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Observation of High Seebeck Coefficient and Low Thermal Conductivity in [SrO]-Intercalated CuSbSe2 Compound

  • Kejun Bu
    Kejun Bu
    State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
    University of Chinese Academy of Sciences, Beijing 100049, China
    More by Kejun Bu
  • Jian Huang
    Jian Huang
    State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
    More by Jian Huang
  • Mengjia Luo
    Mengjia Luo
    State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
    University of Chinese Academy of Sciences, Beijing 100049, China
    More by Mengjia Luo
  • Mengjia Guan
    Mengjia Guan
    State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
    University of Chinese Academy of Sciences, Beijing 100049, China
    More by Mengjia Guan
  • Chong Zheng
    Chong Zheng
    Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, Illinois 60115, United States
    More by Chong Zheng
  • Jie Pan
    Jie Pan
    State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
    More by Jie Pan
  • Xian Zhang
    Xian Zhang
    State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
    More by Xian Zhang
  • Sishun Wang
    Sishun Wang
    State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
    More by Sishun Wang
  • Wei Zhao
    Wei Zhao
    State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
    More by Wei Zhao
  • Xun Shi
    Xun Shi
    State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
    More by Xun Shi
  • Li Xu
    Li Xu
    Material Laboratory of State Grid Corporation of China, State Key laboratory of Advanced Transmission Technology, Global Energy Interconnection Research Institute Co., Ltd., Beijing 102209, China
    More by Li Xu
  • , and 
  • Fuqiang Huang*
    Fuqiang Huang
    State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
    State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
    *E-mail: [email protected] (Fuqiang Huang).
Cite this: Chem. Mater. 2018, 30, 16, 5539–5543
Publication Date (Web):August 6, 2018
https://doi.org/10.1021/acs.chemmater.8b02651
Copyright © 2018 American Chemical Society
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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.chemmater.8b02651.

  • Data for CuOSbSe2, Sr (CIF)

  • Experimental details, crystal structure details, TG-DTA, TEM, Supplementary equations, ELF calculation, DFT calculation of SrOCuSbSe2 (PDF)

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Cited By


This article is cited by 5 publications.

  1. Kejun Bu, Mengjia Luo, Ruiqi Wang, Xian Zhang, Jianqiao He, Dong Wang, Wei Zhao, Fuqiang Huang. Enhanced Photoelectric SrOCuSbS2 of a [SrO]-Intercalated CuSbS2 Structure. Inorganic Chemistry 2019, 58 (1) , 69-72. https://doi.org/10.1021/acs.inorgchem.8b03082
  2. Mengjia Luo, Kejun Bu, Xian Zhang, Jian Huang, Ruiqi Wang, Fuqiang Huang. Intrinsically low thermal conductivity in a p-type semiconductor SrOCuBiSe 2 with a [SrO]-intercalated CuBiSe 2 structure. Chemical Communications 2020, 56 (31) , 4356-4359. https://doi.org/10.1039/D0CC00035C
  3. Yang Wang, Mengjia Luo, Pei Zhao, Xiangli Che, Yunzhen Cao, Fuqiang Huang. Sr 4 Pb 1.5 Sb 5 O 5 Se 8 : a new mid-infrared nonlinear optical material with a moderate SHG response. CrystEngComm 2020, 77 https://doi.org/10.1039/D0CE00084A
  4. Ruiqi Wang, Fei Liang, Fakun Wang, Yangwu Guo, Xian Zhang, Yi Xiao, Kejun Bu, Zheshuai Lin, Jiyong Yao, Tianyou Zhai, Fuqiang Huang. Sr 6 Cd 2 Sb 6 O 7 S 10 : Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups. Angewandte Chemie 2019, 131 (24) , 8162-8165. https://doi.org/10.1002/ange.201902806
  5. Ruiqi Wang, Fei Liang, Fakun Wang, Yangwu Guo, Xian Zhang, Yi Xiao, Kejun Bu, Zheshuai Lin, Jiyong Yao, Tianyou Zhai, Fuqiang Huang. Sr 6 Cd 2 Sb 6 O 7 S 10 : Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups. Angewandte Chemie International Edition 2019, 58 (24) , 8078-8081. https://doi.org/10.1002/anie.201902806

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