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Active Far-Field Control of the Thermal Near-Field via Plasmon Hybridization

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    Active Far-Field Control of the Thermal Near-Field via Plasmon Hybridization
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    ACS Nano

    Cite this: ACS Nano 2019, 13, 8, 9655–9663
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    https://doi.org/10.1021/acsnano.9b04968
    Published July 30, 2019
    Copyright © 2019 American Chemical Society
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    Abstract

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    The ability to control and manipulate temperature at nanoscale dimensions has the potential to impact applications including heat-assisted magnetic recording, photothermal therapies, and temperature-driven reactivity. One challenge with controlling temperature at nanometer dimensions is the need to mitigate heat diffusion, such that the temperature only changes in well-defined nanoscopic regions of the sample. Here we demonstrate the ability to use far-field laser excitation to actively shape the thermal near-field in individual gold nanorod heterodimers by resonantly pumping either the in-phase or out-of-phase hybridized dipole plasmon modes. Using single-particle photothermal heterodyne imaging, we demonstrate localization bias in the photothermal intensity due to preferential heating of one of the nanorods within the pair. Theoretical modeling and numerical simulation make explicit how the resulting photothermal images encode wavelength-dependent temperature biases between each nanorod within a heterodimer, demonstrating the ability to actively manage the thermal near-field by simply tuning the color of incident light.

    Copyright © 2019 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsnano.9b04968.

    • Additional information includes the electron beam lithography fabrication of the gold heterodimers (S1.1) and the experimental procedure for single particle extinction (S1.2), absorption (S1.3), and scattering measurements (S1.4). A detailed representation of the controls and additional photothermal biasing experiments are included (Figures S1–S5). Simulated plane wave (wide-field) heat power density maps (Figure S7) and temperature maps (Figure S8) are also included to contrast the Gaussian beam (confocal) sourced results presented in the main text. A justification for steady-state heat diffusion temperature calculations are provided in (S2.1–S2.3). Lastly, an in-depth model of photothermal imaging and a derivation of eq 3 are presented in S3 (PDF)

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    This article is cited by 22 publications.

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    ACS Nano

    Cite this: ACS Nano 2019, 13, 8, 9655–9663
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsnano.9b04968
    Published July 30, 2019
    Copyright © 2019 American Chemical Society
    Request reuse permissions

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