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Bismuth Nanoparticles Confined in Carbonaceous Nanospheres as Anodes for High-Performance Potassium-Ion Batteries

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Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Appl. Mater. Interfaces 2021, 13, 27, 31766-31774
    Energy, Environmental, and Catalysis Applications

    Bismuth Nanoparticles Confined in Carbonaceous Nanospheres as Anodes for High-Performance Potassium-Ion Batteries
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    • Jie Yao
      Jie Yao
      Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
      More by Jie Yao
    • Chenglin Zhang
      Chenglin Zhang
      Institut für Physik & IMN MacroNano (ZIK), Technische Universität Ilmenau, Ilmenau 98693, Germany
      More by Chenglin Zhang
    • Guowei Yang
      Guowei Yang
      Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
      More by Guowei Yang
    • Mo Sha
      Mo Sha
      Institut für Physik & IMN MacroNano (ZIK), Technische Universität Ilmenau, Ilmenau 98693, Germany
      More by Mo Sha
    • Yulian Dong
      Yulian Dong
      Institut für Physik & IMN MacroNano (ZIK), Technische Universität Ilmenau, Ilmenau 98693, Germany
      More by Yulian Dong
    • Qun Fu
      Qun Fu
      Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
      More by Qun Fu
    • Yuhan Wu
      Yuhan Wu
      Institut für Physik & IMN MacroNano (ZIK), Technische Universität Ilmenau, Ilmenau 98693, Germany
      More by Yuhan Wu
    • Huaping Zhao
      Huaping Zhao
      Institut für Physik & IMN MacroNano (ZIK), Technische Universität Ilmenau, Ilmenau 98693, Germany
      More by Huaping Zhao
    • Minghong Wu
      Minghong Wu
      Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
      More by Minghong Wu
      Orcidhttps://orcid.org/0000-0002-9776-671X
    • Yong Lei*
      Yong Lei
      Institut für Physik & IMN MacroNano (ZIK), Technische Universität Ilmenau, Ilmenau 98693, Germany
      *Email: [email protected]
      More by Yong Lei
      Orcidhttps://orcid.org/0000-0001-5048-7433
    Other Access OptionsSupporting Information (1)

    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2021, 13, 27, 31766–31774
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.1c09286
    Published July 1, 2021
    Copyright © 2021 American Chemical Society
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    Abstract

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    Bismuth (Bi) has been considered as a promising alloying-type anode for potassium-ion batteries (PIBs), owing to its high theoretical capacity and suitable working voltage plateaus. However, Bi suffers from dramatic volume fluctuation and significant pulverization during the discharge/charge processes, resulting in fast capacity decay. Herein, we synthesize Bi nanoparticles confined in carbonaceous nanospheres (denoted as Bi@C) for PIBs by first utilizing BiOCl nanoflakes as a hard template and a Bi precursor. The construction of the loose structure buffers the mechanical stresses resulting from the volume expansion of Bi during the alloying reaction and avoids the fracture of the electrode structure, thus improving the cycling performance. Moreover, the carbonaceous layers increase the electronic conductivity and disperse the Bi nanoparticles, enhancing the charge transportation and ionic diffusion, which further promotes the rate capability of Bi@C. It exhibits a superior capacity (389 mAh g–1 at 100 mA g–1 after 100 cycles), excellent cycling stability (206 mAh g–1 at 500 mA g–1 over 1000 cycles), and an improved rate capability (182 mAh g–1 at 2.0 A g–1). This work provides a new structuring strategy in alloying materials for boosting reversible and stable potassium-ion storage.

    Copyright © 2021 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsami.1c09286.

    • SEM and TEM images, control experiments, TGA analysis, BET measurement, and the calculation of Dk (PDF)

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    Cited By

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    This article is cited by 24 publications.

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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2021, 13, 27, 31766–31774
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsami.1c09286
    Published July 1, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

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