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Hybrid Composite Ni(OH)2@NiCo2O4 Grown on Carbon Fiber Paper for High-Performance Supercapacitors

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    Hybrid Composite Ni(OH)2@NiCo2O4 Grown on Carbon Fiber Paper for High-Performance Supercapacitors
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    † Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
    ‡ School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, Georgia 30332-0245, United States
    *E-mail: [email protected]. Phone:404-894-6114.
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2013, 5, 21, 11159–11162
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    https://doi.org/10.1021/am403367u
    Published October 11, 2013
    Copyright © 2013 American Chemical Society
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    Abstract

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    We have successfully fabricated and tested the electrochemical performance of supercapacitor electrodes consisting of Ni(OH)2 nanosheets coated on NiCo2O4 nanosheets grown on carbon fiber paper (CFP) current collectors. When the NiCo2O4 nanosheets are replaced by Co3O4 nanosheets, however, the energy and power density as well as the rate capability of the electrodes are significantly reduced, most likely due to the lower conductivity of Co3O4 than that of NiCo2O4. The 3D hybrid composite Ni(OH)2/NiCo2O4/CFP electrodes demonstrate a high areal capacitance of 5.2 F/cm2 at a cycling current density of 2 mA/cm2, with a capacitance retention of 79% as the cycling current density was increased from 2 to 50 mA/cm2. The remarkable performance of these hybrid composite electrodes implies that supercapacitors based on them have potential for many practical applications.

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    Synthesis detail of hybrid composite Ni(OH)2/NiCo2O4 and Ni(OH)2/Co3O4. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: ACS Appl. Mater. Interfaces 2013, 5, 21, 11159–11162
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