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High-Throughput Stamping of Hybrid Functional Surfaces

  • Muhammad Jahidul Hoque
    Muhammad Jahidul Hoque
    Department of Mechanical Science and Engineering, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States
  • Xiao Yan
    Xiao Yan
    Department of Mechanical Science and Engineering, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States
    More by Xiao Yan
  • Hohyun Keum
    Hohyun Keum
    Department of Mechanical Science and Engineering, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States
    More by Hohyun Keum
  • Longnan Li
    Longnan Li
    Department of Mechanical Science and Engineering, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States
    More by Longnan Li
  • Hyeongyun Cha
    Hyeongyun Cha
    Department of Mechanical Science and Engineering, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States
  • Jun Kyu Park
    Jun Kyu Park
    Department of Mechanical Science and Engineering, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States
    More by Jun Kyu Park
  • Seok Kim*
    Seok Kim
    Department of Mechanical Science and Engineering, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States
    *Email: [email protected]
    More by Seok Kim
  • , and 
  • Nenad Miljkovic*
    Nenad Miljkovic
    Department of Mechanical Science and Engineering, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States
    Department of Electrical and Computer Engineering, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States
    Materials Research Laboratory, University of Illinois at Urbana−Champaign, Urbana, Illinois 61801, United States
    International Institute for Carbon Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395, Japan
    *Email: [email protected]
Cite this: Langmuir 2020, 36, 21, 5730–5744
Publication Date (Web):May 5, 2020
https://doi.org/10.1021/acs.langmuir.0c00416
Copyright © 2020 American Chemical Society

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    Abstract

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    Hydrophobic–hydrophilic hybrid surfaces, sometimes termed biphilic surfaces, have shown potential to enhance condensation and boiling heat transfer, anti-icing, and fog harvesting performance. However, state of art techniques to develop these surfaces have limited substrate selection, poor scalability, and lengthy and costly fabrication methods. Here, we develop a simple, scalable, and rapid stamping technique for hybrid surfaces with spatially controlled wettability. To enable stamping, rationally designed and prefabricated polydimethylsiloxane (PDMS) stamps, which are reusable and independent of the substrate and functional coating, were used. To demonstrate the stamping technique, we used silicon wafer, copper, and aluminum substrates functionalized with a variety of hydrophobic chemistries including heptadecafluorodecyltrimethoxy-silane, octafluorocyclobutane, and slippery omniphobic covalently attached liquids. Condensation experiments and microgoniometric characterization demonstrated that the stamped surfaces have global hydrophobicity or superhydrophobicity with localized hydrophilicity (spots) enabled by local removal of the functional coating during stamping. Stamped surfaces with superhydrophobic backgrounds and hydrophilic spots demonstrated stable coalescence induced droplet jumping. Compared to conventional techniques, our stamping method has comparable prototyping cost with reduced manufacturing time scale and cost. Our work not only presents design guidelines for the development of scalable hybrid surfaces for the study of phase change phenomena, it develops a scalable and rapid stamping protocol for the cost-effective manufacture of next-generation hybrid wettability surfaces.

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.langmuir.0c00416.

    • Details of different surface fabrication (Sections S1 to S4); experimental setup (Section S5); scalability and uniformity (Section S6); additional condensation results (Section S7); durability of hybrid surfaces (Section S8); long time scales condensation (Section S9); Videos S1 to S4 (Section S10); and effects of stamping load on surface (Section S11) (PDF)

    • Side-view high-speed microscopy video of coalescence and jumping of binary equally sized water droplets on the homogeneous superhydrophobic surface (AVI)

    • Side-view high-speed microscopy video of coalescence and jumping of binary equally sized water droplets on the stamped hybrid surface (AVI)

    • Top-view high-speed microscopy video showing jumping of six droplets cluster (AVI)

    • Top-view optical microscopy video of atmospheric water vapor condensation on the superhydrophobic hybrid surface (AVI)

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    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 24 publications.

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