Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
Concomitant Conformational Polymorphism: Mechanochemical Reactivity and Phase Relationships in the (Methanol)cis-dioxo(N-salicylidene-2-amino-3-hydroxypyridine)molybdenum(VI) Trimorph

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Crystal Growth & Design 2009, 9, 12, 5327-5333
    Article

    Concomitant Conformational Polymorphism: Mechanochemical Reactivity and Phase Relationships in the (Methanol)cis-dioxo(N-salicylidene-2-amino-3-hydroxypyridine)molybdenum(VI) Trimorph
    Click to copy article linkArticle link copied!

    View Author Information
    † Laboratory of General and Inorganic Chemistry, Chemistry Department, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia
    ‡ Laboratory for Solid-State and Complex Compounds Chemistry, Institute “Ruđer Bošković”, Bijenic̆ka 54, 10000 Zagreb, Croatia
    *To whom correspondence should be addressed. Telephone (+)385 14606350. Fax: (+)385 1 4606341. E-mail: [email protected]
    Other Access OptionsSupporting Information (1)

    Crystal Growth & Design

    Cite this: Cryst. Growth Des. 2009, 9, 12, 5327–5333
    Click to copy citationCitation copied!
    https://doi.org/10.1021/cg900824n
    Published September 24, 2009
    Copyright © 2009 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    The title compound, [MoO2(L)(CH3OH)], crystallizes as a concomitant conformational trimorph. The occurrence domains, under which these forms can be prepared, separated, and/or interconverted, were explored and determined in terms of the crystallization conditions and solid-state reactions. Solvent-free reactions resulted in dissociation of coordinated methanol, producing two new complexes, monomeric [MoO2(L)] and polymeric [MoO2(L)]n. They both bind methanol molecule from its vapor, thus providing a pure α-form of the title complex. All forms have been characterized and compared to each other by a variety of methods including elemental analysis, Fourier transform IR, thermal methods, X-ray powder diffraction, and single-crystal X-ray structure determination.

    Copyright © 2009 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    Thermogravimetric and infrared spectra analyses of three mononuclear cis-dioxomolybdenum(VI) polymorphs, α, β, and γ. Detailed description of solvent-free reactions. Thermogravimetric analyses of solvent-free reactions products, GP and HP. Comparison of powder patterns for all above-mentioned products. Selected geometrical parameters and intermolecular C−H···O interactions for α-, β-, and γ-forms. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 30 publications.

    1. Sixue Cheng, Gregory B. McKenna. Isothermal Crystallization and Time–Temperature Transformation of Amorphous Nifedipine: A Case of Polymorphism Formation and Conversion. Molecular Pharmaceutics 2021, 18 (7) , 2786-2802. https://doi.org/10.1021/acs.molpharmaceut.1c00331
    2. Kristina Smokrović, Senada Muratović, Bahar Karadeniz, Krunoslav Užarević, Dijana Žilić, Ivica Đilović. Synthon Robustness and Structural Modularity of Copper(II) Two-Dimensional Coordination Polymers with Isomeric Amino Acids and 4,4′-Bipyridine. Crystal Growth & Design 2020, 20 (4) , 2415-2423. https://doi.org/10.1021/acs.cgd.9b01601
    3. Bahar Karadeniz, Dijana Žilić, Igor Huskić, Luzia S. Germann, Athena M. Fidelli, Senada Muratović, Ivor Lončarić, Martin Etter, Robert E. Dinnebier, Dajana Barišić, Nikola Cindro, Timur Islamoglu, Omar K. Farha, Tomislav Friščić, Krunoslav Užarević. Controlling the Polymorphism and Topology Transformation in Porphyrinic Zirconium Metal–Organic Frameworks via Mechanochemistry. Journal of the American Chemical Society 2019, 141 (49) , 19214-19220. https://doi.org/10.1021/jacs.9b10251
    4. Audrey Beillard, Xavier Bantreil, Thomas-Xavier Métro, Jean Martinez, Frédéric Lamaty. Alternative Technologies That Facilitate Access to Discrete Metal Complexes. Chemical Reviews 2019, 119 (12) , 7529-7609. https://doi.org/10.1021/acs.chemrev.8b00479
    5. Jelena Pejić, Darko Vušak, Gábor Szalontai, Biserka Prugovečki, Draginja Mrvoš-Sermek, Dubravka Matković-Čalogović, Jasmina Sabolović. Disorder at the Chiral Cα Center and Room-Temperature Solid-State cis–trans Isomerization; Synthesis and Structural Characterization of Copper(II) Complexes with d-allo,l-Isoleucine. Crystal Growth & Design 2018, 18 (9) , 5138-5154. https://doi.org/10.1021/acs.cgd.8b00589
    6. Mirta Rubčić, Nives Galić, Ivan Halasz, Tomislav Jednačak, Nenad Judaš, Janez Plavec, Primož Šket, and Predrag Novak . Multiple Solid Forms of 1,5-Bis(salicylidene)carbohydrazide: Polymorph-Modulated Thermal Reactivity. Crystal Growth & Design 2014, 14 (6) , 2900-2912. https://doi.org/10.1021/cg500203k
    7. Marina Juribašić, Ivan Halasz, Darko Babić, Dominik Cinčić, Janez Plavec, and Manda Ćurić . Aging and Ball-Milling as Low-Energy and Environmentally Friendly Methods for the Synthesis of Pd(II) Photosensitizers. Organometallics 2014, 33 (5) , 1227-1234. https://doi.org/10.1021/om500008v
    8. Višnja Vrdoljak, Biserka Prugovečki, Dubravka Matković-Čalogović, Tomica Hrenar, Renata Dreos, and Patrizia Siega . Three Polymorphic Forms of a Monomeric Mo(VI) Complex: Building Blocks for Two Metal–Organic Supramolecular Isomers. Intermolecular Interactions and Ligand Substituent Effects. Crystal Growth & Design 2013, 13 (8) , 3773-3784. https://doi.org/10.1021/cg400782c
    9. Dominik Cinčić, Ivana Brekalo, and Branko Kaitner . Solvent-Free Polymorphism Control in a Covalent Mechanochemical Reaction. Crystal Growth & Design 2012, 12 (1) , 44-48. https://doi.org/10.1021/cg2013705
    10. Mirta Rubčić, Dalibor Milić, Gordana Pavlović, and Marina Cindrić . Conformational Diversity of Thiosemicarbazonatovanadium(V) Complexes in the Solid State: From Polymorphism to Isostructurality. Crystal Growth & Design 2011, 11 (12) , 5227-5240. https://doi.org/10.1021/cg200466b
    11. Hadi Kargar, Maryam Nateghi-Jahromi, Mehdi Fallah-Mehrjardi, Reza Behjatmanesh-Ardakani, Khurram Shahzad Munawar, Saqib Ali, Muhammad Ashfaq, Muhammad Nawaz Tahir. Synthesis, spectral characterization, crystal structure and catalytic activity of a novel dioxomolybdenum Schiff base complex containing 4-aminobenzhydrazone ligand: A combined experimental and theoretical study. Journal of Molecular Structure 2022, 1249 , 131645. https://doi.org/10.1016/j.molstruc.2021.131645
    12. Tomislav Balić, Franc Perdih, Marta Počkaj, Maja Molnar, Mario Komar, Ivana Balić. Polymorphism of coumarin thione-triazole - 4-methyl-7-[(4-phenyl-5-thioxo-4,5-dihydro-1H-1,2,4-triazol-3-yl)methoxy]-2H-chromen-2-one. Journal of Molecular Structure 2021, 1231 , 129957. https://doi.org/10.1016/j.molstruc.2021.129957
    13. Edi Topić, Ivana Landripet, Maëlle Duguin, Jana Pisk, Ivica Đilović, Višnja Vrdoljak, Mirta Rubčić. Coordinating and supramolecular prospects of unsymmetrically substituted carbohydrazides. New Journal of Chemistry 2020, 44 (31) , 13357-13367. https://doi.org/10.1039/D0NJ03106B
    14. Edi Topić, Jana Pisk, Dominique Agustin, Martin Jendrlin, Danijela Cvijanović, Višnja Vrdoljak, Mirta Rubčić. Discrete and polymeric ensembles based on dinuclear molybdenum( vi ) building blocks with adaptive carbohydrazide ligands: from the design to catalytic epoxidation. New Journal of Chemistry 2020, 44 (19) , 8085-8097. https://doi.org/10.1039/D0NJ01045F
    15. Mirna Mandarić, Biserka Prugovečki, Danijela Cvijanović, Jelena Parlov Vuković, Jasna Lovrić, Mirjana Skočibušić, Renata Odžak, Marina Cindrić, Višnja Vrdoljak. Vapour- and solvent-mediated crystalline transformations in Mo( vi ) hydrazone complexes controlled by noncovalent interactions. CrystEngComm 2019, 21 (41) , 6281-6292. https://doi.org/10.1039/C9CE01273G
    16. Jana Pisk, Mirta Rubčić, Dino Kuzman, Marina Cindrić, Dominique Agustin, Višnja Vrdoljak. Molybdenum( vi ) complexes of hemilabile aroylhydrazone ligands as efficient catalysts for greener cyclooctene epoxidation: an experimental and theoretical approach. New Journal of Chemistry 2019, 43 (14) , 5531-5542. https://doi.org/10.1039/C9NJ00229D
    17. Cameron Capeletti da Silva, Felipe Terra Martins. Multiple conformations and supramolecular synthons in almost fifty crystal structures of the anti-HIV/HBV drug lamivudine. Journal of Molecular Structure 2019, 1181 , 157-170. https://doi.org/10.1016/j.molstruc.2018.12.099
    18. Marija Zbačnik, Ivana Nogalo, Dominik Cinčić, Branko Kaitner. Polymorphism control in the mechanochemical and solution-based synthesis of a thermochromic Schiff base. CrystEngComm 2015, 17 (41) , 7870-7877. https://doi.org/10.1039/C5CE01445J
    19. Marina Juribašić, Nikola Bregović, Vladimir Stilinović, Vladislav Tomišić, Marina Cindrić, Primož Šket, Janez Plavec, Mirta Rubčić, Krunoslav Užarević. Supramolecular Stabilization of Metastable Tautomers in Solution and the Solid State. Chemistry – A European Journal 2014, 20 (52) , 17333-17345. https://doi.org/10.1002/chem.201403543
    20. Christian Näther, Inke Jess, Julia Bahrenburg, Dennis Bank, Friedrich Temps. Trimorphism of N-(3-pyridyl)-benzamide. CrystEngComm 2014, 16 (25) , 5633-5641. https://doi.org/10.1039/C4CE00495G
    21. Jana Pisk, Biserka Prugovečki, Dubravka Matković-Čalogović, Tomislav Jednačak, Predrag Novak, Dominique Agustin, Višnja Vrdoljak. Pyridoxal hydrazonato molybdenum( vi ) complexes: assembly, structure and epoxidation (pre)catalyst testing under solvent-free conditions. RSC Advances 2014, 4 (73) , 39000. https://doi.org/10.1039/C4RA08179J
    22. Reza Takjoo, Alireza Akbari, Seyyed Yousef Ebrahimipour, Hadi Amiri Rrudbari, Giuseppe Brunò. Synthesis, characterization, X-ray structure and DFT calculation of two Mo(VI) and Ni(II) Schiff-base complexes. Comptes Rendus. Chimie 2014, 17 (11) , 1144-1153. https://doi.org/10.1016/j.crci.2014.01.009
    23. Krunoslav Užarević, Gordana Pavlović, Marina Cindrić. Mononuclear and polynuclear molybdenum(vi) complexes with the interchangeable coordination site. Polyhedron 2013, 52 , 294-300. https://doi.org/10.1016/j.poly.2012.09.023
    24. Julien Morlot, Nicolas Uyttebroeck, Dominique Agustin, Rinaldo Poli. Solvent‐Free Epoxidation of Olefins Catalyzed by “[MoO 2 (SAP)]”: A New Mode of tert ‐Butylhydroperoxide Activation. ChemCatChem 2013, 5 (2) , 601-611. https://doi.org/10.1002/cctc.201200068
    25. Krunoslav Užarević, Zoran Kokan, Berislav Perić, Nikola Bregović, Srećko I. Kirin. Concomitant polymorphism in the pseudo-peptide Me2N-pC6H4C(O)-Phe-OEt. Journal of Molecular Structure 2013, 1031 , 160-167. https://doi.org/10.1016/j.molstruc.2012.07.026
    26. Mirta Rubčić, Krunoslav Užarević, Ivan Halasz, Nikola Bregović, Momir Mališ, Ivica Đilović, Zoran Kokan, Robin S. Stein, Robert E. Dinnebier, Vladislav Tomišić. Desmotropy, Polymorphism, and Solid‐State Proton Transfer: Four Solid Forms of an Aromatic o ‐Hydroxy Schiff Base. Chemistry – A European Journal 2012, 18 (18) , 5620-5631. https://doi.org/10.1002/chem.201103508
    27. Dario Braga, Elena Dichiarante, Fabrizia Grepioni, Giulio I. Lampronti, Lucia Maini, Paolo P. Mazzeo, Simone D'Agostino. Mechanical Preparation of Crystalline Materials. An Oxymoron?. 2012https://doi.org/10.1002/9780470661345.smc115
    28. Jana Pisk, Dominique Agustin, Višnja Vrdoljak, Rinaldo Poli. Epoxidation Processes by Pyridoxal Dioxomolybdenum(VI) (Pre)Catalysts Without Organic Solvent. Advanced Synthesis & Catalysis 2011, 353 (16) , 2910-2914. https://doi.org/10.1002/adsc.201100439
    29. Krunoslav Užarević, Mirta Rubčić, Maja Radić, Andreas Puškarić, Marina Cindrić. Mechanosensitive metal–ligand bonds in the design of new coordination compounds. CrystEngComm 2011, 13 (13) , 4314. https://doi.org/10.1039/c0ce00807a
    30. Fiona C. Strobridge, Nenad Judaš, Tomislav Friščić. A stepwise mechanism and the role of water in the liquid-assisted grinding synthesis of metal–organic materials. CrystEngComm 2010, 12 (8) , 2409. https://doi.org/10.1039/c003521a
    Download PDF
    Go to Crystal Growth & Design
    Get e-Alerts
    Get e-Alerts

    Crystal Growth & Design

    Cite this: Cryst. Growth Des. 2009, 9, 12, 5327–5333
    Click to copy citationCitation copied!
    https://doi.org/10.1021/cg900824n
    Published September 24, 2009
    Copyright © 2009 American Chemical Society
    Request reuse permissions

    Article Views

    481

    Altmetric

    -

    Citations

    30
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.