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Crystal Structure and Nontypical Deep-Red Luminescence of Ca3Mg[Li2Si2N6]:Eu2+

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    Crystal Structure and Nontypical Deep-Red Luminescence of Ca3Mg[Li2Si2N6]:Eu2+
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    Department of Chemistry, University of Munich (LMU), Butenandtstr. 5-13 (D), 81377 Munich, Germany
    *E-mail: [email protected]
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    Chemistry of Materials

    Cite this: Chem. Mater. 2017, 29, 8, 3778–3784
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    https://doi.org/10.1021/acs.chemmater.7b00871
    Published April 3, 2017
    Copyright © 2017 American Chemical Society
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    Abstract

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    Rare-earth-doped nitridosilicates exhibit outstanding luminescence properties and have been intensively studied for solid-state lighting. Here, we describe the new nitridolithosilicate Ca3Mg[Li2Si2N6]:Eu2+ with extraordinary luminescence characteristics. The compound was synthesized by the solid-state metathesis reaction in sealed Ta ampules. The crystal structure was solved and refined on the basis of single-crystal X-ray diffraction data. Ca3Mg[Li2Si2N6]:Eu2+ crystallizes in the monoclinic space group C2/m (no. 12) [Z = 4, a = 5.966(1), b = 9.806(2), c = 11.721(2) Å, β = 99.67(3)°, V = 675.9(2) Å3] and exhibits a layered anionic network made up of edge- and corner-sharing LiN4 tetrahedra and [Si2N6]10– bow-tie units. The network charge is compensated by Ca2+ and Mg2+ ions. Upon irradiation with UV to blue light, red emission at exceptionally long wavelengths (λem = 734 nm, fwhm ≈2293 cm–1) is observed. According to emission in the near-infrared, application in LEDs for horticultural lighting appears promising.

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.7b00871.

    • Selected bond lengths in Ca3Mg[Li2Si2N6]:Eu2+, selected bond angles in Ca3Mg[Li2Si2N6]:Eu2+, and anisotropic displacement parameters for Ca3Mg[Li2Si2N6]:Eu2+ (PDF)

    • Crystallographic data for Ca3Mg[Li2Si2N6]:Eu2+ (CIF)

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    Cited By

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    This article is cited by 45 publications.

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    Cite this: Chem. Mater. 2017, 29, 8, 3778–3784
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.chemmater.7b00871
    Published April 3, 2017
    Copyright © 2017 American Chemical Society
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