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Unravelling New Processes at Interfaces: Photochemical Isoprene Production at the Sea Surface

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† Université de Lyon 1, Lyon, F-69626, France
‡ CNRS, UMR5256, IRCELYON, Institut de Recherches sur la Catalyse et l′Environnement de Lyon, Villeurbanne, F-69626, France
§ Leibniz-Institut für Troposphärenforschung e.V. (TROPOS), Permoserstraße 15, 04318 Leipzig, Germany
*E-mail: [email protected]. Phone: +33 4 72 44 54 92.
Cite this: Environ. Sci. Technol. 2015, 49, 22, 13199–13205
Publication Date (Web):September 10, 2015
https://doi.org/10.1021/acs.est.5b02388
Copyright © 2015 American Chemical Society
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Abstract

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Isoprene is an important reactive gas that is produced mainly in terrestrial ecosystems but is also produced in marine ecosystems. In the marine environment, isoprene is produced in the seawater by various biological processes. Here, we show that photosensitized reactions involving the sea-surface microlayer lead to the production of significant amounts of isoprene. It is suggested that H-abstraction processes are initiated by photochemically excited dissolved organic matter which will the degrade fatty acids acting as surfactants. This chemical interfacial processing may represent a significant abiotic source of isoprene in the marine boundary layer.

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