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Rational Design of Antifouling Polymeric Nanocomposite for Sustainable Fluoride Removal from NOM-Rich Water
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    Rational Design of Antifouling Polymeric Nanocomposite for Sustainable Fluoride Removal from NOM-Rich Water
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    State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China
    Research Center for Environmental Nanotechnology (ReCENT), Nanjing University, Nanjing 210023, China
    *E-mail: [email protected]. Tel: +86-25-8968-0390.
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    Environmental Science & Technology

    Cite this: Environ. Sci. Technol. 2017, 51, 22, 13363–13371
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    https://doi.org/10.1021/acs.est.7b04164
    Published November 1, 2017
    Copyright © 2017 American Chemical Society

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    The presence of natural organic matter (NOM) exerts adverse effects on adsorptive removal of various pollutants including fluoride from water. Herein, we designed a novel nanocomposite adsorbent for preferable and sustainable defluoridation from NOM-rich water. The nanocomposite (HZO@HCA) is obtained by encapsulating hydrous zirconium oxide nanoparticles (HZO NPs) inside hyper-cross-linked polystyrene anion exchanger (HCA) binding tertiary amine groups. Another commercially available nanocomposite HZO@D201, with the host of a cross-linked polystyrene anion exchanger (D201) binding ammonium groups, was involved for comparison. HZO@HCA features with abundant micropores instead of meso-/macropores of HZO@D201, resulting in the inaccessible sites for NOM due to the size exclusion. Also, the tertiary amine groups of HCA favor an efficient desorption of the slightly loaded NOM from HZO@HCA. As expected, Sigma-Aldrich humic acid even at 20 mg of DOC/L did not exert any observable effect on fluoride sequestration by HZO@HCA, whereas a significant inhibition was observed for HZO@D201. Cyclic adsorption runs further verified the superior reusability of HZO@HCA for defluoridation from NOM-rich water. In addition, the HZO@HCA column could generate ∼80 bed volume (BV) effluent from a synthetic fluoride-containing groundwater to meet the drinking water standard (<1.5 mg F/L), whereas HCA and HZO@D201 columns could only generate <5 and ∼40 BV effluents, respectively. This study is believed to shed new light on how to rationally design antifouling nanocomposites for water remediation.

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    Environmental Science & Technology

    Cite this: Environ. Sci. Technol. 2017, 51, 22, 13363–13371
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    https://doi.org/10.1021/acs.est.7b04164
    Published November 1, 2017
    Copyright © 2017 American Chemical Society

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