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Shaping of Alginate–Silica Hybrid Materials into Microspheres through Vibrating-Nozzle Technology and Their Use for the Recovery of Neodymium from Aqueous Solutions
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    Shaping of Alginate–Silica Hybrid Materials into Microspheres through Vibrating-Nozzle Technology and Their Use for the Recovery of Neodymium from Aqueous Solutions
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    Sustainable Materials Management, Flemish Institute for Technological Research (VITO), Boeretang 200, 2400 Mol, Belgium
    Department of Chemistry, KU Leuven, Celestijnenlaan 200F, P.O. Box 2404, 3001 Heverlee, Belgium
    § Department of Chemistry, University of Antwerp, Universiteitsplein 1, 2610 Wilrijk, Belgium
    *E-mail: [email protected]. Tel: +32 16 32 7446.
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    Industrial & Engineering Chemistry Research

    Cite this: Ind. Eng. Chem. Res. 2015, 54, 51, 12836–12846
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    https://doi.org/10.1021/acs.iecr.5b03494
    Published November 30, 2015
    Copyright © 2015 American Chemical Society

    Abstract

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    The vibrating-nozzle technology is very interesting to very easily and very rapidly produce industrial amounts of functional microspheres. The technology was used to make hybrid alginate–silica microspheres by droplet coagulation. The microspheres were formed starting from suspensions of sodium alginate, and coagulation occurred in an aqueous solution of calcium ions. To enhance the mechanical properties of the alginate raw material, it was combined with two different silica sources: tetramethyl orthosilicate (TMOS) and commercial silica powder. The two different batches of alginate–silica microspheres were fully compared with regard to their morphology, composition, shrinking behavior, and stability in acidic conditions. It was shown that the incorporation of an inorganic matrix resulted in a material with a better stabilized porous structure and a higher resistance in an acidic environment. Both are important when functional particles are designed to be used for adsorption of metal ions, either as a stirred suspension or as a stationary phase in a chromatographic column. A study of the adsorption performance was conducted in batch mode for neodymium(III), a representative element for the group of critical rare-earth elements. The effect of stripping (desorption) on the adsorption performance and reusability was also investigated. The functional alginate–silica microspheres show a sustainable character.

    Copyright © 2015 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.iecr.5b03494.

    • Ostwald–de Waele model fitting parameters for suspension viscosities, experimental parameters for vibrational droplet coagulation experiments, FTIR spectra, shrinkage data resulting from different drying techniques, TGA traces, CaII release as a function of the HCl concentration, and stripping percentage as a function of the HCl concentration (PDF)

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    Industrial & Engineering Chemistry Research

    Cite this: Ind. Eng. Chem. Res. 2015, 54, 51, 12836–12846
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.iecr.5b03494
    Published November 30, 2015
    Copyright © 2015 American Chemical Society

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