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High-Pressure Chemistry of Graphene Oxide in the Presence of Ar, N2, and NH3

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Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. C 2016, 120, 9, 5174-5187
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    High-Pressure Chemistry of Graphene Oxide in the Presence of Ar, N2, and NH3
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    † LENS, European Laboratory for Non-Linear Spectroscopy, Via N. Carrara 1, I-50019 Sesto Fiorentino, Firenze, Italy
    ‡ ICCOM-CNR, Institute of Chemistry of OrganoMetallic Compounds, National Research Council of Italy, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Firenze, Italy
    § Kazan Federal University, 420008 Kazan, Russian Federation
    ∥ ESRF, European Synchrotron Radiation Facility, 6 rue Jules Horowitz, BP 220, F-38043 Grenoble, Cedex, France
    ⊥ Dipartimento di Chimica “Ugo Schiff”, Università degli Studi di Firenze, Via della Lastruccia 3, I-50019 Sesto Fiorentino, Firenze, Italy
    *E-mail [email protected], [email protected] (M.C.).
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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2016, 120, 9, 5174–5187
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    https://doi.org/10.1021/acs.jpcc.5b12274
    Published February 12, 2016
    Copyright © 2016 American Chemical Society
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    Abstract

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    The high pressure structural and reactive beahvior of graphene oxide (GO) in the presence of Ar, N2, and NH3 was studied in diamond anvil cells (DAC) by X-ray diffraction (XRD) and vibrational spectroscopy (FTIR and Raman), with the purpose of investigating the use of pressure for N-doping and functionalization of GO in high-density conditions. The pressure evolution of the interlayer d-spacing of GO during room temperature compression and decompression indicates the pressure-induced insertion of the selected systems between the GO layers and the stability of the GO layered structure at high pressure. Thermal and photoinduced reactivity was studied in GO with N2 and in GO with NH3 in different pressure conditions. The comparison of the infrared spectra of the recovered samples at ambient conditions with respect to the starting GO provides evidence for the occurrence of chemical reactivity of N2 and NH3 with GO, leading to N incorporation and GO functionalization, as also confirmed by the Raman spectra. The observed reactivity opens new perspectives for the high-pressure chemistry of GO and carbon-based nanostructured systems.

    Copyright © 2016 American Chemical Society

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jpcc.5b12274.

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    Cited By

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    This article is cited by 7 publications.

    1. Demetrio Scelta, Adhara Baldassarre, Manuel Serrano-Ruiz, Alexey Marchuk, Sebastian Vogel, Wolfgang Schnick, Maurizio Peruzzini, Roberto Bini, Matteo Ceppatelli. High-Pressure Synthesis of Cyclic Phosphazenes by Near-UV Photoinduced Reactivity of NH3 and Elemental Phosphorus. The Journal of Physical Chemistry C 2020, 124 (7) , 4308-4319. https://doi.org/10.1021/acs.jpcc.9b11462
    2. Giuseppina Balassone, Dominik Talla, Anton Beran, Fabio Bellatreccia. Infrared Spectroscopy and Application to Forensics. 2023, 93-140. https://doi.org/10.1007/978-3-031-08834-6_4
    3. Yiwei Sun, Paolo Passaretti, Ignacio Hernandez, Jesus Gonzalez, Wei Liu, Fernando Rodriguez, David J. Dunstan, Pola Goldberg Oppenheimer, Colin J. Humphreys. Nanomechanics of graphene oxide-bacteriophage based self-assembled porous composites. Scientific Reports 2020, 10 (1) https://doi.org/10.1038/s41598-020-72372-1
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    5. Han Lin, Yifan Li, Jiahua Zhu. Cross-linked GO membranes assembled with GO nanosheets of differently sized lateral dimensions for organic dye and chromium separation. Journal of Membrane Science 2020, 598 , 117789. https://doi.org/10.1016/j.memsci.2019.117789
    6. Karuna Kara Mishra, Kalpataru Panda, Niranjan Kumar, Deepika Malpani, T.R. Ravindran, Om P. Khatri. Nanofluid lubrication and high pressure Raman studies of oxygen functionalized graphene nanosheets. Journal of Industrial and Engineering Chemistry 2018, 61 , 97-105. https://doi.org/10.1016/j.jiec.2017.12.005
    7. Demetrio Scelta, Matteo Ceppatelli, Riccardo Ballerini, Ahmed Hajeb, Maurizio Peruzzini, Roberto Bini. Spray-loading: A cryogenic deposition method for diamond anvil cell. Review of Scientific Instruments 2018, 89 (5) https://doi.org/10.1063/1.5011286
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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2016, 120, 9, 5174–5187
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jpcc.5b12274
    Published February 12, 2016
    Copyright © 2016 American Chemical Society
    Request reuse permissions

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