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Missing Piece of the Mechanism of the Turkevich Method: The Critical Role of Citrate Protonation

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    Missing Piece of the Mechanism of the Turkevich Method: The Critical Role of Citrate Protonation
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    † Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489 Berlin, Germany
    ‡ Technische Universität Berlin, Straße des 17. Juni 124, 10623 Berlin, Germany
    *E-mail: [email protected]
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    Chemistry of Materials

    Cite this: Chem. Mater. 2016, 28, 11, 4072–4081
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    https://doi.org/10.1021/acs.chemmater.6b01796
    Published May 17, 2016
    Copyright © 2016 American Chemical Society
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    Abstract

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    This contribution investigates the growth mechanism of the Turkevich method. The experimental results provide the missing piece of the mechanistic puzzle which enables the actual control of particle growth in the commonly used Turkevich method. Applying the gained knowledge, the boundary conditions for a successful Turkevich synthesis are deduced. Moreover, the conditions under which the Turkevich method is highly reproducible are derived. Following these conditions, the Turkevich synthesis is modified to reveal small monodisperse particles with an unprecedented reproducibility of ±0.1 nm.

    Copyright © 2016 American Chemical Society

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.6b01796.

    • Details on the evaluation of SAXS data; additional SAXS scattering curves and TEM images; additional data of the reproducibility studies; UV–vis studies on the speciation and aging of HAuCl4 (PDF)

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    Cite this: Chem. Mater. 2016, 28, 11, 4072–4081
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.chemmater.6b01796
    Published May 17, 2016
    Copyright © 2016 American Chemical Society
    Request reuse permissions

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