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Thermal Cracking of Oil under Water Pressure up to 900 bar at High Thermal Maturities. 1. Gas Compositions and Carbon Isotopes
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    Thermal Cracking of Oil under Water Pressure up to 900 bar at High Thermal Maturities. 1. Gas Compositions and Carbon Isotopes
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    Department of Earth Science, Zhejiang University, Hangzhou 310027, China
    Research Institute of Unconventional Petroleum and Renewable Energy, China University of Petroleum, Qingdao 266580, China
    § Faculty of Engineering, University of Nottingham, Energy Technologies Building, Triumph Road, Nottingham NG7 2TU, U.K.
    Beijing Research Center of CNOOC China Ltd., Beijing 100027, China
    Centre for Environmental Geochemistry, British Geological Survey, Keyworth, Nottingham, NG12 5GG, U.K.
    *E-mail: [email protected] (Y. Sun).
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    Energy & Fuels

    Cite this: Energy Fuels 2016, 30, 4, 2617–2627
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    https://doi.org/10.1021/acs.energyfuels.5b02792
    Published March 4, 2016
    Copyright © 2016 American Chemical Society

    Abstract

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    In this study, a C9+ fraction of saturate-rich Tertiary source rock-derived oil from the South China Sea basin was pyrolyzed in normal and supercritical water using a 25 mL vessel at a range of temperature from 350 to 425 °C for 24 h, to probe pressure effects up to 900 bar on gas yields and their stable carbon isotopic compositions during thermal cracking. Pressure generally retards oil cracking, as evidenced by reduced gas yields, but the trends depend upon the level of thermal evolution. In the early stages of cracking (350 and 373 °C, equivalent vitrinite reflectance of < ∼1.1% R0), the suppression effect increases with pressure from 200 to 900 bar, but it is most marked between 200 and 470 bar. At the later stages in the wet gas window (390, 405, and 425 °C, equivalent vitrinite reflectance of >1.3% R0), pressure still has a strong suppression effect from 200 to 470 bar, which then levels off or is reversed as the pressure is increased further to 750 and 900 bar. Interestingly, the stable carbon isotopic composition of the generated methane becomes enriched in 13C as the pressure increases from 200 to 900 bar. A maximum fractionation effect of ∼3‰ is observed over this pressure range. Due to pressure retardation, the isotopically heaviest methane signature does not coincide with the maximum gas yield, contrary to what might be expected. In contrast, pressure has little effect on ethane, propane, and butane carbon isotope ratios, which show a maximum variation of ∼1‰. The results suggest that the rates of methane-forming reactions affected by pressure control methane carbon isotope fractionation. Based on distinctive carbon isotope patterns of methane and wet gases from pressurized oil cracking, a conceptual model using “natural gas plot” is constructed to identify pressure effect on in situ oil cracking providing other factors excluded. The transition in going from dry conditions to normal and supercritical water does not have a significant effect on oil-cracking reactions as evidenced by gold bag hydrous and anhydrous pyrolysis results at the same temperatures as used in the pressure vessel.

    Copyright © 2016 American Chemical Society

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    This article is cited by 14 publications.

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    Energy & Fuels

    Cite this: Energy Fuels 2016, 30, 4, 2617–2627
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.energyfuels.5b02792
    Published March 4, 2016
    Copyright © 2016 American Chemical Society

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