castor oil based-lubricating greases. Industrial Crops and Products 2016, 87 , 297-303. https://doi.org/10.1016/j.indcrop.2016.04.068
- Gobinda Karmakar, Pranab Ghosh. Vegetable Oils as Additive in the Formulation of Eco-Friendly Lubricant. 2016, 291-313. https://doi.org/10.1201/9781315373256-16
- Padmaja V. Korlipara. Vegetable Oil-Based Lubricant Additives. 2016, 315-331. https://doi.org/10.1201/9781315373256-17
- Raluca N. Darie‐Niţă, Cornelia Vasile, Anamaria Irimia, Rodica Lipşa, Maria Râpă. Evaluation of some eco‐friendly plasticizers for
PLA
films processing. Journal of Applied Polymer Science 2016, 133
(13)
https://doi.org/10.1002/app.43223
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.