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    How Fast Can a Li-Ion Battery Be Charged? Determination of Limiting Fast Charging Conditions
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    • Marco T. F. Rodrigues
      Marco T. F. Rodrigues
      Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
      More by Marco T. F. Rodrigues
      Orcidhttp://orcid.org/0000-0003-0833-6556
    • Seoung-Bum Son
      Seoung-Bum Son
      Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
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    • Andrew M. Colclasure
      Andrew M. Colclasure
      Center for Integrated Mobility Sciences, National Renewable Energy Laboratory, Golden, Colorado 80401, United States of America
      More by Andrew M. Colclasure
    • Ilya A. Shkrob
      Ilya A. Shkrob
      Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
      More by Ilya A. Shkrob
      Orcidhttp://orcid.org/0000-0002-8851-8220
    • Stephen E. Trask
      Stephen E. Trask
      Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
      More by Stephen E. Trask
      Orcidhttp://orcid.org/0000-0002-0879-4779
    • Ira D. Bloom
      Ira D. Bloom
      Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
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      Orcidhttp://orcid.org/0000-0002-4877-473X
    • Daniel P. Abraham*
      Daniel P. Abraham
      Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
      *Email: [email protected]. Phone: (630) 252-4332.
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    ACS Applied Energy Materials

    Cite this: ACS Appl. Energy Mater. 2021, 4, 2, 1063–1068
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    https://doi.org/10.1021/acsaem.0c03114
    Published January 26, 2021
    Copyright 2021 © UChicago Argonne, LLC, Operator of Argonne National Laboratory
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    Fast-charge protocols that prevent lithium plating are needed to extend the life span of lithium-ion batteries. Here, we describe a simple experimental method to estimate the minimum charging time below which it is simply impossible to avoid plating at a given temperature. We demonstrate that, by gauging and correcting the ohmic drop that is intrinsic to reference electrodes, the local potential at the anode surface can be reasonably approximated. This finer anode control enables the determination of the maximum average rate at which lithium deposition can be mitigated, establishing realistic boundaries that can inform the development of advanced charging protocols.

    Copyright 2021 © UChicago Argonne, LLC, Operator of Argonne National Laboratory

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    This article is cited by 48 publications.

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    ACS Applied Energy Materials

    Cite this: ACS Appl. Energy Mater. 2021, 4, 2, 1063–1068
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsaem.0c03114
    Published January 26, 2021
    Copyright 2021 © UChicago Argonne, LLC, Operator of Argonne National Laboratory
    Request reuse permissions

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