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Development of a New Tandem Ion Exchange and Size Exclusion Chromatography Method To Monitor Vaccine Particle Titer in Cell Culture Media
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    Development of a New Tandem Ion Exchange and Size Exclusion Chromatography Method To Monitor Vaccine Particle Titer in Cell Culture Media
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    • Andrew W. Shaddeau
      Andrew W. Shaddeau
      Vaccine Production Program, Vaccine Research Center, National Institute of Allergy and Infectious Diseases, National Institutes of Health, Gaithersburg Maryland United States
    • Nicole A. Schneck*
      Nicole A. Schneck
      Vaccine Production Program, Vaccine Research Center, National Institute of Allergy and Infectious Diseases, National Institutes of Health, Gaithersburg Maryland United States
      *E-mail: [email protected]. Tel.: 1-301-761-7574 (N.A.S.).
    • Yile Li
      Yile Li
      Vaccine Production Program, Vaccine Research Center, National Institute of Allergy and Infectious Diseases, National Institutes of Health, Gaithersburg Maryland United States
      More by Yile Li
    • Vera B. Ivleva
      Vera B. Ivleva
      Vaccine Production Program, Vaccine Research Center, National Institute of Allergy and Infectious Diseases, National Institutes of Health, Gaithersburg Maryland United States
    • Frank J. Arnold
      Frank J. Arnold
      Vaccine Production Program, Vaccine Research Center, National Institute of Allergy and Infectious Diseases, National Institutes of Health, Gaithersburg Maryland United States
    • Jonathan W. Cooper
      Jonathan W. Cooper
      Vaccine Production Program, Vaccine Research Center, National Institute of Allergy and Infectious Diseases, National Institutes of Health, Gaithersburg Maryland United States
    • Q. Paula Lei*
      Q. Paula Lei
      Vaccine Production Program, Vaccine Research Center, National Institute of Allergy and Infectious Diseases, National Institutes of Health, Gaithersburg Maryland United States
      *E-mail: [email protected]. Tel.: 1-301-761-7288 (Q.P.L.).
      More by Q. Paula Lei
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    Analytical Chemistry

    Cite this: Anal. Chem. 2019, 91, 10, 6430–6434
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    https://doi.org/10.1021/acs.analchem.9b00095
    Published April 29, 2019
    Copyright © 2019 American Chemical Society

    Abstract

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    A new tandem chromatography method was developed to directly measure the titers of various vaccine candidate molecules in cell culture without a prior purification step. The method utilized a strong anion exchange chromatography (IEC) column in tandem with a size exclusion chromatography (SEC) column to efficiently separate the nanoparticle and virus-like particle (VLP) vaccine molecules from host cell proteins and other components in the cell culture media. The dual (charge and hydrodynamic size) separation mode was deemed necessary to achieve good separation of the vaccine product for quantitation. The method development and quality assessment illustrated herein was focused on the influenza vaccine candidate H1ssF, a hemagglutinin (group 1) stabilized stem molecule fused to ferritin to form nanoparticles. This newly established method was then successfully applied to several vaccine candidate developmental projects, such as the hemagglutinin–ferritin (HAF) nanoparticle and encephalitic alphavirus VLP-based vaccines. This IEC–SEC strategy was established as a platform approach for direct titer measurement of novel vaccine molecules in cell culture.

    Copyright © 2019 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.analchem.9b00095.

    • Screening SEC columns with different pore sizes for IEC–SEC method development, representative calibration curves of the various vaccine particles, and intra- and intermediate precision assessment of the IEC–SEC assay for H1ssF (PDF)

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    Cited By

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    This article is cited by 9 publications.

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    6. Shixiang Liu, Zhihua Li, Bing Yu, Song Wang, Youqing Shen, Hailin Cong. Recent advances on protein separation and purification methods. Advances in Colloid and Interface Science 2020, 284 , 102254. https://doi.org/10.1016/j.cis.2020.102254
    7. Ming Zheng, Mugui Zhuo. PPI Inference Algorithms Using MS Data. 2020, 931-936. https://doi.org/10.1007/978-981-15-2568-1_127
    8. Daniel J. Blackstock, Alvenne Goh, Shamitha Shetty, Giulia Fabozzi, Rong Yang, Vera B. Ivleva, Richard Schwartz, Joseph Horwitz. Comprehensive Flow Cytometry Analysis of PEI-Based Transfections for Virus-Like Particle Production. Research 2020, 2020 https://doi.org/10.34133/2020/1387402
    9. Peifeng Chen, Jacob Demirji, Vera B. Ivleva, Joe Horwitz, Richard Schwartz, Frank Arnold. The transient expression of CHIKV VLP in large stirred tank bioreactors. Cytotechnology 2019, 71 (6) , 1079-1093. https://doi.org/10.1007/s10616-019-00346-x

    Analytical Chemistry

    Cite this: Anal. Chem. 2019, 91, 10, 6430–6434
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.analchem.9b00095
    Published April 29, 2019
    Copyright © 2019 American Chemical Society

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