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Rational Synthesis of Hyperbranched Poly(ester)s
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    Rational Synthesis of Hyperbranched Poly(ester)s
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    Michigan State University − Saint Andrews Campus, 1910 W. St. Andrews Rd., Midland, Michigan 48640, United States
    Center for Applications in Polymer Science Department of Chemistry, Central Michigan University, Mt. Pleasant, Michigan 48859-0001, United States
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    Industrial & Engineering Chemistry Research

    Cite this: Ind. Eng. Chem. Res. 2017, 56, 6, 1661–1670
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    https://doi.org/10.1021/acs.iecr.6b04435
    Published January 19, 2017
    Copyright © 2017 American Chemical Society

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    Hyperbranched poly(ester)s have a variety of unique properties as a result of their abundance of end groups which make them useful in a range of applications. The synthesis of hyperbranched polymers has generally been carried out using empirically derived procedures to avoid gelation. However, such synthetic strategies lead to materials with unpredictable molecular weight and properties. It has now been demonstrated that modeling may be utilized to direct the synthesis of hyperbranched poly(ester)s from a variety of monomers to form well-defined structures and terminal-group functionality while avoiding gelation. In particular, Macosko–Miller modeling permits the synthesis of hyperbranched poly(ester)s of specific molecular weights and end-group functionality even for multifunctional monomers for which functional groups are not equally reactive.

    Copyright © 2017 American Chemical Society

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    This article is cited by 34 publications.

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    Industrial & Engineering Chemistry Research

    Cite this: Ind. Eng. Chem. Res. 2017, 56, 6, 1661–1670
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.iecr.6b04435
    Published January 19, 2017
    Copyright © 2017 American Chemical Society

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