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Programmable Macroscopic Supramolecular Assembly through Combined Molecular Recognition and Magnetic Field-Assisted Localization

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    Research Article

    Programmable Macroscopic Supramolecular Assembly through Combined Molecular Recognition and Magnetic Field-Assisted Localization
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    State Key Laboratory of Chemical Resource Engineering & Key Laboratory of Carbon Fiber and Functional Polymer, Ministry of Education, Beijing University of Chemical Technology, 15 Beisanhuan East Road, Chaoyang Distrist, Beijing 100029, China
    *E-mail: [email protected]
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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2014, 6, 10, 7572–7578
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    https://doi.org/10.1021/am500910y
    Published April 9, 2014
    Copyright © 2014 American Chemical Society
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    Abstract

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    Macroscopic supramolecular assembly is a promising bottom-up method to construct ordered three-dimensional structures in a programmable way because of its flexible tailoring features. To handle the challenges of precisely aligning the building blocks, we proposed the combination of magnetic field-assisted localization for the locomotion of building blocks and host/guest supramolecular recognition for their immobilization. By applying this strategy, we have realized the stepwise construction of microscale glass fibers into an ordered complex pattern. Furthermore, through the introduction of a competitive guest molecule to disassemble the assembled structure, we demonstrated that the interaction between the fibers and the substrate was supramolecular rather than nonselective stickiness. Multivalent theory was used to interpret the mechanism for the interaction process.

    Copyright © 2014 American Chemical Society

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    Supporting Information

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    Synthesis of PAA-CD and PAA-Azo, TEM images of Fe3O4 MNPs, AFM images of (PDDA/PAA–Azo)20 multilayer, and Movie S1 of introducing competitive Ad for disassembly. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cited By

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    This article is cited by 33 publications.

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    ACS Applied Materials & Interfaces

    Cite this: ACS Appl. Mater. Interfaces 2014, 6, 10, 7572–7578
    Click to copy citationCitation copied!
    https://doi.org/10.1021/am500910y
    Published April 9, 2014
    Copyright © 2014 American Chemical Society
    Request reuse permissions

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