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Highly Efficient Ionic Gating of Solid-State Nanosensors by the Reversible Interaction between Pillar[6]arene-AuNPs and Azobenzene

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    Highly Efficient Ionic Gating of Solid-State Nanosensors by the Reversible Interaction between Pillar[6]arene-AuNPs and Azobenzene
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    • Ruiping Zhang
      Ruiping Zhang
      The Affiliated Bethune Hospital of Shanxi Medical University, Taiyuan 030001, P. R. China
      More by Ruiping Zhang
    • Jinmei Huang
      Jinmei Huang
      Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control (AEMPC), Nanjing University of Information Science & Technology, Nanjing 210044, China
      Key Laboratory of Pesticides and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China
      More by Jinmei Huang
    • Kai Chen
      Kai Chen
      Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control (AEMPC), Nanjing University of Information Science & Technology, Nanjing 210044, China
      More by Kai Chen
      Orcidhttps://orcid.org/0000-0002-5852-3264
    • Imene Boussouar
      Imene Boussouar
      Key Laboratory of Pesticides and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China
      More by Imene Boussouar
    • Xiaoya Chen
      Xiaoya Chen
      The State Key Laboratory of Fine Chemicals, Dalian University of Technology, Liaoning 116024, China
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    • Yifan Fan
      Yifan Fan
      Key Laboratory of Pesticides and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China
      Guangdong Provincial Key Laboratory of Radioactive and Rare Resource Utilization, Shaoguan 512026, China
      More by Yifan Fan
    • Yao Sun*
      Yao Sun
      Key Laboratory of Pesticides and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China
      *Email: [email protected]
      More by Yao Sun
      Orcidhttps://orcid.org/0000-0002-6519-7436
    • Haibing Li
      Haibing Li
      Key Laboratory of Pesticides and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China
      More by Haibing Li
      Orcidhttps://orcid.org/0000-0002-6374-4694
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    Analytical Chemistry

    Cite this: Anal. Chem. 2021, 93, 6, 3280–3286
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    https://doi.org/10.1021/acs.analchem.0c05241
    Published February 2, 2021
    Copyright © 2021 American Chemical Society
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    Abstract

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    By mimicking nature, various artificial nanofluidic platforms have been widely applied in a range of scientific fields. However, their low performance in terms of gating efficiency (<25) still hinders their practical applications. Herein, we present a highly efficient ionic gating nanosensor by fusing the merits of host–guest chemistry and Au nanoparticles (AuNPs). Based on this strategy, the pillar[6]arene (WP6)-functionalized AuNPs facilely regulated an azobenzene (AZO)-modified nanosensor with an excellent ion rectification ratio (∼22.2) and gating efficiency (∼89.5). More importantly, this gating nanosensor system also demonstrated promising stability and recyclability under conditions of alternative irradiation of visible and ultraviolet light. These excellent results would significantly help in expanding the utilization of artificial nanosensors for controllable drug delivery and biosensors.

    Copyright © 2021 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.analchem.0c05241.

    • Detailed description of the experimental method; SEM spectra; device diagram; contact angles; XPS data; fluorescence spectra; ion gating ratio; EOF experiments; finite element computation; and electrospray ionization-mass spectrometer (ESI-MS) analysis (PDF)

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    Cited By

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    This article is cited by 22 publications.

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    Analytical Chemistry

    Cite this: Anal. Chem. 2021, 93, 6, 3280–3286
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.analchem.0c05241
    Published February 2, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

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