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Band Renormalization of Blue Phosphorus on Au(111)
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    Band Renormalization of Blue Phosphorus on Au(111)
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    • Evangelos Golias*
      Evangelos Golias
      Helmholtz-Zentrum Berlin für Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein Straße 15, 12489 Berlin, Germany
      Institut für Experimentalphysik, Freie Universität Berlin, Arnimallee 14, 14195 Berlin, Germany
      *(E.G.) E-mail: [email protected]
    • Maxim Krivenkov
      Maxim Krivenkov
      Helmholtz-Zentrum Berlin für Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein Straße 15, 12489 Berlin, Germany
    • Andrei Varykhalov
      Andrei Varykhalov
      Helmholtz-Zentrum Berlin für Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein Straße 15, 12489 Berlin, Germany
    • Jaime Sánchez-Barriga
      Jaime Sánchez-Barriga
      Helmholtz-Zentrum Berlin für Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein Straße 15, 12489 Berlin, Germany
    • Oliver Rader
      Oliver Rader
      Helmholtz-Zentrum Berlin für Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein Straße 15, 12489 Berlin, Germany
      More by Oliver Rader
    Other Access OptionsSupporting Information (1)

    Nano Letters

    Cite this: Nano Lett. 2018, 18, 11, 6672–6678
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    https://doi.org/10.1021/acs.nanolett.8b01305
    Published October 3, 2018
    Copyright © 2018 American Chemical Society

    Abstract

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    Most recently, theoretical calculations predicted the stability of a novel two-dimensional phosphorus honeycomb lattice named blue phosphorus. Here, we report on the growth of blue phosphorus on Au(111) and unravel its structural details using diffraction, microscopy and theoretical calculations. Most importantly, by utilizing angle-resolved photoemission spectroscopy we identify its momentum-resolved electronic structure. We find that Au(111) breaks the sublattice symmetry of blue phosphorus leading to an orbital-dependent band renormalization upon the formation of a (4 × 4) superstructure. Notably, the semiconducting two-dimensional phosphorus realizes its valence band maximum at 0.9 eV binding energy, however, shifted in momentum space due to the substrate-induced band renormalization.

    Copyright © 2018 American Chemical Society

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    This material is available free of charge via the Internet at http://pubs.acs.org/. The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.nanolett.8b01305.

    • STM images, ARPES spectra, band structure calculations, and XPS spectra of BlueP on Au(111) (PDF)

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    This article is cited by 65 publications.

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    Nano Letters

    Cite this: Nano Lett. 2018, 18, 11, 6672–6678
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.nanolett.8b01305
    Published October 3, 2018
    Copyright © 2018 American Chemical Society

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