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Concentration Measurement of Length-Fractionated Colloidal Single-Wall Carbon Nanotubes

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Polymers Division, National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899-8542, United States
School of Materials Engineering, and §Division of Environmental and Ecological Engineering, Purdue University, West Lafayette, Indiana 47907, United States
Cite this: Anal. Chem. 2012, 84, 20, 8733–8739
Publication Date (Web):September 20, 2012
https://doi.org/10.1021/ac302023n
Copyright © 2012 American Chemical Society
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Abstract

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The determination of the carbon concentration of single-wall carbon nanotubes (SWCNTs) in a given dispersion is a basic requirement for many studies. The commonly used optical absorption-based concentration measurement is complicated by the spectral change due to variations in nanotube chirality and length. In particular, the origin of the observed length-dependent spectral change and its effect on concentration determination has been the subject of considerable debate. Here, we use length-fractionated DNA-wrapped SWCNTs to establish the relationship between SWCNT carbon concentration and optical absorption spectra by directly quantifying the amount of wrapping DNA and, independently, the DNA/carbon nanotube mass ratio. We find that SWCNT carbon concentrations derived from either the E11 peak or spectral baseline deviate significantly from the SWCNT carbon concentrations derived from the DNA measurement method. Instead, SWCNT carbon concentrations derived from the spectral integration of the E11 optical transition region match most closely with the DNA-derived SWCNT carbon concentrations. We also observe that shorter SWCNT fractions contain more curved carbon nanotubes, and propose that these defective nanotubes are largely responsible for the observed spectral variation with nanotube length.

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Complete UV–vis NIR absorbance spectra for the SEC separated fractions, as well as AFM length histograms and several AFM images. Additional details concerning XPS experiments are also given. This material is available free of charge via the Internet at http://pubs.acs.org.

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This article is cited by 18 publications.

  1. Feng Yang, Meng Wang, Daqi Zhang, Juan Yang, Ming Zheng, Yan Li. Chirality Pure Carbon Nanotubes: Growth, Sorting, and Characterization. Chemical Reviews 2020, 120 (5) , 2693-2758. https://doi.org/10.1021/acs.chemrev.9b00835
  2. Mohammad Moein Safaee, Mitchell Gravely, Caroline Rocchio, Matthew Simmeth, Daniel Roxbury. DNA Sequence Mediates Apparent Length Distribution in Single-Walled Carbon Nanotubes. ACS Applied Materials & Interfaces 2019, 11 (2) , 2225-2233. https://doi.org/10.1021/acsami.8b16478
  3. Mark Freeley, Harley L. Worthy, Rochelle Ahmed, Ben Bowen, Daniel Watkins, J. Emyr Macdonald, Ming Zheng, D. Dafydd Jones, and Matteo Palma . Site-Specific One-to-One Click Coupling of Single Proteins to Individual Carbon Nanotubes: A Single-Molecule Approach. Journal of the American Chemical Society 2017, 139 (49) , 17834-17840. https://doi.org/10.1021/jacs.7b07362
  4. Fuyou Ke and Xiangyun Qiu . Nanoscale Structure and Interaction of Condensed Phases of DNA–Carbon Nanotube Hybrids. The Journal of Physical Chemistry C 2015, 119 (27) , 15763-15769. https://doi.org/10.1021/acs.jpcc.5b04794
  5. Jason K. Streit, Sergei M. Bachilo, Saunab Ghosh, Ching-Wei Lin, and R. Bruce Weisman . Directly Measured Optical Absorption Cross Sections for Structure-Selected Single-Walled Carbon Nanotubes. Nano Letters 2014, 14 (3) , 1530-1536. https://doi.org/10.1021/nl404791y
  6. Ming-Hui Shang, Takashi Fujikawa, and Nobuo Ueno . Recoil Effects in Valence Band Photoemission of Organic Solids. Analytical Chemistry 2013, 85 (7) , 3739-3745. https://doi.org/10.1021/ac4000865
  7. Constantine Y. Khripin, Xiaomin Tu, John M. Heddleston, Carlos Silvera-Batista, Angela R. Hight Walker, Jeffrey Fagan, and Ming Zheng . High-Resolution Length Fractionation of Surfactant-Dispersed Carbon Nanotubes. Analytical Chemistry 2013, 85 (3) , 1382-1388. https://doi.org/10.1021/ac303349q
  8. Fuyou Ke, Jiaoli Chen, Rongliang Wu, Ye Chen. Dispersion quality of single-walled carbon nanotubes reveals the recognition sequence of DNA. Nanotechnology 2020, 31 (25) , 255708. https://doi.org/10.1088/1361-6528/ab7de3
  9. Prakrit V. Jena, Christian Cupo, Daniel A. Heller. Near Infrared Spectral Imaging of Carbon Nanotubes for Biomedicine. 2020,,, 103-132. https://doi.org/10.1007/978-3-030-32036-2_6
  10. Peter Laux, Christian Riebeling, Andy M. Booth, Joseph D. Brain, Josephine Brunner, Cristina Cerrillo, Otto Creutzenberg, Irina Estrela-Lopis, Thomas Gebel, Gunnar Johanson, Harald Jungnickel, Heiko Kock, Jutta Tentschert, Ahmed Tlili, Andreas Schäffer, Adriënne J. A. M. Sips, Robert A. Yokel, Andreas Luch. Challenges in characterizing the environmental fate and effects of carbon nanotubes and inorganic nanomaterials in aquatic systems. Environmental Science: Nano 2018, 5 (1) , 48-63. https://doi.org/10.1039/C7EN00594F
  11. Ming Zheng. Sorting Carbon Nanotubes. Topics in Current Chemistry 2017, 375 (1) https://doi.org/10.1007/s41061-016-0098-z
  12. Yeon Seok Kim, Rick Davis, Nasir Uddin, Marc Nyden, Savelas A. Rabb. Quantification of nanoparticle release from polymer nanocomposite coatings due to environmental stressing. Journal of Occupational and Environmental Hygiene 2016, 13 (4) , 303-313. https://doi.org/10.1080/15459624.2015.1116696
  13. Cristina Cerrillo, Gotzone Barandika, Amaya Igartua, Olatz Areitioaurtena, Nerea Uranga, Gemma Mendoza. Colloidal stability and ecotoxicity of multiwalled carbon nanotubes: Influence of select organic matters. Environmental Toxicology and Chemistry 2016, 35 (1) , 74-83. https://doi.org/10.1002/etc.3172
  14. Fernando Vargas–Lara, Ahmed M. Hassan, Edward J. Garboczi, Jack F. Douglas. Intrinsic conductivity of carbon nanotubes and graphene sheets having a realistic geometry. The Journal of Chemical Physics 2015, 143 (20) , 204902. https://doi.org/10.1063/1.4935970
  15. Cristina Cerrillo, Gotzone Barandika, Amaya Igartua, Olatz Areitioaurtena, Arrate Marcaide, Gemma Mendoza. Ecotoxicity of multiwalled carbon nanotubes: Standardization of the dispersion methods and concentration measurements. Environmental Toxicology and Chemistry 2015, 34 (8) , 1854-1862. https://doi.org/10.1002/etc.2999
  16. Saurabh Jyoti Sarma, Indrani Bhattacharya, Satinder Kaur Brar, Rajeshwar Dayal Tyagi, Rao y. Surampalli. Carbon Nanotube—Bioaccumulation and Recent Advances in Environmental Monitoring. Critical Reviews in Environmental Science and Technology 2015, 45 (9) , 905-938. https://doi.org/10.1080/10643389.2014.924177
  17. Anton V. Naumov, Dmitri A. Tsyboulski, Sergei M. Bachilo, R. Bruce Weisman. Length-dependent optical properties of single-walled carbon nanotube samples. Chemical Physics 2013, 422 , 255-263. https://doi.org/10.1016/j.chemphys.2012.12.033
  18. Xiangyun Qiu, Constantine Y. Khripin, Fuyou Ke, Steven C. Howell, Ming Zheng. Electrostatically Driven Interactions between Hybrid DNA-Carbon Nanotubes. Physical Review Letters 2013, 111 (4) https://doi.org/10.1103/PhysRevLett.111.048301

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