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Glyphosate

  • Anne Louise Gimsing
    Anne Louise Gimsing
    Department of Natural Sciences, The Royal Veterinary and Agricultural University, Thorvaldsensvej 40, 1871 Frederiksberg C., Denmark
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  • Afonso Maria dos Santos
    Afonso Maria dos Santos
    INQUIMAE and Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria Pabellǒn II 3er Piso, C1428EHA Buenos Aires, Argentina
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DOI: 10.1021/bk-2005-0910.ch016
    Publication Date (Print):July 21, 2005
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    Copyright © 2005 American Chemical Society.
    Biogeochemistry of Chelating Agents
    Chapter 16pp 263-277
    ACS Symposium SeriesVol. 910
    ISBN13: 9780841238978eISBN: 9780841220287

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    Abstract

    The herbicide glyphosate (N-phosphonomethylglycine) interacts strongly with many soil components. It forms strong complexes with many metals in solution, and it is adsorbed through innersphere complexation to iron- and aluminium oxides. Glyphosate can also be adsorbed by clay minerals by forming complexes with interlayer cations. Because of these interactions, glyphosate is strongly adsorbed in soils. It is mainly the phosphonic acid moiety that participates in the adsorption, and therefore phosphate competes with glyphosate for adsorption sites.

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