Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Water-Triggered Ductile–Brittle Transition of Anisotropic Lamellar Hydrogels and Effect of Confinement on Polymer Dynamics

View Author Information
‡ § Graduate School of Life Science, Faculty of Advanced Life Science, and §Soft Matter GI-CoRE, Hokkaido University, N21W11, Kita-ku, Sapporo 001-0021, Japan
Department of Chemistry, University of Dhaka, Dhaka, Bangladesh
*E-mail [email protected], Tel/fax + 81-11-706-9011 (J.P.G.).
Cite this: Macromolecules 2017, 50, 20, 8169–8177
Publication Date (Web):October 4, 2017
https://doi.org/10.1021/acs.macromol.7b01438
Copyright © 2017 American Chemical Society

    Article Views

    1832

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (1)»

    Abstract

    Abstract Image

    We study the effect of dehydration on the structure and mechanical properties of anisotropic lamellar hydrogels, consisting of alternative stacking of several thousands of nanoscale rigid bilayers from amphiphilic poly(dodecyl glyceryl itaconate) (PDGI) and submicroscale soft hydrogel layers from hydrophilic polyacrylamide (PAAm) networks. We found that the layered microstructure is well preserved with dehydration, and a ductile–brittle transition occurs at the critical water content. This transition is related to the rubbery–glassy transition of the PAAm layers, which occurs at 58 wt % water content and is much higher than 26 wt % of bulk PAAm hydrogels. Such specific behavior of the lamellar hydrogels indicates that the dynamics of the submicroscale PAAm hydrated layer intercalated between the rigid bilayers are very different from its bulk state.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.macromol.7b01438.

    • Additional results and discussions related to microstructure analysis (SEM) of the substantially dehydrated samples, thermogravimetric analysis (TGA) for measuring water content, photographs of the dumbbell-shaped samples at different water content, toughness of gels, and differential scanning calorimetry (DSC) for measuring enthalpy change of different water content gels (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 28 publications.

    1. Milena Lama, Jian Ping Gong. Mechanical Reinforcement of Lamellar Bilayer Hydrogels by Small Amounts of Co-surfactants. ACS Omega 2023, 8 (28) , 25185-25194. https://doi.org/10.1021/acsomega.3c02274
    2. Noy Cohen, Cong Du, Zi Liang Wu. Understanding the Dissociation of Hydrogen Bond Based Cross-Links In Hydrogels Due to Hydration and Mechanical Forces. Macromolecules 2021, 54 (24) , 11316-11325. https://doi.org/10.1021/acs.macromol.1c01927
    3. Xiansheng Zhang, Hongwei Yan, Chongzhi Xu, Xia Dong, Yu Wang, Aiping Fu, Hao Li, Jin Yong Lee, Sheng Zhang, Jiahua Ni, Min Gao, Jing Wang, Jinpeng Yu, Shuzhi Sam Ge, Ming Liang Jin, Lili Wang, Yanzhi Xia. Skin-like cryogel electronics from suppressed-freezing tuned polymer amorphization. Nature Communications 2023, 14 (1) https://doi.org/10.1038/s41467-023-40792-y
    4. Junju Wang, Jie Tang, Yichao Lin, Hong He, Chaoshan Zhao, Wenrui Ma, Xiang Wang, Muling Zeng, Shunbo Li. Construction of organic–inorganic hybrid heterostructure towards solvent responsive hydrogel with high stiffness. Smart Materials and Structures 2023, 32 (8) , 085018. https://doi.org/10.1088/1361-665X/ace174
    5. Yunpeng Wang, Huimin Zhang, Shufen Zhang, Wenbin Niu. Squid-inspired photonic-ionic skin with anti-freezing, drying-tolerance, and antibacterial abilities for wirelessly interactive multi-sensing. Chemical Engineering Journal 2023, 462 , 142290. https://doi.org/10.1016/j.cej.2023.142290
    6. Anaïs Giustiniani, Muhammad Ilyas, Tsutomu Indei, Jian Ping Gong. Relaxation mechanisms in hydrogels with uniaxially oriented lamellar bilayers. Polymer 2023, 267 , 125686. https://doi.org/10.1016/j.polymer.2023.125686
    7. Chiharu Ueda, Junsu Park, Kazuya Hirose, Subaru Konishi, Yuka Ikemoto, Motofumi Osaki, Hiroyasu Yamaguchi, Akira Harada, Masaru Tanaka, Go Watanabe, Yoshinori Takashima. Behavior of supramolecular cross-links formed by host-guest interactions in hydrogels responding to water contents. Supramolecular Materials 2022, 1 , 100001. https://doi.org/10.1016/j.supmat.2021.100001
    8. Wenpeng Zhao, Zixiang Zhang, Jian Hu, Xianqi Feng, Jun Xu, Yumin Wu, Shouke Yan. Robust and ultra-fast self-healing elastomers with hierarchically anisotropic structures and used for wearable sensors. Chemical Engineering Journal 2022, 446 , 137305. https://doi.org/10.1016/j.cej.2022.137305
    9. Zhichao Sun, Yaxin Hu, Cong Wei, Rui Hao, Chaobo Hao, Wentao Liu, Hao Liu, Miaoming Huang, Suqin He, Mingcheng Yang. Transparent, photothermal and stretchable alginate-based hydrogels for remote actuation and human motion sensing. Carbohydrate Polymers 2022, 293 , 119727. https://doi.org/10.1016/j.carbpol.2022.119727
    10. Xuan Lin, Xianwei Zhao, Chongzhi Xu, Lili Wang, Yanzhi Xia. Progress in the mechanical enhancement of hydrogels: Fabrication strategies and underlying mechanisms. Journal of Polymer Science 2022, 60 (17) , 2525-2542. https://doi.org/10.1002/pol.20220154
    11. Vivek P. Chavda, Shilpa Dawre, Anjali Pandya, Lalitkumar K. Vora, Dharti H. Modh, Vidhi Shah, Divyang J. Dave, Vandana Patravale. Lyotropic liquid crystals for parenteral drug delivery. Journal of Controlled Release 2022, 349 , 533-549. https://doi.org/10.1016/j.jconrel.2022.06.062
    12. Md. Tariful Islam Mredha, Insu Jeon. Biomimetic anisotropic hydrogels: Advanced fabrication strategies, extraordinary functionalities, and broad applications. Progress in Materials Science 2022, 124 , 100870. https://doi.org/10.1016/j.pmatsci.2021.100870
    13. Chang-Cheng Wang, Rong Zhang, Shiqi Li, Guangsu Huang, Maozhu Tang, Yun-Xiang Xu. Influence of Oligopeptide Length and Distribution on Polyisoprene Properties. Polymers 2021, 13 (24) , 4408. https://doi.org/10.3390/polym13244408
    14. Ziyu Xing, Peizhao Li, Haibao Lu, Yong Qing Fu. Mechanoresponsive resonance differences in double-network hydrogels towards multipartite dynamics. Journal of Physics D: Applied Physics 2021, 54 (46) , 465301. https://doi.org/10.1088/1361-6463/ac1e4f
    15. Youfeng Yue, Jian Ping Gong. Structure and Unique Functions of Anisotropic Hydrogels Comprising Uniaxially Aligned Lamellar Bilayers. Bulletin of the Chemical Society of Japan 2021, 94 (9) , 2221-2234. https://doi.org/10.1246/bcsj.20210209
    16. Francesca Scarpelli, Loredana Ricciardi, Massimo La Deda, Elvira Brunelli, Alessandra Crispini, Mauro Ghedini, Nicolas Godbert, Iolinda Aiello. A luminescent lyotropic liquid-crystalline gel of a water-soluble Ir(III) complex. Journal of Molecular Liquids 2021, 334 , 116187. https://doi.org/10.1016/j.molliq.2021.116187
    17. Ziyu Xing, Haibao Lu, Mokarram Hossain. Renormalized Flory‐Huggins lattice model of physicochemical kinetics and dynamic complexity in self‐healing double‐network hydrogel. Journal of Applied Polymer Science 2021, 138 (17) https://doi.org/10.1002/app.50304
    18. Ziyu Xing, Haibao Lu, Ansu Sun, Yong Qing Fu, Muhammad Wakil Shahzad, Ben Bin Xu. Understanding complex dynamics of interfacial reconstruction in polyampholyte hydrogels undergoing mechano-chemo-electrotaxis coupling. Journal of Physics D: Applied Physics 2021, 54 (8) , 085301. https://doi.org/10.1088/1361-6463/abc649
    19. Ziyu Xing, Haibao Lu, Yong Qing Fu. A dynamic model of complexly mechanoresponsive chain-poly[n]-catenations in double-network polyampholyte hydrogels. Smart Materials and Structures 2021, 30 (1) , 015027. https://doi.org/10.1088/1361-665X/abc872
    20. Jae-Man Park, Jinwoo Park, Young-Hoon Kim, Huanyu Zhou, Younghoon Lee, Seung Hyeon Jo, Jinwoo Ma, Tae-Woo Lee, Jeong-Yun Sun. Aromatic nonpolar organogels for efficient and stable perovskite green emitters. Nature Communications 2020, 11 (1) https://doi.org/10.1038/s41467-020-18383-y
    21. Haibao Lu, Ziyu Xing, Mokarram Hossain, Jinsong Leng. Scaling dynamics of globule-to-coil phase transition in double-network hydrogel with ultra-high stretchable strength. Smart Materials and Structures 2020, 29 (8) , 085050. https://doi.org/10.1088/1361-665X/ab9e0c
    22. Yunpeng Wang, Wenbin Niu, Chiao‐Yueh Lo, Yusen Zhao, Ximin He, Guorui Zhang, Suli Wu, Benzhi Ju, Shufen Zhang. Interactively Full‐Color Changeable Electronic Fiber Sensor with High Stretchability and Rapid Response. Advanced Functional Materials 2020, 30 (19) https://doi.org/10.1002/adfm.202000356
    23. Katja Steck, Sonja Dieterich, Cosima Stubenrauch, Frank Giesselmann. Surfactant-based lyotropic liquid crystal gels – the interplay between anisotropic order and gel formation. Journal of Materials Chemistry C 2020, 8 (16) , 5335-5348. https://doi.org/10.1039/D0TC00561D
    24. Ghazi Ben Messaoud, Patrick Le Griel, Sylvain Prévost, Daniel Hermida-Merino, Wim Soetaert, Sophie L. K. W. Roelants, Christian V. Stevens, Niki Baccile. Single-molecule lamellar hydrogels from bolaform microbial glucolipids. Soft Matter 2020, 16 (10) , 2528-2539. https://doi.org/10.1039/C9SM02158B
    25. Ghazi Ben Messaoud, Patrick Le Griel, Daniel Hermida-Merino, Niki Baccile. Effects of pH, temperature and shear on the structure–property relationship of lamellar hydrogels from microbial glucolipids probed by in situ rheo-SAXS. Soft Matter 2020, 16 (10) , 2540-2551. https://doi.org/10.1039/C9SM02494H
    26. Takayuki Nonoyama, Yong Woo Lee, Kumi Ota, Keigo Fujioka, Wei Hong, Jian Ping Gong. Instant Thermal Switching from Soft Hydrogel to Rigid Plastics Inspired by Thermophile Proteins. Advanced Materials 2020, 32 (4) https://doi.org/10.1002/adma.201905878
    27. Lili Wang, Xiansheng Zhang, Yanzhi Xia, Xianwei Zhao, Zhixin Xue, Kunyan Sui, Xia Dong, Dujin Wang. Cooking‐Inspired Versatile Design of an Ultrastrong and Tough Polysaccharide Hydrogel through Programmed Supramolecular Interactions. Advanced Materials 2019, 31 (41) https://doi.org/10.1002/adma.201902381
    28. Heqin Huang, Yang Yang, Xiaojie Wang, Florian Rehfeldt, Kai Zhang. Thermoresponsive Water Transportation in Dually Electrostatically Crosslinked Nanocomposite Hydrogels. Macromolecular Rapid Communications 2019, 40 (19) https://doi.org/10.1002/marc.201900317