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Intumescent Multilayer Nanocoating, Made with Renewable Polyelectrolytes, for Flame-Retardant Cotton
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    Intumescent Multilayer Nanocoating, Made with Renewable Polyelectrolytes, for Flame-Retardant Cotton
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    Department of Mechanical Engineering, Texas A&M University, College Station, Texas 77843, United States
    Multiscale Composites and Polymers Division, University of Dayton Research Institute, Dayton, Ohio 45469, United States
    *Tel: +1 979 845 3027; fax: +1 979 862 3989. E-mail address: [email protected]
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    Biomacromolecules

    Cite this: Biomacromolecules 2012, 13, 9, 2843–2848
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    https://doi.org/10.1021/bm300873b
    Published August 17, 2012
    Copyright © 2012 American Chemical Society

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    Thin films of fully renewable and environmentally benign electrolytes, cationic chitosan (CH) and anionic phytic acid (PA), were deposited on cotton fabric via layer-by-layer (LbL) assembly in an effort to reduce flammability. Altering the pH of aqueous deposition solutions modifies the composition of the final nanocoating. CH–PA films created at pH 6 were thicker and had 48 wt % PA in the coating, while the thinnest films (with a PA content of 66 wt %) were created at pH 4. Each coating was evaluated at both 30 bilayers (BL) and at the same coating weight added to the fabric. In a vertical flame test, fabrics coated with high PA content multilayers completely extinguished the flame, while uncoated cotton was completely consumed. Microcombustion calorimetry confirmed that all coated fabric reduces peak heat release rate (pkHRR) by at least 50% relative to the uncoated control. Fabric coated with pH 4 solutions shows the greatest reduction in pkHRR and total heat release of 60% and 76%, respectively. This superior performance is believed to be due to high phosphorus content that enhances the intumescent behavior of these nanocoatings. These results demonstrate the first completely renewable intumescent LbL assembly, which conformally coats every fiber in cotton fabric and provides an effective alternative to current flame retardant treatments.

    Copyright © 2012 American Chemical Society

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    Supporting Information

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    The weight of each CH and PA layer deposited, as measured by QCM, allows CH-PA assembly composition to be determined. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: Biomacromolecules 2012, 13, 9, 2843–2848
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    https://doi.org/10.1021/bm300873b
    Published August 17, 2012
    Copyright © 2012 American Chemical Society

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