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High-Resolution Length Fractionation of Surfactant-Dispersed Carbon Nanotubes

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National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899-8542, United States
Cite this: Anal. Chem. 2013, 85, 3, 1382–1388
Publication Date (Web):December 23, 2012
https://doi.org/10.1021/ac303349q
Copyright © 2012 American Chemical Society
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Abstract

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Length fractionation of colloidal single-wall carbon nanotube (SWCNT) dispersions is required for many studies. Size-exclusion chromatography (SEC) has been developed as a reliable method for high-resolution length fractionation of DNA-dispersed SWCNTs but has not been applied to surfactant-dispersed SWCNTs due to their lower dispersion stability and tendency to adsorb onto SEC stationary phases. Here, we report that SEC length fractionation can be achieved for bile salt dispersed SWCNTs by using porous silica-based beads as the stationary phase and bile salt solution as the mobile phase. We demonstrate that the SEC length sorting method can be combined with existing ultracentrifugation SWCNT sorting methods to produce “orthogonally sorted” samples, including length sorted semiconducting SWCNTs, which are important for electronics applications as well as length sorted empty-core SWCNTs. Importantly, we show that unlike simple length fractionation by SEC or any other method, orthogonal sorting produces samples of consistent quality for different length fractions, with similar UV–vis-nearIR absorption and Raman spectral features.

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Elution profiles of several runs, AFM images of long and short fractions of the double-purified CoMoCAT and empty/water-filled sorted arc-discharge materials, curvature quantification data for the CoMoCAT materials, and sample Raman spectra. This material is available free of charge via the Internet at http://pubs.acs.org.

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