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Introduction of Molecular Building Blocks to Improve the Stability of Metal–Organic Frameworks for Efficient Mercury Removal

  • Shu-Yi Jiang
    Shu-Yi Jiang
    Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024 Jilin, China
    More by Shu-Yi Jiang
  • Wen-Wen He
    Wen-Wen He
    School of Chemistry and Life Science, Advanced Institute of Materials Science, Changchun University of Technology, Changchun 130012, China
    More by Wen-Wen He
  • Shun-Li Li
    Shun-Li Li
    China Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023 Jiangsu, China
    More by Shun-Li Li
  • Zhong-Min Su*
    Zhong-Min Su
    Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024 Jilin, China
    *E-mail: [email protected]
    More by Zhong-Min Su
  • , and 
  • Ya-Qian Lan*
    Ya-Qian Lan
    China Jiangsu Key Laboratory of Biofunctional Materials, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing, 210023 Jiangsu, China
    *E-mail: [email protected]
    More by Ya-Qian Lan
Cite this: Inorg. Chem. 2018, 57, 10, 6118–6123
Publication Date (Web):May 8, 2018
https://doi.org/10.1021/acs.inorgchem.8b00704
Copyright © 2018 American Chemical Society

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    Abstract

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    With expanding human needs, many heavy metals were mined, smelted, processed, and manufactured for commercialization, which caused serious environmental pollutions. Currently, many adsorption materials are applied in the field of adsorption of heavy metals. Among them, the principle of many mercury adsorbents is based on the interaction between mercury and sulfur. Here, a S-containing metal–organic framework NENU-400 was synthesized for effective mercury extraction. Unfortunately, the skeleton of NENU-400 collapsed easily when exposed to the mercury liquid solution. To improve the stability, a synthetic strategy installing molecular building blocks (MBBs) into the channels was used. Modified by the MBBs, a more stable nanoporous framework was synthesized, which not only exhibits a high capacity of saturation mercury uptake but also shows high selectivity and efficient recyclability.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.8b00704.

    • Ligand synthesis, crystal data, general procedures for Hg(II) adsorption, PXRD patterns, TGA curves, XPS spectra, and IR spectra (PDF)

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    CCDC 15841391584140 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

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