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Extraordinary Porous Few-Layer Carbons of High Capacitance from Pechini Combustion of Magnesium Nitrate Gel

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State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
University of Chinese Academy of Sciences, 19 Yuquan Road, Beijing 100049, China
§ Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
*E-mail: [email protected] (T.L.).
*E-mail: [email protected] (F.H.).
Cite this: ACS Appl. Mater. Interfaces 2018, 10, 1, 381–388
Publication Date (Web):December 8, 2017
https://doi.org/10.1021/acsami.7b11042
Copyright © 2017 American Chemical Society
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Abstract

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Highly capacitive carbons are viewed as promising commercial materials for supercapacitors, but few species satisfy the requirements of high capacitance and low cost. Here, we demonstrate an extraordinary porous few-layer carbon by facile Pechini combustion of magnesium nitrate gel, which combined salicylic acid as a complexing agent with magnesium nitrate as an inorganic metal salt. The as-synthesized carbon material delivers a capacitance of 415 F g–1, mostly stemming from a large specific surface area (∼1312 m2 g–1), a fluent channel for transport of the electrolyte, as well as electrochemical redox reactions at O,N-associated active sites. Such porous few-layer carbons may accelerate the adoption of carbon-based supercapacitors for commercial high-power energy storage applications.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.7b11042.

  • The calculation formulas for capacitance in two-electrode system XRD spectra of PFC-3/MgO and PFC-3; TEM images of PFC-1 and PFC-2; C 1s spectrum of the PFC-3 sample; the relationships between peak currents versus ν1/2 of the PFC-3 sample from CV tests; (capacitance, C)−1 versus (scan rate, ν)1/2 and capacitance versus (scan rate, ν)−1/2 of the PFC-3 sample; and capacitance of the PFC-3 sample at 0.5 to 20 A g–1 with 1 M H2SO4 and 2 M Li2SO4 as electrolytes in the two-electrode system (PDF)

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Cited By


This article is cited by 2 publications.

  1. Jinghai Liu, Lei Ji, Xia Wang, Limei Duan, Jiaqi Zhou, Yongfeng Jia, Simei Zeng, Keke Huang, Zhibin Geng, Xiyang Wang, Changmin Hou, Xiaofeng Wu, Luhua Lu, Zhili Pei, Yongsheng Chen, Jun Zhang, Shouhua Feng, Yuegang Zhang. Commercial-Level Energy Storage via Free-Standing Stacking Electrodes. Matter 2019, 1 (6) , 1694-1709. https://doi.org/10.1016/j.matt.2019.07.017
  2. Meng Qian, Zhaoming Wang, Zhi Li, Jijian Xu, Peng Sun, Jie Lin, Tianquan Lin, Fuqiang Huang. Sol-gel assisted chemical activation for nitrogen doped porous carbon. Microporous and Mesoporous Materials 2019, 286 , 18-24. https://doi.org/10.1016/j.micromeso.2019.05.038

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