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Laser Carbonization of PAN-Nanofiber Mats with Enhanced Surface Area and Porosity

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† DWI−Leibniz Institute for Interactive Materials, RWTH Aachen University, Forckenbeckstraße 50, 52074 Aachen, Germany
‡ Fraunhofer Institute for Laser Technology (ILT), Steinbachstraße 15, 52074 Aachen, Germany
*E-mail: [email protected]
Cite this: ACS Appl. Mater. Interfaces 2016, 8, 42, 28412–28417
Publication Date (Web):September 13, 2016
https://doi.org/10.1021/acsami.6b09358
Copyright © 2016 American Chemical Society
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    Abstract

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    Here we present a novel laser process to generate carbon nanofiber nonwovens from polyacrylonitrile. We produce carbon nanofabrics via electrospinning followed by infrared laser-induced carbonization, facilitating high surface area and well-controlled hierarchical porosity. The process allows precise control of the carbonization conditions and provides high nanoscale porosity. In comparison with classical thermal carbonization, the laser process produces much higher surface areas and smaller pores. Furthermore, we investigate the carbonization performance and the morphology of polyacrylonitrile nanofibers compounded with graphene nanoplatelet fillers.

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