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Microgels with Linear Thermosensitivity in a Wide Temperature Range
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    Microgels with Linear Thermosensitivity in a Wide Temperature Range
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    State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science, and Laboratory of Advanced Materials, Fudan University, Shanghai 200433, China
    *E-mail [email protected]; phone 021-65643255 (P.Y.).
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    Macromolecules

    Cite this: Macromolecules 2016, 49, 16, 6095–6100
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    https://doi.org/10.1021/acs.macromol.6b01359
    Published August 11, 2016
    Copyright © 2016 American Chemical Society

    Abstract

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    A newly developed poly(2-methoxyethyl acrylate-co-oligo(ethylene glycol) methyl ether acrylate) (P(MEA-co-OEGA) microgel, synthesized by free radical precipitation copolymerization, displays a linear volume phase transition in water upon heating in a wide range of temperature. Varying cross-linking density in the microgels does not interrupt the linear thermosensitivity. By changing the feeding molar ratio of MEA and OEGA, the linear thermosensitive temperature range can be adjusted, where higher OEGA content results in higher plateau starting temperature. Furthermore, temperature- and pH-sensitive microgels could be achieved by adding another comonomer, acrylic acid (AA). The resulting P(MEA-co-OEGA-co-AA) microgels are ideal candidates to prepare hybrid microgels by in situ formation of silver nanoparticles (AgNPs).

    Copyright © 2016 American Chemical Society

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    This article is cited by 23 publications.

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    Macromolecules

    Cite this: Macromolecules 2016, 49, 16, 6095–6100
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.macromol.6b01359
    Published August 11, 2016
    Copyright © 2016 American Chemical Society

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