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Ti3+-Promoted High Oxygen-Reduction Activity of Pd Nanodots Supported by Black Titania Nanobelts

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‡ State Key Laboratory of Rare Earth Materials Chemistry and Applications and Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, People’s Republic of China
§ State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, People’s Republic of China
*E-mail: [email protected]
Cite this: ACS Appl. Mater. Interfaces 2016, 8, 41, 27654–27660
Publication Date (Web):September 26, 2016
https://doi.org/10.1021/acsami.6b07062
Copyright © 2016 American Chemical Society
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One-dimensional nanocrystals favoring efficient charge transfer have attracted enormous attentions, and conductive nanobelts of black titania with a unique band structure and high electrical conductivity would be interestingly used in electrocatalysis. Here, Pd nanodots supported by two kinds of black titania, the oxygen-deficient titania (TiO2–x) and nitrogen-doped titania (TiO2–x:N), were synthesized as efficient composite catalysts for oxygen-reduction reaction (ORR). These composite catalysts show improved catalytic activity with lower overpotential and higher limited current, compared to the Pd nanodots supported on the white titania (Pd/TiO2). The improved activity is attributed to the relatively high conductivity of black titania nanobelts for efficient charge transfer (CT) between Ti3+ species and Pd nanodots. The CT process enhances the strong metal–support interaction (SMSI) between Pd and TiO2, which lowers the absorption energy of O2 on Pd and makes it more suitable for oxygen reduction. Because of the stronger interaction between Pd and support, the Pd/TiO2–x:N also shows excellent durability and immunity to methanol poisoning.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.6b07062.

  • TEM images of Pd/TiO2 and Pd/TiO2–x:N; XPS spectrum of Pd/TiO2 and Pd/TiO2–x; RDE measurements of Pd/TiO2 and Pd/TiO2–x under different rotation speeds; RRDE measurements of Pd/C; stability test of Pd/C (PDF)

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