Stereoselective Synthesis of Conjugated Polyenes Based on Tethered Olefin Metathesis and Carbonyl Olefination: Application to the Total Synthesis of (+)-Bretonin BClick to copy article linkArticle link copied!
- Kajsa LoodKajsa LoodUniversität Potsdam, Institut für Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam-Golm, GermanyMore by Kajsa Lood
- Bernd Schmidt*Bernd Schmidt*Email: [email protected]Universität Potsdam, Institut für Chemie, Karl-Liebknecht-Strasse 24-25, D-14476 Potsdam-Golm, GermanyMore by Bernd Schmidt
Abstract
The combination of a highly stereoselective tethered olefin metathesis reaction and a Julia–Kocienski olefination is presented as a strategy for the synthesis of conjugated polyenes with at least one Z-configured C═C bond. The strategy is exemplified by the synthesis of the marine natural product (+)-bretonin B.
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This article is cited by 4 publications.
- Jie Jack Li. Julia–Kocienski Olefinierung. 2024, 303-306. https://doi.org/10.1007/978-3-031-52850-7_75
- Capucine Jourdain de Muizon, Céline Moriou, Sylvain Petek, Merrick Ekins, Marthe Rousseau, Ali Al Mourabit. Isolation, Synthesis and Absolute Configuration of the Pericharaxins A and B, Epimeric Hydroxy-Polyene Glycerol Ethers from the Calcarean Sponge Pericharax heteroraphis. Marine Drugs 2022, 20
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, 635. https://doi.org/10.3390/md20100635
- Pulluparambil Xavier Thresia Rinu, Sankaran Radhika, Gopinathan Anilkumar. Recent Applications and Trends in the Julia‐Kocienski Olefination. ChemistrySelect 2022, 7
(31)
https://doi.org/10.1002/slct.202200760
- Jie Jack Li. Julia–Kocienski Olefination. 2021, 288-290. https://doi.org/10.1007/978-3-030-50865-4_75
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