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High-Performance All-Bio-Based Laminates Derived from Delignified Wood

  • Marion Frey*
    Marion Frey
    Wood Materials Science, Institute for Building Materials, ETH Zürich, Stefano-Franscini-Platz 3, Zurich CH-8093, Switzerland
    WoodTec Group, Cellulose & Wood Materials, EMPA, Ueberlandstrasse 129, Dübendorf CH-8600, Switzerland
    *Email: [email protected]
    More by Marion Frey
  • Livia Schneider
    Livia Schneider
    Wood Materials Science, Institute for Building Materials, ETH Zürich, Stefano-Franscini-Platz 3, Zurich CH-8093, Switzerland
  • Hajar Razi
    Hajar Razi
    Wood Materials Science, Institute for Building Materials, ETH Zürich, Stefano-Franscini-Platz 3, Zurich CH-8093, Switzerland
    WoodTec Group, Cellulose & Wood Materials, EMPA, Ueberlandstrasse 129, Dübendorf CH-8600, Switzerland
    More by Hajar Razi
  • Etienne Trachsel
    Etienne Trachsel
    Wood Materials Science, Institute for Building Materials, ETH Zürich, Stefano-Franscini-Platz 3, Zurich CH-8093, Switzerland
  • Eric Faude
    Eric Faude
    Wood Materials Science, Institute for Building Materials, ETH Zürich, Stefano-Franscini-Platz 3, Zurich CH-8093, Switzerland
    More by Eric Faude
  • Sophie Marie Koch
    Sophie Marie Koch
    Wood Materials Science, Institute for Building Materials, ETH Zürich, Stefano-Franscini-Platz 3, Zurich CH-8093, Switzerland
    WoodTec Group, Cellulose & Wood Materials, EMPA, Ueberlandstrasse 129, Dübendorf CH-8600, Switzerland
  • Kunal Masania
    Kunal Masania
    Shaping Matter Lab, Faculty of Aerospace Engineering, TU Delft, HS Delft 2629, the Netherlands
  • Peter Fratzl
    Peter Fratzl
    Department of Biomaterials, Max Planck Institute of Colloids and Interfaces, Potsdam 14424, Germany
    More by Peter Fratzl
  • Tobias Keplinger*
    Tobias Keplinger
    Wood Materials Science, Institute for Building Materials, ETH Zürich, Stefano-Franscini-Platz 3, Zurich CH-8093, Switzerland
    WoodTec Group, Cellulose & Wood Materials, EMPA, Ueberlandstrasse 129, Dübendorf CH-8600, Switzerland
    *Email: [email protected]
  • , and 
  • Ingo Burgert
    Ingo Burgert
    Wood Materials Science, Institute for Building Materials, ETH Zürich, Stefano-Franscini-Platz 3, Zurich CH-8093, Switzerland
    WoodTec Group, Cellulose & Wood Materials, EMPA, Ueberlandstrasse 129, Dübendorf CH-8600, Switzerland
    More by Ingo Burgert
Cite this: ACS Sustainable Chem. Eng. 2021, 9, 29, 9638–9646
Publication Date (Web):July 12, 2021
https://doi.org/10.1021/acssuschemeng.0c08373
Copyright © 2021 American Chemical Society

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    Abstract

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    The need for renewable bio-based materials that could replace well-established synthetic composite materials is rapidly growing. For example, bio-based materials are increasingly used in applications where a lightweight design should be combined with sustainability and recyclability. However, it is often very challenging to directly transfer the excellent properties of biological materials to a product in a scalable and cost-efficient manner. In this study, we combined delignified wood layers (veneers) and a starch-based glue into bio-based high-performance composites. First, we investigated the ideal amount of starch-based glue between the layers to prevent delamination in the final composite. Then, we produced laminates in unidirectional, cross-ply, and quasi-isotropic configurations using wet processing. Laminates with tensile properties up to 40 GPa and 200 MPa in tensile stiffness and strength, respectively, were fabricated with a very high fiber volume content of up to 80%. The high fiber volume contents led to mechanical interlocks between neighboring fibers and made the need for an additional matrix unnecessary. The water-based laminate process is cost-efficient and scalable and additionally allows one to make full use of delignified wood’s formability by producing shaped parts for various applications.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acssuschemeng.0c08373.

    • Mechanical properties of laminates and the corresponding densification parameters, CLT model calculations and FEM parameters, IR spectra of reference and delignified veneers, and wet chemistry analysis including the corresponding materials and methods section (PDF)

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    Cited By

    This article is cited by 13 publications.

    1. Sophie Marie Koch, Manuel Pillon, Tobias Keplinger, Christopher Hubert Dreimol, Stephan Weinkötz, Ingo Burgert. Intercellular Matrix Infiltration Improves the Wet Strength of Delignified Wood Composites. ACS Applied Materials & Interfaces 2022, 14 (27) , 31216-31224. https://doi.org/10.1021/acsami.2c04014
    2. Laura Lemetti, Jennifer Tersteegen, Juuso Sammaljärvi, A. Sesilja Aranko, Markus B. Linder. Recombinant Spider Silk Protein and Delignified Wood Form a Strong Adhesive System. ACS Sustainable Chemistry & Engineering 2022, 10 (1) , 552-561. https://doi.org/10.1021/acssuschemeng.1c07043
    3. Shen Wang, Pengfei Zhang, Yanhui Li, Junru Li, Xinlin Li, Jihua Yang, Maocheng Ji, Fangyi Li, Chuanwei Zhang. Recent advances and future challenges of the starch-based bio-composites for engineering applications. Carbohydrate Polymers 2023, 307 , 120627. https://doi.org/10.1016/j.carbpol.2023.120627
    4. Wanting Liu, Yuan Zhang, Ping Li, Yiqiang Wu, Xingong Li, Yingfeng Zuo. Exploring the effect of lignin on the chemical structure and microstructure of Chinese fir wood by segmental delignification. Wood Science and Technology 2023, 3 https://doi.org/10.1007/s00226-023-01461-x
    5. Ran Zhang, Hairong Gao, Yongtai Wang, Boyang He, Jun Lu, Wanbin Zhu, Liangcai Peng, Yanting Wang. Challenges and perspectives of green-like lignocellulose pretreatments selectable for low-cost biofuels and high-value bioproduction. Bioresource Technology 2023, 369 , 128315. https://doi.org/10.1016/j.biortech.2022.128315
    6. Hao Sun, Congyu Hou, Tong Ji, Xinyuan Zhou, Zechun Ren, Yongming Song. Processing bulk wood into a light-permeable passive radiative cooling material for energy-efficient building. Composites Part B: Engineering 2023, 250 , 110426. https://doi.org/10.1016/j.compositesb.2022.110426
    7. Sophie Marie Koch, Philippe Grönquist, Cyril Monney, Ingo Burgert, Andrea Frangi. Densified delignified wood as bio-based fiber reinforcement for stiffness increase of timber structures. Composites Part A: Applied Science and Manufacturing 2022, 163 , 107220. https://doi.org/10.1016/j.compositesa.2022.107220
    8. Quan Quan, Yajing Zhang, Hongwei Piao, Hongjie Zhang, Jian Zhao. Polybutyrolactam (PBY) fiber: a promising biobased and biodegradable fiber fabricated by dry-jet-wet spinning. Polymer 2022, 260 , 125392. https://doi.org/10.1016/j.polymer.2022.125392
    9. Muhammad Iqbal Maulana, Muhammad Adly Rahandi Lubis, Fauzi Febrianto, Lee Seng Hua, Apri Heri Iswanto, Petar Antov, Lubos Kristak, Efri Mardawati, Rita Kartika Sari, Lukmanul Hakim Zaini, Wahyu Hidayat, Valentina Lo Giudice, Luigi Todaro. Environmentally Friendly Starch-Based Adhesives for Bonding High-Performance Wood Composites: A Review. Forests 2022, 13 (10) , 1614. https://doi.org/10.3390/f13101614
    10. Boyu Cui, Hao Xie, Hao Sun, Tong Ji, Shuang Li, Xue Jia, Weihong Wang. Anisotropic, ultrastrong and light-transmission film designed on wheat straw. Journal of Materials Chemistry A 2022, 10 (24) , 12968-12976. https://doi.org/10.1039/D2TA01204A
    11. Zhenjiong Wang, Zheng Xing, Qin Zhang, Dongxia Hu, Jiasheng Lv, Chaoyi Wu, Wenzhi Zhou, Zia-ud-Din. Effects of various durations of enzyme hydrolysis on properties of starch-based wood adhesive. International Journal of Biological Macromolecules 2022, 205 , 664-671. https://doi.org/10.1016/j.ijbiomac.2022.02.036
    12. Hao Sun, Congyu Hou, Tong Ji, Xinyuan Zhou, Zechun Ren, Yongming Song. Processing Bulk Wood into a Light-Permeable Passive Radiative Cooling Material for Energy-Efficient Building. SSRN Electronic Journal 2022, 524 https://doi.org/10.2139/ssrn.4007270
    13. Xiaoshuai Han, Weijie Wu, Jingwen Wang, Zhiwei Tian, Shaohua Jiang. Hydrogen-Bonding-Aided Fabrication of Wood Derived Cellulose Scaffold/Aramid Nanofiber into High-Performance Bulk Material. Materials 2021, 14 (18) , 5444. https://doi.org/10.3390/ma14185444

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