Self-Assembly of Tetrameric and Hexameric Terpyridine-Based Macrocycles Using Cd(II), Zn(II), and Fe(II)Click to copy article linkArticle link copied!
- Lei WangLei WangDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United StatesMore by Lei Wang
- Zhe ZhangZhe ZhangDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United StatesCollege of Chemistry, Central China Normal University, Wuhan 430079, ChinaMore by Zhe Zhang
- Xin JiangXin JiangState Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin 130012, ChinaMore by Xin Jiang
- Jennifer A. IrvinJennifer A. IrvinDepartment of Chemistry and Biochemistry, Texas State University, San Marcos, Texas 78666, United StatesMore by Jennifer A. Irvin
- Changlin LiuChanglin LiuCollege of Chemistry, Central China Normal University, Wuhan 430079, ChinaMore by Changlin Liu
- Ming Wang*Ming Wang*E-mail: [email protected] (M.W.).State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin 130012, ChinaMore by Ming Wang
- Xiaopeng Li*Xiaopeng Li*E-mail: [email protected] (X.L.).Department of Chemistry, University of South Florida, Tampa, Florida 33620, United StatesMore by Xiaopeng Li
Abstract
The self-assembly behavior of a tritopic 2,2′:6′,2″-terpyridine (tpy) ligand with Cd(II), Zn(II), and Fe(II) has been exploited herein to generate a series of tetrameric and hexameric macrocycles. The main advantage of using such transition metals with an octahedral coordination geometry is their distinct coordination abilities (e.g., binding strength and reversibility). With the same ligand, this study reveals that the supramolecular structural variation between tetrameric and hexameric macrocycle architectures can be precisely controlled using different metal ions with the same coordination geometry. When Cd(II) was used, a tetrameric macrocycle was the only observed structure in the self-assembly, whereas Zn(II) and Fe(II) assembled a mixture of tetrameric and hexameric macrocycles. Because of the high stability of Fe(II) as the coordination center, we successfully isolated tetrameric and hexameric macrocycles using a regular column. In-depth characterization was carried out to establish the proposed structures, including multinuclear NMR (1H, 19F, and 13C) analysis, electrospray ionization mass spectrometry, and 2D ion-mobility mass spectrometry.
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