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Heteroleptic Copper-Based Complexes for Energy-Transfer Processes: E → Z Isomerization and Tandem Photocatalytic Sequences

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    Research Article

    Heteroleptic Copper-Based Complexes for Energy-Transfer Processes: E → Z Isomerization and Tandem Photocatalytic Sequences
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    • Corentin Cruché
      Corentin Cruché
      Département de Chimie, Centre for Green Chemistry and Catalysis, Université de Montréal, 1375 Avenue Thérèse-Lavoie-Roux, Montréal, QC H2V 0B3 Canada
      More by Corentin Cruché
    • William Neiderer
      William Neiderer
      Département de Chimie, Centre for Green Chemistry and Catalysis, Université de Montréal, 1375 Avenue Thérèse-Lavoie-Roux, Montréal, QC H2V 0B3 Canada
      More by William Neiderer
    • Shawn K. Collins*
      Shawn K. Collins
      Département de Chimie, Centre for Green Chemistry and Catalysis, Université de Montréal, 1375 Avenue Thérèse-Lavoie-Roux, Montréal, QC H2V 0B3 Canada
      *Email:[email protected]
      More by Shawn K. Collins
      Orcidhttps://orcid.org/0000-0001-9206-5538
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    ACS Catalysis

    Cite this: ACS Catal. 2021, 11, 14, 8829–8836
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    https://doi.org/10.1021/acscatal.1c01983
    Published July 4, 2021
    Copyright © 2021 American Chemical Society
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    Abstract

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    Energy-transfer processes involving copper complexes are rare. Using an optimized heteroleptic copper complex, Cu(bphen)(XantPhos)BF4, photosensitized E → Z isomerization of olefins is demonstrated. The XantPhos ligand afforded sensitizers with improved catalyst stability, while the bphen ligand lengthened the excited-state lifetime. A series of 25 di- and trisubstituted alkenes underwent photoisomerization, including macrocycles and 1,3-enynes. Cu(bphen)(XantPhos)BF4 could also be employed in a tandem ATRA/photoisomerization process employing arylsulfonyl chlorides, an example of photoisomerization with halide-substituted olefins.

    Copyright © 2021 American Chemical Society

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    Cited By

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    This article is cited by 28 publications.

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    ACS Catalysis

    Cite this: ACS Catal. 2021, 11, 14, 8829–8836
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acscatal.1c01983
    Published July 4, 2021
    Copyright © 2021 American Chemical Society
    Request reuse permissions

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