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Template-Free Synthesis of Highly Porous Boron Nitride: Insights into Pore Network Design and Impact on Gas Sorption

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† Barrer Centre, Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ, U.K.
‡ Department of Materials, Imperial College London, South Kensington Campus, London SW7 2AZ, U.K.
§ Department of Chemical Engineering, University College London, Gower Street, London WC1E 6BT, U.K.
*E-mail: [email protected]. Phone: +44 (0)20 7594 3182 (C. Petit).
Cite this: ACS Nano 2017, 11, 10, 10003–10011
Publication Date (Web):September 11, 2017
https://doi.org/10.1021/acsnano.7b04219
Copyright © 2017 American Chemical Society
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    Production of biocompatible and stable porous materials, e.g., boron nitride, exhibiting tunable and enhanced porosity is a prerequisite if they are to be employed to address challenges such as drug delivery, molecular separations, or catalysis. However, there is currently very limited understanding of the formation mechanisms of porous boron nitride and the parameters controlling its porosity, which ultimately prevents exploiting the material’s full potential. Herein, we produce boron nitride with high and tunable surface area and micro/mesoporosity via a facile template-free method using multiple readily available N-containing precursors with different thermal decomposition patterns. The gases are gradually released, creating hierarchical pores, high surface areas (>1900 m2/g), and micropore volumes. We use 3D tomography techniques to reconstruct the pore structure, allowing direct visualization of the mesopore network. Additional imaging and analytical tools are employed to characterize the materials from the micro- down to the nanoscale. The CO2 uptake of the materials rivals or surpasses those of commercial benchmarks or other boron nitride materials reported to date (up to 4 times higher), even after pelletizing. Overall, the approach provides a scalable route to porous boron nitride production as well as fundamental insights into the material’s formation, which can be used to design a variety of boron nitride structures.

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    • Video displaying the images aligned collected with TEM tomography for a single N-precursor BN-U5 (AVI)

    • Video displaying the images aligned collected with TEM tomography for a multiple N-precursor BN-MU1:5 (AVI)

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