Band Renormalization of Blue Phosphorus on Au(111)Click to copy article linkArticle link copied!
- Evangelos Golias*Evangelos Golias*(E.G.) E-mail: [email protected]Helmholtz-Zentrum Berlin für Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein Straße 15, 12489 Berlin, GermanyInstitut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, 14195 Berlin, GermanyMore by Evangelos Golias
- Maxim KrivenkovMaxim KrivenkovHelmholtz-Zentrum Berlin für Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein Straße 15, 12489 Berlin, GermanyMore by Maxim Krivenkov
- Andrei VarykhalovAndrei VarykhalovHelmholtz-Zentrum Berlin für Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein Straße 15, 12489 Berlin, GermanyMore by Andrei Varykhalov
- Jaime Sánchez-BarrigaJaime Sánchez-BarrigaHelmholtz-Zentrum Berlin für Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein Straße 15, 12489 Berlin, GermanyMore by Jaime Sánchez-Barriga
- Oliver RaderOliver RaderHelmholtz-Zentrum Berlin für Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein Straße 15, 12489 Berlin, GermanyMore by Oliver Rader
Abstract
Most recently, theoretical calculations predicted the stability of a novel two-dimensional phosphorus honeycomb lattice named blue phosphorus. Here, we report on the growth of blue phosphorus on Au(111) and unravel its structural details using diffraction, microscopy and theoretical calculations. Most importantly, by utilizing angle-resolved photoemission spectroscopy we identify its momentum-resolved electronic structure. We find that Au(111) breaks the sublattice symmetry of blue phosphorus leading to an orbital-dependent band renormalization upon the formation of a (4 × 4) superstructure. Notably, the semiconducting two-dimensional phosphorus realizes its valence band maximum at 0.9 eV binding energy, however, shifted in momentum space due to the substrate-induced band renormalization.
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