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Self-Assembly of Tetrameric and Hexameric Terpyridine-Based Macrocycles Using Cd(II), Zn(II), and Fe(II)
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    Self-Assembly of Tetrameric and Hexameric Terpyridine-Based Macrocycles Using Cd(II), Zn(II), and Fe(II)
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    • Lei Wang
      Lei Wang
      Department of Chemistry, University of South Florida, Tampa, Florida 33620, United States
      More by Lei Wang
    • Zhe Zhang
      Zhe Zhang
      Department of Chemistry, University of South Florida, Tampa, Florida 33620, United States
      College of Chemistry, Central China Normal University, Wuhan 430079, China
      More by Zhe Zhang
    • Xin Jiang
      Xin Jiang
      State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin 130012, China
      More by Xin Jiang
    • Jennifer A. Irvin
      Jennifer A. Irvin
      Department of Chemistry and Biochemistry, Texas State University, San Marcos, Texas 78666, United States
    • Changlin Liu
      Changlin Liu
      College of Chemistry, Central China Normal University, Wuhan 430079, China
      More by Changlin Liu
    • Ming Wang*
      Ming Wang
      State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin 130012, China
      *E-mail: [email protected] (M.W.).
      More by Ming Wang
    • Xiaopeng Li*
      Xiaopeng Li
      Department of Chemistry, University of South Florida, Tampa, Florida 33620, United States
      *E-mail: [email protected] (X.L.).
      More by Xiaopeng Li
    Other Access OptionsSupporting Information (1)

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2018, 57, 7, 3548–3558
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    https://doi.org/10.1021/acs.inorgchem.7b02361
    Published November 22, 2017
    Copyright © 2017 American Chemical Society

    Abstract

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    The self-assembly behavior of a tritopic 2,2′:6′,2″-terpyridine (tpy) ligand with Cd(II), Zn(II), and Fe(II) has been exploited herein to generate a series of tetrameric and hexameric macrocycles. The main advantage of using such transition metals with an octahedral coordination geometry is their distinct coordination abilities (e.g., binding strength and reversibility). With the same ligand, this study reveals that the supramolecular structural variation between tetrameric and hexameric macrocycle architectures can be precisely controlled using different metal ions with the same coordination geometry. When Cd(II) was used, a tetrameric macrocycle was the only observed structure in the self-assembly, whereas Zn(II) and Fe(II) assembled a mixture of tetrameric and hexameric macrocycles. Because of the high stability of Fe(II) as the coordination center, we successfully isolated tetrameric and hexameric macrocycles using a regular column. In-depth characterization was carried out to establish the proposed structures, including multinuclear NMR (1H, 19F, and 13C) analysis, electrospray ionization mass spectrometry, and 2D ion-mobility mass spectrometry.

    Copyright © 2017 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.7b02361.

    • Synthesis details for compounds 25, NMR spectra (1H, 13C, and 19F 2D COSY), and ESI-MS isotope patterns for complexes Cd6L4, Zn6L4, Zn9L6, Fe6L4, and Fe9L6 (PDF)

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    Cited By

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    This article is cited by 21 publications.

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2018, 57, 7, 3548–3558
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.7b02361
    Published November 22, 2017
    Copyright © 2017 American Chemical Society

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